Behaviour of Pluronic P84 block copolymer micelles above the gelification temperature as probed by positron annihilation lifetime spectroscopy

The new method based on positron annihilation lifetime spectroscopy (PALS) to determine both the mean core radius, R(core), and aggregation number, N(ag), of micelles is applied to the study of aqueous solutions of the triblock Pluronic P84 copolymer as a function of temperature (T), beyond the gelification point (334 K). Two long-lived components appear in the PALS spectra, ascribed to triplet positronium in the water bulk (o-Ps(aq)) and in the organic core of the micelles (o-Ps(org)). Of the various fitting parameters, only the lifetime of the latter species, tau4, and the micellar parameters, R(core) and N(ag), disclose the occurrence of gelification by first increasing up to 334 K, then decreasing. By contrast to what is known in case of phase transition, none of the parameters shows any abrupt change at 334 K, whereas the macroscopic viscosity of the solutions suffers a drastic increase. This is attributed to the fact that positronium is sensitive to the microviscosity of the solutions. At the transition point, the properties of the polyoxipropylene aggregates forming the organic core of the P84 micelles are not greatly affected. Furthermore, the fact that the experimental N(ag) values coincide with those calculated for spheres, from the R(core) values, indicates that the shape of the P84 cores does not change significantly after gelification. The onset of gelification results from a decrease in the hydrogen bonding interactions in the solution with an ensuing relative increase in the interactions between the polyoxipropylene (PPO) groups, initially forming the corona of the P84 micelles, in an intermicellar mode. This increased solicitation of the PPO groups outside their initial location would result in depletion in the number of surfactant molecules forming the micelles, viz. a decrease in both R(core) and N(ag) above 334 K. From the data, additional information can be gained regarding the local viscosity and surface tension in the micellar cores.     

Potassium Fluoride on Alumina: A Convenient Synthesis of O-Alkyl Methyldithiocarbonates. Pyrolysis of O-Benzyl-S-Methyldithiocarbonates

Xanthates were easily prepared by adsorption of alcohol on KF-Al₂O₃ followed by treatment of carbon disulfide and iodomethane at room temperature. Pyrolysis of benzyl xanthate affords to a complex mixture of products. A radical process was proposed to explain the nature of products obtained.     

Performance evaluation and implementation complexity analysis framework for ZF based linear massive MIMO detection

Wireless Networks - This paper discusses a framework for algorithm-architecture synergy for (1) performance evaluation and (2) FPGA implementation complexity analysis of linear massive MIMO...     

Solvent-Free Condensation of Methyl Pyridinium and Quinolinium Salts with Aldehydes Catalyzed by DBU

Methylpyridinium and methylquinolinium salts were condensed under solvent-free conditions with aromatic aldehydes in the presence of 1,8-diazabicyclo[5.4.]undec-7-ene (DBU) as catalyst, by grinding at room temperature. The products are dyes or useful intermediates. The DBU can be easily recycled and reused.     

Impact of the Cd2+ treatment on the electrical properties of Cu2ZnSnSe4 and Cu(In,Ga)Se2 solar cells

The present contribution aims at determining the impact of modifying the properties of the absorber/buffer layer interface on the electrical performance of Cu₂ZnSnSe₄ (CZTSe) thin‐film solar cells, by using a Cd²⁺ partial electrolyte (Cd PE) treatment of the absorber before the buffer layer deposition. In this work, CZTSe/CdS solar cells with and without Cd PE treatment were compared with their respective Cu(In,Ga)Se₂ (CIGSe)/CdS references. The Cd PE treatment was performed in a chemical bath for 7 min at 70 °C using a basic solution of cadmium acetate. X‐ray photoemission spectroscopy measurements have revealed the presence of Cd at the absorber surface after the treatment. The solar cells were characterized using current density–voltage (J–V), external quantum efficiency, and drive‐level capacitance profiling measurements. For the CZTSe‐based devices, the fill factor increased from 57.7% to 64.0% when using the Cd PE treatment, leading to the improvement of the efficiency (η) from 8.3% to 9.0% for the best solar cells. Similar observations were made on the CIGSe solar cell reference. This effect comes from a considerable reduction of the series resistance (R_S) of the dark and light J–V, as determined using the one‐diode model. The crossover effect between dark and light J–V curves is also significantly reduced by Cd PE treatment. Copyright © 2015 John Wiley & Sons, Ltd.     

Prolongement d'un courant négatif plurisousharmonique avec condition sur les tranches

In this Note, we prove a theorem on the extension of a negative (or positive) plurisubharmonic current T (i.e. such that $d{d}^{c}T?0$) with condition on the slices with respect to some coordinates. This theorem generalizes a result proved by El Mir–Ben Messaoud relative to d-closed positive currents with a condition on slices. The method consists first of proving a Chern–Levine–Nirenberg inequality for a positive (or negative) psh current, which is a generalization of results obtained by Bedford–Taylor, Demailly and Sibony for d-closed positive currents. Also we prove an Oka type inequality for positive psh currents, thereby generalizing former results by Ben Messaoud–El Mir concerning positive currents with a negative $d{d}^c$. To cite this article: M. Toujani, H. Ben Messaoud, C. R. Acad. Sci. Paris, Ser. I 339 (2004).     

Opérateur de Monge-Ampère et Tranchage des Courants Positifs Fermés

Sans résumé

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An analytical model for the performance evaluation of stack‐based Web cache replacement algorithms

Web caching has been the solution of choice to web latency problems. The efficiency of a Web cache is strongly affected by the replacement algorithm used to decide which objects to evict once the cache is saturated. Numerous web cache replacement algorithms have appeared in the literature. Despite their diversity, a large number of them belong to a class known as stack‐based algorithms. These algorithms are evaluated mainly via trace‐driven simulation. The very few analytical models reported in the literature were targeted at one particular replacement algorithm, namely least recently used (LRU) or least frequently used (LFU). Further they provide a formula for the evaluation of the Hit Ratio only. The main contribution of this paper is an analytical model for the performance evaluation of any stack‐based web cache replacement algorithm. The model provides formulae for the prediction of the object Hit Ratio, the byte Hit Ratio, and the delay saving ratio. The model is validated against extensive discrete event trace‐driven simulations of the three popular stack‐based algorithms, LRU, LFU, and SIZE, using NLANR and DEC traces. Results show that the analytical model achieves very good accuracy. The mean error deviation between analytical and simulation results is at most 6% for LRU, 6% for the LFU, and 10% for the SIZE stack‐based algorithms. Copyright © 2009 John Wiley & Sons, Ltd.     

Directional Lipschitzness of Minimal Time Functions in Hausdorff Topological Vector Spaces

In a general Hausdorff topological vector space E, we associate to a given nonempty closed set S???E and a bounded closed set Ω???E, the minimal time function T _S,Ω defined by $T_{S,\Omega}(x):= \inf \{ t> 0: S\cap (x+t\Omega)\not = \emptyset\}$ . The study of this function has been the subject of various recent works (see Bounkhel (2012, submitted, 2013, accepted); Colombo and Wolenski (J Global Optim 28:269–282, 2004, J Convex Anal 11:335–361, 2004); He and Ng (J Math Anal Appl 321:896–910, 2006); Jiang and He (J Math Anal Appl 358:410–418, 2009); Mordukhovich and Nam (J Global Optim 46(4):615–633, 2010) and the references therein). The main objective of this work is in this vein. We characterize, for a given Ω, the class of all closed sets S in E for which T _S,Ω is directionally Lipschitz in the sense of Rockafellar (Proc Lond Math Soc 39:331–355, 1979). Those sets S are called Ω-epi-Lipschitz. This class of sets covers three important classes of sets: epi-Lipschitz sets introduced in Rockafellar (Proc Lond Math Soc 39:331–355, 1979), compactly epi-Lipschitz sets introduced in Borwein and Strojwas (Part I: Theory, Canad J Math No. 2:431–452, 1986), and K-directional Lipschitz sets introduced recently in Correa et al. (SIAM J Optim 20(4):1766–1785, 2010). Various characterizations of this class have been established. In particular, we characterize the Ω-epi-Lipschitz sets by the nonemptiness of a new tangent cone, called Ω-hypertangent cone. As for epi-Lipschitz sets in Rockafellar (Canad J Math 39:257–280, 1980) we characterize the new class of Ω-epi-Lipschitz sets with the help of other cones. The spacial case of closed convex sets is also studied. Our main results extend various existing results proved in Borwein et al. (J Convex Anal 7:375–393, 2000), Correa et al. (SIAM J Optim 20(4):1766–1785, 2010) from Banach spaces and normed spaces to Hausdorff topological vector spaces.