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1.
The applicability of differential electrolytic potentiometry as a detection system in flow injection analysis is investigated. A computer-controlled injector which delivers precise volumes of sample solutions in a reproducible manner was developed. Conditions such as current density employed, the concentrations of the solutions used and the flow rate were optimized. Chloride in water was determined by means of this system. The relation between chloride concentration and the measured signal was found to be Nernstian for solutions of concentrations above 6 μg ml−1 chloride. For solutions below this concentration, the relation is linear. 相似文献
2.
Khaled Al-Takhman 《Journal of Pure and Applied Algebra》2002,173(3):245-271
In this article we defined and studied quasi-finite comodules, the cohom functors for coalgebras over rings. Linear functors between categories of comodules are also investigated and it is proved that good enough linear functors are nothing but a cotensor functor. Our main result of this work characterizes equivalences between comodule categories generalizing the Morita-Takeuchi theory to coalgebras over rings. Morita-Takeuchi contexts in our setting is defined and investigated, a correspondence between strict Morita-Takeuchi contexts and equivalences of comodule categories over the involved coalgebras is obtained. Finally, we proved that for coalgebras over QF-rings Takeuchi's representation of the cohom functor is also valid. 相似文献
3.
Khaled A. Aamer Gregory N. Tew 《Journal of polymer science. Part A, Polymer chemistry》2007,45(6):1109-1121
Supramolecular block‐random copolymers containing [Ir(terpy)2]3+ in the side chain were synthesized via postfunctionalization of a P(S‐b‐ACterpy) block copolymer. Absorbance and emission spectra compared to a model compound show that the polymer backbone has a minor effect on the polymer absorbance but produces a larger shift for the phosphorescence signals to higher wavelength. Dynamic light scattering of the metal complex containing copolymer studied in various solvents showed monomodal aggregation with decreasing aggregate size as the solvent dielectric constant increased. The copolymer precursor P(S‐b‐ACterpy) shows multimodal aggregation in different solvents with the major population consisting of single chains. This difference in behavior between the two polymers is attributed to the electrolytic nature of the complex and the amphiphilicity induced by the charged metal complex. Supramolecular copolymers like these will continue to have interesting self‐organizational properties and may find applications in multicomponent systems for photoinduced charge separation processes. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1109–1121, 2007 相似文献
4.
David A. J. Moran Helen McLelland Khaled Elgaid Griogair Whyte Colin R. Stanley Iain Thayne 《Electron Devices, IEEE Transactions on》2006,53(12):2920-2925
Continued research into the development of III-V high-electron mobility transistors (HEMTs), specifically the minimization of the device gate length, has yielded the fastest performance reported for any three terminal devices to date. In addition, more recent research has begun to focus on reducing the parasitic device elements such as access resistance and gate fringing capacitance, which become crucial for short gate length device performance maximization. Adopting a self-aligned T-gate architecture is one method used to reduce parasitic device access resistance, but at the cost of increasing parasitic gate fringing capacitances. As the device gate length is then reduced, the benefits of the self-aligned gate process come into question, as at these ultrashort-gate dimensions, the magnitude of the static fringing capacitances will have a greater impact on performance. To better understand the influence of these issues on the dc and RF performance of short gate length InP pHEMTs, the authors present a comparison between In0.7Ga0.3As channel 50-nm self-aligned and "standard" T-gate devices. Figures of merit for these devices include transconductance greater than 1.9 S/mm, drive current in the range 1.4 A/mm, and fT up to 490 GHz. Simulation of the parasitic capacitances associated with the self-aligned gate structure then leads a discussion concerning the realistic benefits of incorporating the self-aligned gate process into a sub-50-nm HEMT system 相似文献
5.
The effects of oscillatory motions that may present at a wall during vibrating conditions are studied on flow induced by natural convection and heat transfer inside an open-end vertical channel. The governing equations are non-dimensionalized and reduced to simpler forms. Analytical solutions are obtained for several limiting cases. The reduced governing equations are solved for various values of the controlling parameters. It is found that mean values of average Nusselt numbers are mainly affected by the Grashof number and the amplitude of the horizontal vibrations. Further, amplitudes of Nusselt numbers at the vibrated wall are decreased as the Grashof number increases for horizontal vibrations while they are increased as amplitudes of vibrations increase. It is also found that the squeezing/vibrational Reynolds number, Grashof number and amplitudes of vibrations have a great influence on the trends of stream lines and isotherms especially at low Grashof numbers. Finally, correlations that summarize the effects of the different controlling parameters are determined on the Nusselt numbers and their amplitudes at relatively low frequency of vibrations. 相似文献
6.
Nowadays, tandem structures have become a valuable competitor to conventional silicon solar cells, especially for perovskite over silicon, as metal halides surpassed Si with tunable bandgaps, high absorption coefficient, low deposition, and preparation costs. This led to a remarkable enhancement in the overall efficiency of the whole cell and its characteristics. Consequently, this expands the usage of photovoltaic technology in various fields of applications not only under conventional light source spectrum in outdoor areas, i.e., AM1.5G, but also under artificial light sources found indoors with broadband intensity values, such as Internet of things (IoTs) applications to name a few. We introduce a numerical model to analyze perovskite/Si tandem cells (PSSTCs) using both crystalline silicon (c-Si) and hydrogenated amorphous silicon (a-Si:H) experimentally validated as base cells. All proposed layers have been studied with J-V characteristics and energy band diagrams under AM1.5G by using SCAPS-1D software version 3.7.7. Thereupon, the proposed architectures were tested under various artificial lighting spectra. The proposed structures of Li4Ti5O12/CsPbCl3/MAPbBr3/CH3NH3PbI3/Si recorded a maximum power conversion efficiency (PCE) of 25.25% for c-Si and 17.02% for a-Si:H, with nearly 7% enhancement concerning the Si bare cell in both cases. 相似文献
7.
Dimethyl 1′,1′-ureylenedi(1-ferrocenecarboxylate) (1) formed during the synthesis of 1-amino, 1′-ferrocenecarboxylic acid shows virtual molecular centrosymmetry. Electronic coupling between the two Fc groups through the ureylene bridge results in both Fc groups being individually oxidizable (ΔE1/2?0.14 V). The possible existence of intermolecular electronic communication has discussed. The oxidation was followed by spectroelectrochemistry. The separation between the two halfwave potentials ΔE1/2=137±5 mV and the comproportionation constant Kc=207. 相似文献
8.
Time-weighted average sampling of volatile and semi-volatile airborne organic compounds by the solid-phase microextraction device 总被引:1,自引:0,他引:1
The ultimate goal of the chemist is to perform sample preparation, and analysis, if possible at the place where a sample is located rather than moving the sample to laboratory, as is common practice in many cases at the present time. This approach eliminates errors and time associated with sample transport and storage and therefore it would result in more accurate, precise and faster analytical data. In addition to portability, two other important features of ideal field sample preparation technique are elimination of solvent use and integration with a sampling step. A method is developed which addresses these requirements for the determination of time-weighted average concentration of gas phase compounds using a solid-phase microextraction device. Quantification of target analytes in air using this method can be carried out without external calibration. The volatile and semi-volatile organic compounds in air diffuse into the fiber coating which is retracted a known distance into its needle housing during the sampling period. The coatings used are poly(dimethylsiloxane) and poly(dimethylsiloxane)-divinylbenzene. The sampling rate at which gas phase analytes load onto the fiber is determined for a wide range of hydrocarbons. There is a good agreement between the theoretical and experimental sampling rates. Sampling time ranges from 1 min to 24 h depending on the coating used and its retraction distance. Effect of the flow-rate on the uptake rate by the fiber is studied. The method is tested in the field and compared with National Institute of Occupational Health and Safety Method 1550. Good agreement between the results is obtained. 相似文献
9.
10.
Mohy eldinAbdelFattah Samir ElRayes ElSayedAhmed Soliman Anthony Linden Khaled Abou‐Hadeed Hans‐Jürgen Hansen 《Helvetica chimica acta》2005,88(5):1085-1101
3‐(Phenylsulfonyl)benzo[a]heptalene‐2,4‐diols 1 can be desulfonylated with an excess of LiAlH4/MeLi?LiBr in boiling THF in good yields (Scheme 6). When the reaction is run with LiAlH4/MeLi, mainly the 3,3′‐disulfides 6 of the corresponding 2,4‐dihydroxybenzo[a]heptalene‐3‐thiols are formed after workup (Scheme 7). However, the best yields of desulfonylated products are obtained when the 2,4‐dimethoxy‐substituted benzo[a]heptalenes 2 are reduced with an excess of LiAlH4/TiCl4 at ?78→20° in THF (Scheme 10). Attempts to substitute the PhSO2 group of 2 with freshly prepared MeONa in boiling THF led to a highly selective ether cleavage of the 4‐MeO group, rather than to desulfonylation (Scheme 13). 相似文献