全文获取类型
收费全文 | 271篇 |
免费 | 28篇 |
国内免费 | 1篇 |
专业分类
化学 | 215篇 |
力学 | 2篇 |
数学 | 8篇 |
物理学 | 24篇 |
无线电 | 51篇 |
出版年
2022年 | 3篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 4篇 |
2016年 | 11篇 |
2015年 | 16篇 |
2014年 | 12篇 |
2013年 | 10篇 |
2012年 | 26篇 |
2011年 | 21篇 |
2010年 | 10篇 |
2009年 | 16篇 |
2008年 | 15篇 |
2007年 | 10篇 |
2006年 | 17篇 |
2005年 | 16篇 |
2004年 | 13篇 |
2003年 | 12篇 |
2002年 | 19篇 |
2001年 | 8篇 |
2000年 | 17篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1997年 | 3篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1994年 | 3篇 |
1993年 | 3篇 |
1992年 | 1篇 |
1989年 | 2篇 |
1988年 | 2篇 |
1981年 | 2篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1977年 | 3篇 |
1976年 | 3篇 |
排序方式: 共有300条查询结果,搜索用时 453 毫秒
1.
2.
Many natural products contain carbohydrate moieties that contribute to their biological activity. Manipulation of the carbohydrate domain of natural products through multiple glycosylations to identify new derivatives with novel biological activities has been a difficult and impractical process. We report a practical one‐pot enzymatic approach with regeneration of cosubstrates to synthesize analogues of vancomycin that contain an N‐alkyl glucosamine, which exhibited marked improvement in antibiotic activity against a vancomycin‐resistant strain of Enterococcus. 相似文献
3.
A direct and efficient method for the conversion of alkyl aryl ketones to imidazo[1,2‐α]pyridines has been developed based on initial formation of α‐organosulfonyloxy ketones and their subsequent cyclocondensation by 2‐aminopyridines in one‐pot conditions. 相似文献
4.
The room temperature ionic liquid n‐butylpyridinium tetrafluoroborate (BPyBF4) is used as a ‘green’ recyclable alternative to classical molecular solvents for the cyclocondensation of α‐tosyloxyketones with 1‐aminoisoquinoline to prepare imidazo[2,1‐a]isoquinolines in good yields. 相似文献
5.
Ding L Liu W Wang W Glinka CJ Worcester DL Yang L Huang HW 《Langmuir : the ACS journal of surfaces and colloids》2004,20(21):9262-9269
A neutron diffraction method applicable to nonlamellar phases of substrate-supported lipid membranes is described and validated. When prepared on a flat substrate, the resulting nonlamellar phases have layered symmetry which provides some advantages over powder diffraction for detailed structure determination. This approach recently led to the detection of a rhombohedral phase and a distorted hexagonal phase of lipids. Here the determination of intensity and phase information for such phases is demonstrated by application to the hexagonal phase of diphytanoyl phosphatidylcholine (DPhPC). The hexagonal symmetry is used to verify the data reduction procedure for the intensities of the diffraction peaks. Diffraction intensities measured while varying the D2O/H2O ratio in the relative humidity was used to solve the phase problem. The neutron scattering length density distribution of the hexagonal phase was constructed and analyzed to elucidate the packing of the lipid molecules. The structure of DPhPC in the hexagonal phase is of interest in connection with its stalk structure in the rhombohedral phase. We also found that the incorporation of tetradecane into the DPhPC hexagonal phase is limited, similar to the case for dioleoyl phosphatidylethanolamine. 相似文献
6.
Huey G. Lee 《Journal of chromatography. A》1997,790(1-2):215-223
Rapid (<5 min) high-performance isoelectric focusing was performed in uncoated fused-silica capillaries to resolve isoforms of monoclonal antibodies and to determine their isoelectric points (pI). The methodology involved the use of a 32 cm (effective length 9 cm)×50 μm I.D. uncoated capillary. (Hydroxypropyl)methyl cellulose was used as an additive to suppress analyte–wall interaction and to precisely control electroosmotic flow so that focusing and mobilization of focused zones past detector occur simultaneously. Urea was included in the separation medium to solubilize the antibodies that precipitated at their point of focusing. The methods with and without urea used ampholytes pH 5–8 to generate a demonstrable linear gradient between pH 5.4 and pH 7.2, based on the separation of various protein standards. Reproducibility [<2% (R.S.D.)] of the migration times (corresponding to the detectable isoforms of the antibodies) was obtained by using two sets of reagents and capillaries on three consecutive days. pI values determined from day-to-day with a reference standard were shown to vary by only 0.01 pH unit. The described capillary isoelectric focusing methods provided a rapid, simple and reproducible way of monitoring micro-heterogeneity and pI of the murine monoclonal antibodies investigated. 相似文献
7.
Hoh Huey Jiun Ibrahim Ahmad Azman Jalar Ghazali Omar 《Microelectronics Reliability》2006,46(5-6):836-845
This paper characterizes die damage resulting from various wafer thinning processes. Die fracture strength is measured using ball breaker test with respect to die surface finish. Further study on surface roughness and topography of each surface finish is obtained by atomic force microscopy (AFM) and scanning electron microscopy (SEM) techniques. Stress relief process with 25 μm removal is able to strengthen 100 μm wafer by 20.4% using chemical wet etch and 75 μm wafer by 36.4% with plasma etch. Relatively, plasma etching shows higher fracture strength and flexibility compared to chemical wet etch. This is due to topography of the finished surface of plasma etch is smoother and rounded, leading to a reduced stress concentration, hence improved fracture strength. 相似文献
8.
9.
Synthesis of Two‐Dimensional Transition‐Metal Phosphates with Highly Ordered Mesoporous Structures for Lithium‐Ion Battery Applications
下载免费PDF全文
![点击此处可从《Angewandte Chemie (International ed. in English)》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Dan Yang Dr. Ziyang Lu Dr. Xianhong Rui Xiao Huang Dr. Hai Li Dr. Jixin Zhu Wenyu Zhang Prof. Yeng Ming Lam Prof. Huey Hoon Hng Prof. Hua Zhang Prof. Qingyu Yan 《Angewandte Chemie (International ed. in English)》2014,53(35):9352-9355
Materials with ordered mesoporous structures have shown great potential in a wide range of applications. In particular, the combination of mesoporosity, low dimensionality, and well‐defined morphology in nanostructures may exhibit even more attractive features. However, the synthesis of such structures is still challenging in polar solvents. Herein, we report the preparation of ultrathin two‐dimensional (2D) nanoflakes of transition‐metal phosphates, including FePO4, Mn3(PO4)2, and Co3(PO4)2, with highly ordered mesoporous structures in a nonpolar solvent. The as‐obtained nanoflakes with thicknesses of about 3.7 nm are constructed from a single layer of parallel‐packed pore channels. These uniquely ordered mesoporous 2D nanostructures may originate from the 2D assembly of cylindrical micelles formed by the amphiphilic precursors in the nonpolar solvent. The 2D mesoporous FePO4 nanoflakes were used as the cathode for a lithium‐ion battery, which exhibits excellent stability and high rate capabilities. 相似文献
10.
Jiun‐Wei Horng Chun‐Li Hou Chun‐Ming Chang Hung‐Pin Chou Chun‐Ta Lin Yao‐Hsin Wen 《ETRI Journal》2006,28(4):486-494
Two current‐mode and/or voltage‐mode quadrature oscillator circuits each using one fully‐differential second‐generation current conveyor (FDCCII), two grounded capacitors, and two (or three) grounded resistors are presented. In the proposed circuits, the current‐mode quadrature signals have the advantage of high‐output impedance. The oscillation conditions and oscillation frequencies are orthogonally (or independently) controllable. The current‐mode and voltage‐mode quadrature signals can be simultaneously obtained from the second proposed circuit. The use of only grounded capacitors and resistors makes the proposed circuits ideal for integrated circuit implementation. Simulation results are also included. 相似文献