排序方式: 共有36条查询结果,搜索用时 9 毫秒
1.
Blume Hans-Juergen C. Huhnerfuss Heinrich Alpers Werner 《Geoscience and Remote Sensing, IEEE Transactions on》1983,(3):295-300
Airborne microwave radiometer measurements over mineral and monomolecular oil films and adjacent clean sea surfaces are reported. An artificial crude-oil spill experiment in the New York Bight area showed a brightness temperature increase of the sea surface at 1.43 GHz as expected from a multilayered system with different dielectric constants. However, a monomolecular surface-film experiment with oleyl alcohol conducted in the North Sea during MARSEN in 1979 showed a strong brightness temperature depression at 1.43 GHz and no change in brightness temperature at 2.65 GHz. It is postulated that the monomolecular layer, because of its physical and chemical properties, polarized the underlying water molecules so strongly that the emissivity decreased from 0.31 to 0.016. It is estimated that the effective dielectric constant changed from 90 to 5.2 × 104. Because these phenomena occurred at 1.43 GHz it may be concluded that this frequency is very close to the center of a new anomalous dispersion region resulting from a restructuring of the water layer below the surface film. 相似文献
2.
Sebastian Mendrek Aleksandra Mendrek Hans-Juergen Adler Andrzej Dworak Dirk Kuckling 《Colloid and polymer science》2010,288(7):777-786
Temperature-sensitive poly(glycidol)-b-poly(N-isopropylacrylamide) block copolymers (PGl55PNIPAAmy) were synthesised and their aqueous solutions investigated by different methods including differential scanning calorimetry
(DSC), UV-VIS spectroscopy as well as dynamic and static light scattering. The cloud point temperature (T
c) depended on the composition of the investigated block copolymers and increased with decreasing length of the PNIPAAm block
in PGl55PNIPAAmy copolymers. In contrast, the enthalpy of phase separation of PNIPAAm segments measured by DSC decreased with decreasing length
of the PNIPAAm block in the polymer. These findings can be correlated with the behaviour of homo-PNIPAAm with similar molecular
weights indicating that the influence of PGl on the local environment and phase separation of PNIPAAm chains is similar to
the influence observed for PNIPAAm chains bearing different low molecular weight end group. Using DLS measurement, it was
shown that the aggregation process depended on the PGl/PNIPAAm block ratio. If the PGl/PNIPAAm ratio was low, stable core-shell
aggregates were formed. In contrast, the tendency to formation of large unstable, loose aggregates was observed for copolymers
with high PGl/PNIPAAm ratio. 相似文献
3.
For grafting polypyrrole layers on oxidic substrates, the synthesis and characterization of a new adhesion promoter 11‐(pyrrol‐3‐yl) undecyl trimethoxysilane (PyTMS) were described in this article. The oxidation potential of PyTMS was determined by cyclic voltammetry. The grafting behavior of such an adhesion promoter on oxidized surface and chemical deposition of polypyrrole over the modified oxidized surface were studied. The adsorbed layer on the oxidized substrates thus formed was determined by both contact angle measurements and X‐ray photoelectron spectroscopy. Chemical polymerization of terminal pyrrole moieties on such substrates yielded adhesive polypyrrole films, and SEM image showed that the morphology of the polypyrrole films was influenced by the experimental conditions. 相似文献
4.
Emission Reduction and Capacity Increase in GSM Networks by Single Antenna Interference Cancellation
Stefan Brueck Hans-Juergen Kettschau Frank Obernosterer 《AEUE-International Journal of Electronics and Communications》2004,58(4):274-283
There is an increasing demand to utilize the frequency spectrum of mobile communication systems most efficiently. This means in particular to GSM networks that the frequency reuse shall be planned as low as possible. In this case the system may become limited by interference rather than coverage. One promising technology for GSM mobiles in interference-limited systems is single antenna interference cancellation (SAIC). This receiver technology allows both for increasing the network capacity and for reducing the base station transmit power. The aim of this paper is to assess the emission reduction as well as the system capacity capabilities when SAIC technology is applied in downlink receivers. 相似文献
5.
ω-(Pyrrol-1-yl alkyl) dimethylchlorosilanes with different chain length were synthesized and characterized with IR, NMR and elemental analysis. The growth of self-assembled monolayers of ω-(pyrrol-1-yl alkyl) dimethylchlorosilanes on oxide surfaces has been investigated. The order gradually improved with adsorption time and highly ordered SAMs were obtained for nearly 2 days adsorption time. Characterization of the films has been performed with contact angle measurements, ellipsometry, SPR and grazing incident FTIR. The chemical deposition of polypyrrole on the modified surface was investigated. The thickness of polypyrrole layer was influenced by the concentration of monomer, the deposition time, and the ratio of monomer to oxidant. 相似文献
6.
Petar P. Novakov Dirk Kuckling Ljubov Fedorova P. Hans-Juergen Adler 《Macromolecular Symposia》1998,128(1):195-201
Novel branched blockcopolymers from polyvinylpyridine are formed by chromium allyl compounds. Our present work shows results for the homopolymerization of vinylpiridine (VP), dimethylacrylamide (DMAA), tert - butylacrylate (t - BA) as well as the graftcopolymerization of poly(vinylpyridine) (PVP), using tris (π - allyl) chromium (TPC) as initiator. PVP activated by TPC was used for grafting with DMAA - “grafting from”. On the other hand living PDMAA polymerized by TPC, was able to react with PVP chain - “grafting onto”. 相似文献
7.
Evelin Jaehne Thomas Kowalik Hans-Juergen P. Adler Andreas Plagge Martin Stratmann 《Macromolecular Symposia》2002,177(1):97-110
Cellulose as natural and non-toxic material is very interesting for biological applications. Its poor solubility in organic solvents can be improved by introduction of long alkyl chains. Phosphate-substituted cellulose derivatives form ultra-thin layers on several metal surfaces [1, 2]. The layers were applied on the surfaces via dip coating from dilute solutions and characterised by contact angle measurements. Initial corrosion tests were performed. These polymers were applied as adhesion promoters for steel-, titanium- and hydroxy apatite surfaces. Medical implants were pre-treated by UV irradiation, coated with the cellulose derivatives and activated by hot water treatment. The adhesion of the implants surpassed that of conventionally used PMMA systems. 相似文献
8.
Susann Schachschal Andrij Pich Hans-Juergen Adler 《Colloid and polymer science》2007,285(10):1175-1180
In the present paper, we describe the preparation of hybrid particles consisting of polymeric core with deposited hydroxyapatite
(HAp) nanocrystals. Polystyrene submicron particles modified by β-diketone groups have been used as templates for the growth of HAp. Hybrid particles with HAp nanocrystal content between
7 and 50 wt% have been prepared. Microscopy studies indicate that hybrid particles exhibit “raspberry” morphology, and HAp
nanoparticles are not homogeneously distributed on the polymer particle surface. The increase in the HAp content on the polymer
particle surface reduces the colloidal stability of the hybrid particles because of the vanishing of the surface charge. 相似文献
9.
Helmut Werner Hans-Juergen Kraus Ulrich Schubert Klaus Ackermann Peter Hofmann 《Journal of organometallic chemistry》1983,250(1):517-536
The complexes (η5-C5H5)Pd(η1-C5H5)PR3 which are prepared from [Cl(PR3)-Pd]2(μ-OCOCH3)2 and TlC5H5 are fluxional in solution. According to the 1H and 13C NMR spectra at various temperatures, two dynamic processes occur. The process with the higher activation energy is a π/σ (η5/η1) exchange of the two different cyclopentadienyl ligands, whereas the second one with the lower activation energy presumably is a metallotropic rearrangement (1,2-shift). The coalescence temperature for the η5/η1 exchange depends on the size of the phosphine. The X-ray structural analysis of (C5H5)2PdPPri3 proves that it exists as a “frozen” η5 + η1 structure in the crystal with the palladium approximately in a square-planar coordination. The η5-bonded cyclopentadienyl ring shows some unusual bonding patterns which are obviously electronic in nature. EHT-MO calculations for (η5-C5H5)PdCH3(PH3) indicate that in this model system alternating CC distances in the ring and a stronger bond of the metal to one of the five carbon atoms of the C5H5 ligand are to be expected. The calculations suggest that in similar complexes possessing a six-electron donor ligand like C5H5? and a metal fragment which is isolobal to PdCH3(PH3)+, analogous distortions should be observed. Some reactions of the compounds (η5-C5H5)Pd(η1-C5H5)PR3 are described. 相似文献
10.
Stable polypyrrole dispersions were prepared by chemical oxidative polymerization of pyrrole in an aqueous medium containing different anionic salts - sodium benzoate, potassium hydrogen phthalate and sodium hydrogen succinate. Results of the elemental analysis and FT-IR spectroscopy confirmed that the anionic salts are incorporated in the conducting polymers and functioned as the dopants. The retardation of pyrrole polymerization was observed when a certain amount of the salt was used as dopant. SEM images of polypyrrole dispersions indicate large spherical particles (150-180nm). The conductivity of polypyrrole composites has also been investigated. 相似文献