An admissible minimax estimator of a bounded scale-parameter in a subclass of the exponential family under scale-invariant squared-error loss

A subclass of the scale-parameter exponential family is considered and for the rth power of the scale parameter, which is lower bounded, an admissible minimax estimator under scale-invariant squared-error loss is presented. Also, an admissible minimax estimator of a lower-bounded parameter in the family of transformed chi-square distributions is given. These estimators are the pointwise limits of a sequence of Bayes estimators. Some examples are given.     

Asphaltene self-association and water-in-hydrocarbon emulsions

The configuration of asphaltenes on the water-oil interface was evaluated from a combination of molar mass, interfacial tension, drop size distribution, and gravimetric measurements of model emulsions consisting of asphaltenes, toluene, heptane, and water. Molar mass measurements were required because asphaltenes self-associate and the level of self-association varies with asphaltene concentration, the resin content, solvent type, and temperature. Plots of interfacial tension versus the log of asphaltene molar concentration were employed to determine the average interfacial area of asphaltene molecules on the interface. The moles of asphaltenes per area of emulsion interface were determined from the molar mass data as well as drop size distributions and gravimetric measurements of the model emulsions. The results indicate that asphaltenes form monolayers on the interface even at concentrations as high as 40 kg/m(3). As well, large aggregates with molar masses exceeding approximately 10,000 g/mol did not appear to adsorb at the interface. The area occupied by the asphaltenes on the interface was constant indicating that self-associated asphaltenes simply extend further into the continuous phase than nonassociated asphaltenes. The thickness of the monolayer ranged from 2 to 9 nm.     

Heteropoly acids, their salts and polyoxometalates as heterogenous, efficient and eco-friendly catalysts in organic reactions: Some recent advances

In this review article, some recent advances of applying heteropoly acids and polyoxometalates as heterogeneous, reusable and eco-friendly catalysts in organic synthesis are discussed.     

Energy and load balancing routing protocol for IoT

Due to the limitation of node energy resources, the management of energy consumption is one of the most important problems of the internet of things (IoT). Therefore, many studies have tried to optimize and manage energy consumption by focusing on different techniques. Although each of these studies has improved and optimized energy consumption, there are many important problems, including maintaining traffic balance and energy consumption of network nodes. Therefore, a new method is necessary to maintain the load and energy balancing of network nodes. Therefore, this paper introduces energy and load balancing routing protocol for IoT (ELBRP) based on the development of the RPL routing protocol and the efficiency of data distribution technique. The ELBRP performance has three steps. In the first step, along with the process of sending DODAG information object (DIO) messages, the status of network nodes is evaluated. In the second step, the DODAG communication graph is formed according to the ELBRP. In the third step, data transmission is done according to the distribution technique with the goal of balancing traffic and energy. The simulation results using cooja simulator showed the superiority of ELBRP in improving energy consumption and successful delivery ratio, reducing delay and increasing the network lifetime compared to the similar methods.     

A Fuzzy Logic-Based Method for Replica Placement in the Peer to Peer Cloud Using an Optimization Algorithm

The Peer to Peer-Cloud (P2P-Cloud) is a suitable alternative to distributed cloud-based or peer-to-peer (P2P)-based content on a large scale. The P2P-Cloud is used in many applications such as IPTV, Video-On-Demand, and so on. In the P2P-Cloud network, overload is a common problem during overcrowds. If a node receives many requests simultaneously, the node may not be able to respond quickly to user requests, and this access latency in P2P-Cloud networks is a major problem for their users. The replication method in P2P-Cloud environments reduces the time to access and uses network bandwidth by making multiple data copies in diverse locations. The replication improves access to the information and increases the reliability of the system. The data replication's main problem is identifying the best possible placement of replica data nodes based on user requests for data access time and an NP-hard optimization problem. This paper proposes a new replica replacement to improve average access time and replica cost using fuzzy logic and Ant Colony Optimization algorithm. Ants can find the shortest path to discover the optimal node to place the duplicate file with the least access time latency. The fuzzy module evaluates the historical information of each node to analyze the pheromone value per iteration. The fuzzy membership function is also used to determine each node's degree based on the four characteristics. The simulation results showed that the access time and replica cost are improved compared to other replica replacement algorithms.

     

An efficient and chemoselective method for protection of thiols catalyzed by aluminumdodecatungstophosphate (AlPW12O40), as a highly water tolerant Lewis acid catalyst

Protection of various thiols with diphenylmethanol was achieved in high yields at room temperature using catalytic amounts of AlPW₁₂O₄₀ in CH₂Cl₂. In the presence of this catalyst, protection of SH versus OH was achieved with high chemoselectivity and yields. The catalyst can be easily recovered and reused. Deprotection of DPM thioethers was also achieved using molecular iodine at reflux in CH₂Cl₂ in high yields.     

Facile protection of carbonyl compounds as oxathiolanes and transoxathioacetalization of oxyacetals promoted by iron(III) trifluoroacetate or trifluoromethanesulfonate as chemoselective and recyclable catalysts

Oxathioacetalization of carbonyl compounds and transoxathioacetalization of O,O-acetals/ketals are reported under nearly neutral conditions promoted by iron(III) trifluoroacetate [Fe(CF₃CO₂)₃] or trifluoromethanesulfonate [Fe(CF₃SO₃)₃] as recyclable and highly efficient Lewis acid catalysts.     

Intersubband optical absorption coefficients and refractive index changes in spherical hydrogenic antidots

In this work, we have studied the optical absorption coefficients and refractive index changes in spherical quantum antidots with hydrogenic donor impurity at the center. For this purpose, the energy spectrum and wavefunctions are first determined, analytically. Then, we have used analytical expressions for the intersubband absorption coefficients and refractive index changes obtained by the compact density matrix formalism. The results show that i—total absorption coeficient increase with increasing size of antidot, ii—the refractive index changes decrease with decreasing antidot size.