Alkyl isocyanides undergo a smooth reaction with alkylidene Meldrum’s acids in the presence of arylhydroxylamines to produce N1-alkyl-2-(3,5-dioxo-2-aryltetrahydro-4-isoxazolyl)alkanamides in high yields. 相似文献
Possible collapsed forms of poly(N-isopropylacrylamide) molecules are reviewed on the basis of first principle calculations. Various configurations and associated conformations are detailed. The calculated optimized structures exhibit different possibilities of creating networks of intra-molecular bonds of the hydrogen type. We show that the most remarkable one is able to form a local, self-saturated and well ordered helix. We also indicate in which direction the synthesis of the molecule should be oriented to improve its global behavior in term of hydrophobic/hydrophilic behavior. 相似文献
Primary and secondary trimethylsilyl ethers were converted to their corresponding ethers in the presence Nafion-H® with good to excellent yields under mild and heterogeneous conditions. 相似文献
The complex anatomy of teeth limits the accessibility and efficacy of regenerative treatments. Therefore, the application of well-known inducers as injectable hydrogels for the regeneration of the dentin-pulp complex is considered a promising approach. In this regard, this study aimed to develop an injectable hydrogel containing mineral trioxide aggregate (MTA). The injectable chitosan/oxidized-nanocrystalline cellulose/MTA (CS/OCNC/MTA) hydrogels were prepared, and the physicochemical properties of these hydrogels were evaluated by TGA, FTIR, Rheological analysis, and SEM. Moreover, the effect of MTA on the swelling and degradability of scaffolds was assessed. The proliferative effects of synthesized hydrogels were also determined on human dental pulp stem cells (hDPSCs) by MTT assay. For induction of differentiation and biomineralization in these cells, the alkaline phosphatase activity and Alizarin Red S staining tests were performed in the presence of fabricated scaffolds. The proliferation of hDPSCs was significantly increased in the presence of these hydrogels. Moreover, the addition of MTA to hydrogel structure dramatically improved the differentiation of hDPSCs. These results suggested that this novel injectable hydrogel provides appropriate physiochemical properties and can be considered a promising scaffold for regenerative endodontic procedures.
Due to the limitation of node energy resources, the management of energy consumption is one of the most important problems of the internet of things (IoT). Therefore, many studies have tried to optimize and manage energy consumption by focusing on different techniques. Although each of these studies has improved and optimized energy consumption, there are many important problems, including maintaining traffic balance and energy consumption of network nodes. Therefore, a new method is necessary to maintain the load and energy balancing of network nodes. Therefore, this paper introduces energy and load balancing routing protocol for IoT (ELBRP) based on the development of the RPL routing protocol and the efficiency of data distribution technique. The ELBRP performance has three steps. In the first step, along with the process of sending DODAG information object (DIO) messages, the status of network nodes is evaluated. In the second step, the DODAG communication graph is formed according to the ELBRP. In the third step, data transmission is done according to the distribution technique with the goal of balancing traffic and energy. The simulation results using cooja simulator showed the superiority of ELBRP in improving energy consumption and successful delivery ratio, reducing delay and increasing the network lifetime compared to the similar methods. 相似文献
Dedicated short-range communications (DSRC) is an important wireless technology for current and future automotive safety and mitigation of traffic jams. In this work, we have designed a Coplanar waveguide microstrip patch antenna with linear, upper and bottom and side slots for application in DSRC. The patch antenna was designed using glass epoxy substrate (FR4). Various parametric analyses such as the current distribution, reflection coefficient, radiation pattern on E- and H-plane as well as the realized gain (dB) were performed. The results were obtained by simulation using high-frequency structure simulator tool. The proposed antenna covers a frequency band of 5.8–5.9 GHz which is highly dedicated to the DSRC wireless communication technology for enhancement of safety of the automotive transport system. The designed antenna shows a good return loss of ??19 dB at 5.9 GHz.The designed antenna shows a promising gain, return loss and radiation pattern for use in DSRC for automotive transport systems.
Urea-hydrogen peroxide (UHP) was used in the presence of maleic anhydride as mediator in a simple and convenient method for the oxidation in high yield of some thiols to the corresponding disulfides. Peroxymaleic acid formed in situ from the reaction of UHP with maleic anhydride has a key role in this oxidation. Performance of the reaction in various solvents showed that methanol was the solvent of choice at 0 oC. The products were isolated by simple filtration on silica gel. 相似文献