Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst

A combination of the newly synthesized and structurally characterized compound, [MoO(O2)2(saloxH)](saloxH2= salicylaldoxime) as catalyst, H2O2 as terminal oxidant and NaHCO3 as co-catalyst when stirred in CH3CN (10 cm3) at room temperature (rt) shows a very pronounced efficiency epoxidation of olefinic compounds, the method being green and economical.     

Gate Current Modeling and Optimal Design of Nanoscale Non-Overlapped Gate to Source/Drain MOSFET

In this paper, novel nanoscale MOSFET with Source/Drain-to-Gate Non-overlapped and high-k spacer structure has been demonstrated to reduce the gate leakage current for the first time. The gate leakage behaviour of novel MOSFET structure has been investigated with help of compact analytical model and Sentaurus Simulation. Fringing gate electric field through the dielectric spacer induces inversion layer in the non-overlap region to act as extended S/D region. It is found that optimal Source/Drain-to-Gate Non-overlapped and high-k spacer structure has reduced the gate leakage current to great extent as compared to those of an overlapped structure. Further, the proposed structure had improved off current, subthreshold slope and DIBL characteristic. It is concluded that this structure solves the problem of high leakage current without introducing the extra series resistance.     

An Adaptive Prediction Strategy with Clustering in Wireless Sensor Network

In Wireless Sensor Network, sensed data reflects two types of correlations of physical attributes: spatial and temporal. In this paper, a scheme named, Adaptive Prediction Strategy with ClusTering (APSCT) is proposed. In APSCT, a data-driven clustering and grey prediction model is used to exploit both the correlations. APSCT minimizes the transmission of messages in the network. However, the use of prediction includes additional computation overhead. There is a trade-off between prediction accuracy and energy consumption in computation and communication in wireless networks. This paper also gives an approach to calculate the upper and lower bound of the prediction interval which is used to evaluate different confidence levels and provides an energy-efficient sensor environment. Simulation is carried out on real-world data collected by Intel Berkeley Lab and results are compared with existing approaches.

     

Alternating current chronopotentiometry: Potential-time equations for quasi-reversible processes and their experimental verification for the limiting reversible case

A general potential-time relationship for quasi-reversible first order electrode reactions with no kinetic complications has been derived for a.c. chronopotentiometry. Cases involving deposition of soluble and insoluble electrode reaction products have been considered. Equations for fully reversible and totally irreversible electrode processes are seen to be limiting cases of this general relation under appropriate conditions. The experimental methodology for a.c. chronopotentiometry has also been described and applied to the studies of the reversible reduction of aqueous cadmium(II) and zinc(II) solutions.     

A zone co‐operation approach for efficient caching in mobile ad hoc networks

Mobile Ad hoc NETwork (MANET) presents a constrained communication environment due to fundamental limitations of client resources, insufficient wireless bandwidth and users' frequent mobility. Caching of frequently accessed data in such environment is a potential technique that can improve the data access performance and availability. Co‐operative caching, which allows the sharing and co‐ordination of cached data among clients, can further explore the potential of the caching techniques. In this paper, we propose a novel scheme, called zone co‐operative (ZC) for caching in MANETs. In ZC scheme, one‐hop neighbours of a mobile client form a co‐operative cache zone. For a data miss in the local cache, each client first searches the data in its zone before forwarding the request to the next client that lies along routing path towards server. As a part of cache management, cache admission control and value‐based replacement policy are developed to improve the data accessibility and reduce the local cache miss ratio. An analytical study of ZC based on data popularity, node density and transmission range is also performed. Simulation experiments show that the ZC caching mechanism achieves significant improvements in cache hit ratio and average query latency in comparison with other caching strategies. Copyright © 2006 John Wiley & Sons, Ltd.     

Priority based efficient data scheduling technique for VANETs

As vehicular networks are gaining popularity, large number of vehicles want to take advantage of these networks, by utilizing the information they have, in order to take decision. Vehicle receives data from other vehicles or from the road side units (RSUs) available across the road. Since RSUs act as router to connect with the external world as well as it is a high capacity storage place where important data (e.g. data used in traffic safety, location dependent query, etc.) can be stored for download purpose for other vehicles moving through the service area. Since the RSUs have limited communication range and vehicles usually moves at very high speed in the service area, they have limited time to serve data to vehicles moving in the service area. For this purpose RSUs have to schedule data in such a way that maximum vehicles can get benefit from the data available with the RSUs. There are many algorithms proposed in the past to schedule data at RSUs. This paper proposes a mechanism to schedule data of those vehicles which are in the coverage range of the RSU. The proposed algorithm outperforms to serve requests whose deadline is about to expire i.e. vehicles which have left the service area after forwarding request to RSU. This scheme performs well in dense network and has good results in highway scenario.     

Room temperature synthesis of protonated layered titanate sheets using peroxo titanium carbonate complex solution

We report the synthesis of peroxo titanium carbonate complex solution as a novel water-soluble precursor for the direct synthesis of layered protonated titanate at room temperature. The synthesized titanates showed excellent removal capacity for Pb(2+) and methylene blue. Based on experimental observations, a probable mechanism for the formation of protonated layered dititanate sheets is also discussed.     

Synthesis and crystal structure of a mixed valence heteropoly green compound, (PPh<Subscript>4</Subscript>)<Subscript>4</Subscript>[PMo<Subscript>12</Subscript>O<Subscript>40</Subscript>], and its use as a catalyst in olefin epoxidation

A green heteropolyblue compound, (PPh₄)₄[PMo₁₂O₄₀] · 3DMF(1), has been synthesized from MoO₃, H₂O₂ and H₃PO₄ in acetylacetone medium and crystallized from N,N-dimethylformamide. Compound 1 was characterized by analytical and spectroscopic methods, and X-ray structure analysis. The compound is a one-electron paramagnet and shows a featureless and cubic EPR spectrum with <g> = 1.95 in DMF glass. The complex shows a Mo(V)–Mo(IV) couple, which has been studied by cyclic voltammetric and coulometric methods. The compound acts as an efficient olefin epoxidation catalyst with H₂O₂ as oxidant and NaHCO₃ as co-catalyst. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Analysis of nano-grating-assisted light absorption enhancement in metal-semiconductor-metal photodetectors patterned using focused ion-beam lithography

We present finite-difference time-domain (FDTD) analysis results of light absorption enhancement factor dependence on the profile shape of nano-gratings etched into the surfaces of metal-semiconductor-metal photodetector (MSM-PD) structures. The MSM-PDs patterned by nano-gratings are optimized geometrically, improving the light absorption near the design wavelength through plasmon-assisted electric field concentration effects. FDTD simulation results show about 50 times light absorption enhancement prediction for 850 nm light due to improved optical signal propagation through the nano-gratings in comparison with the conventional MSM-PD designs employing only a subwavelength aperture. We also report on the nano-grating profile shapes obtained typically in our experiments using focused ion-beam lithography and discuss the dependency of light absorption enhancement on the geometric parameters of nano-gratings inscribed into MSM-PDs.