全文获取类型
收费全文 | 967篇 |
免费 | 4篇 |
国内免费 | 4篇 |
专业分类
化学 | 642篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 10篇 |
物理学 | 273篇 |
无线电 | 46篇 |
出版年
2021年 | 1篇 |
2020年 | 1篇 |
2018年 | 3篇 |
2017年 | 1篇 |
2013年 | 2篇 |
2012年 | 66篇 |
2011年 | 92篇 |
2010年 | 18篇 |
2009年 | 1篇 |
2008年 | 67篇 |
2007年 | 93篇 |
2006年 | 93篇 |
2005年 | 84篇 |
2004年 | 67篇 |
2003年 | 47篇 |
2002年 | 50篇 |
2001年 | 25篇 |
2000年 | 34篇 |
1999年 | 10篇 |
1998年 | 8篇 |
1997年 | 4篇 |
1996年 | 15篇 |
1995年 | 14篇 |
1994年 | 18篇 |
1993年 | 19篇 |
1992年 | 27篇 |
1991年 | 8篇 |
1990年 | 12篇 |
1989年 | 20篇 |
1988年 | 7篇 |
1987年 | 9篇 |
1986年 | 16篇 |
1985年 | 9篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1981年 | 1篇 |
1978年 | 2篇 |
1977年 | 4篇 |
1976年 | 4篇 |
1975年 | 6篇 |
1974年 | 3篇 |
1973年 | 3篇 |
1969年 | 1篇 |
1968年 | 1篇 |
1948年 | 4篇 |
1947年 | 1篇 |
排序方式: 共有975条查询结果,搜索用时 15 毫秒
1.
2.
3.
4.
5.
6.
7.
We performed ab initio quantum-chemical studies for the development of intra- and intermolecular interaction potentials for formic acid for use in molecular-dynamics simulations of formic acid molecular crystal. The formic acid structures considered in the ab initio studies include both the cis and trans monomers which are the conformers that have been postulated as part of chains constituting liquid and crystal phases under extreme conditions. Although the cis to trans transformation is not energetically favored, the trans isomer was found as a component of stable gas-phase species. Our decomposition scheme for the interaction energy indicates that the hydrogen-bonded complexes are dominated by the Hartree-Fock forces while parallel clusters are stabilized by the electron correlation energy. The calculated three-body and higher interactions are found to be negligible, thus rationalizing the development of an atom-atom pair potential for formic acid based on high-level ab initio calculations of small formic acid clusters. Here we present an atom-atom pair potential that includes both intra- and inter molecular degrees of freedom for formic acid. The newly developed pair potential is used to examine formic acid in the condensed phase via molecular-dynamics simulations. The isothermal compression under hydrostatic pressure obtained from molecular-dynamics simulations is in good agreement with experiment. Further, the calculated equilibrium melting temperature is found to be in good agreement with experiment. 相似文献
8.
Jahn A Vreeland WN Gaitan M Locascio LE 《Journal of the American Chemical Society》2004,126(9):2674-2675
Traditional liposome preparation methods are based on mixing of bulk phases, leading to inhomogeneous chemical and/or mechanical conditions during formation; hence liposomes are often polydisperse in size and lamellarity. Here we show the formation of liposomes that encapsulate reagents in a continuous two-phase flow microfluidic network with precision control of size from 100 to 300 nm by manipulation of liquid flow rates. We demonstrate that by creating a solvent-aqueous interfacial region in a microfluidic format that is homogeneous and controllable on the length scale of a liposome, we can facilitate the fine control of liposome size and polydispersity. 相似文献
9.
Frogs are known to obtain some of their nutrients (e.g., glucose and sodium) through their skin. However, no studies have been made of the possible absorption of transition metals, which exist in most river water at low-ppb (w/w) levels. Therefore, this research was undertaken to evaluate the use of ion chromatography for such an investigation. Solutions of copper and zinc (20 ppb in each) were chosen for use in a small-scale screening study. Ten live frogs were each placed in individual baths for approximately 50 h. Of interest were the net changes in the concentrations of the metals. These differences were the result of any absorption and/or excretion processes that took place. A Dionex IonPac CS5 column was used to analyze this simulated river water, both before and after frogs had been placed in the solution. Included in this paper are: (1) methodology and calculation formulas; (2) precautions needed to ensure sample integrity; (3) statistical analyses, which indicated that ion chromatography is an accurate, precise technique for quantifying Cu and Zn in these samples; and (4) screening-study results, which were used to test the null hypothesis that frogs do not absorb copper and zinc either onto or through their skin. 相似文献