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排序方式: 共有111条查询结果,搜索用时 15 毫秒
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2.
A. Vijaya Bhaskar Reddy Rehan Rafiq Aqeel Ahmad Abdulhalim Shah Maulud Muhammad Moniruzzaman 《Molecules (Basel, Switzerland)》2022,27(22)
In the current study, we have synthesized an imidazolium based cross-linked polymer, namely, 1-vinyl-3-ethylimidazolium bis(trifluoromethylsulfonyl)imide (poly[veim][Tf2N]-TRIM) using trimethylolpropane trimethacrylate as cross linker, and demonstrated its efficiency for the removal of two extensively used ionic dyes—methylene blue and orange-II—from aqueous systems. The detailed characterization of the synthesized poly[veim][Tf2N]-TRIM was performed with the help of 1H NMR, TGA, FT-IR and FE-SEM analysis. The concentration of dyes in aqueous samples before and after the adsorption process was measured using an UV-vis spectrophotometer. The process parameters were optimised, and highest adsorption was obtained at a solution pH of 7.0, adsorbent dosage of 0.75 g/L, contact time of 7 h and dye concentrations of 100 mg/L and 5.0 mg/L for methylene blue and orange-II, respectively. The adsorption kinetics for orange-II and methylene blue were well described by pseudo-first-order and pseudo–second-order models, respectively. Meanwhile, the process of adsorption was best depicted by Langmuir isotherms for both the dyes. The highest monolayer adsorption capacities for methylene blue and orange-II were found to be 1212 mg/g and 126 mg/g, respectively. Overall, the synthesized cross-linked poly[veim][Tf2N]-TRIM effectively removed the selected ionic dyes from aqueous samples and provided >90% of adsorption efficiency after four cycles of adsorption. A possible adsorption mechanism between the synthesised polymeric adsorbent and proposed dyes is presented. It is further suggested that the proposed ionic liquid polymer adsorbent could effectively remove other ionic dyes and pollutants from contaminated aqueous systems. 相似文献
3.
Sait Sadiq M. Ahmed Syed Faraz Rafiq Muhammad Rahil 《Journal of Thermal Analysis and Calorimetry》2021,143(3):1935-1942
Journal of Thermal Analysis and Calorimetry - The purpose of this study is to measure and document the maximum level of broadband radiofrequency electromagnetic radiations in the vicinity of... 相似文献
4.
Rafiq Shahid Abbas Zaheer Nawaz Muhammad Alharbi Sayer Obaid 《Journal of Thermal Analysis and Calorimetry》2021,145(6):3269-3279
Journal of Thermal Analysis and Calorimetry - A numerical model is developed to study the effects of temperature-dependent viscosity on heat transfer in magnetohydrodynamic flow of micropolar fluid... 相似文献
5.
This article presents a thorough statistical analysis of the capacity of orthogonal space-time block coded (OSTBC) multiple-input multiple-output (MIMO) Nakagami- lognormal (NLN) channels. The NLN channel model allows to study the joint effects of fast fading and shadowing on the statistical properties of the channel capacity. We have derived exact analytical expressions for the probability density function (PDF), cumulative distribution function (CDF), level-crossing rate (LCR), and average duration of fades (ADF) of the capacity of MIMO NLN channels. It is observed that an increase in the MIMO dimension or a decrease in the severity of fading results in an increase in the mean channel capacity, while the variance of the channel capacity decreases. On the other hand, an increase in the shadowing standard deviation increases the spread of the channel capacity, however the shadowing effect has no influence on the mean channel capacity. We have also presented approximation results for the statistical properties of the channel capacity, obtained using the Gauss-Hermite integration method. It is observed that approximation results not only reduce the complexity, but also have a very good fitting with the exact results. The presented results are very useful and general because they provide the flexibility to study the impact of shadowing on the channel capacity under different fading conditions. Moreover, the effects of severity of fading on the channel capacity can also be studied. The correctness of theoretical results is confirmed by simulations. 相似文献
6.
M. Rafiq H. Siddiqui S.F. Adil K. Nour M.E. Assal A. Al-Warthan 《Arabian Journal of Chemistry》2013,6(4):435-438
Silver chloride was found to be stable even after calcination at 650 °C for 10 h. SEM studies revealed the morphology of silver chloride as hexagonal particles. TEM studies show the size of silver chloride particles to have an average size of 6–7 nm. Thermal studies suggest that silver chloride nanoparticles behave like ionic liquid or molten salt in the range of 455–650 °C. 相似文献
7.
M. Rafiq S. Ali S. Shahzadi M. Shahid S. K. Sharma K. Qanungo 《Journal of the Iranian Chemical Society》2014,11(1):169-178
Organotin complexes have been synthesized by refluxing 2-mercapto-5-methyl benzimidazole with R2SnCl2/R3SnCl (R = Me, n-Bu, Ph) in 1:1 molar ratio in the first step. In the second step, synthesized organotin(IV) complexes were treated with CS2 and R2SnCl2/R3SnCl/PdCl2 to yield homo- and heterobimetallic complexes. The composition of the synthesized complexes, the bonding behavior of the donor groups, and structural assignments were studied by elemental analysis and different spectral techniques, including IR and multinuclear NMR (1H, 13C). The IR data shows bidentate nature of the ligand which is also confirmed by semiempirical study, while NMR data confirms the four-coordinated geometry in solution. The free ligand and its respective homo- and heterobimetallic complexes were screened in vitro against a number of microorganisms to assess their biocidal properties. The biological activity data show that complexes exhibits significant antibacterial and antifungal activities as compared to ligand with few exceptions. 相似文献
8.
BaMnO3 nanorods were synthesized at 200 °C and atmospheric pressure using the composite-hydroxide mediated method. X-ray diffraction, scanning electron microscopy and energy dispersive X-ray spectroscopy were used to investigate the structure, size, morphology, phase purity and elemental composition of BaMnO3 nanorods. Electrical characterization of BaMnO3 pellet was performed at 300-400 K and in the frequency range 200 Hz-2 MHz. Temperature dependence of AC conductivity suggests that the BaMnO3 pellet behaves as a semiconducting material and conduction across the pellet can be explained by the correlated barrier hopping model. Impedance analysis was performed using the equivalent circuit model (R1Q1C1)(R2C2) and it suggests a single relaxation process in the BaMnO3 pellet at a particular temperature. The analysis reveals that the BaMnO3 pellet behaves like an n-type semiconductor material due to the presence of oxygen vacancies and some disorder. Modulus spectroscopy also supports the impedance results. 相似文献
9.
Shaukat Mahmood Nek M. Shaikh M.A. Kalyar M. Rafiq N.K. Piracha M.A. Baig 《Journal of Quantitative Spectroscopy & Radiative Transfer》2009,110(17):1840-1850
In the present work emission and absorption spectroscopy have been used to determine the plasma parameters of neon in a hollow cathode discharge lamp. The excitation temperature is determined using the intensity ratio method and Boltzmann's plot method whereas the electron density is determined from the Stark broadening of the spectral lines. The behavior of the optogalvanic signal as a function of laser energy has been studied for three transitions from the 2p53s [1/2]2 metastable state following ΔJ=ΔK=0, ±1 dipole selection rules. The saturation technique has been used to measure the photoionization cross section from three intermediate states 2p53p′ [1/2]1, 2p53p′ [3/2]2 and 2p53p [5/2]3 up to the 2p5 2P1/2 ionization threshold. 相似文献
10.
Ljubomir iri Arif Rafiq Nenad Caki 《Nonlinear Analysis: Theory, Methods & Applications》2009,70(12):4332-4337
In this note, we speed up the convergence of the Picard sequence of iterations for strongly accretive and strongly pseudo-contractive mappings. Our results improve the results of Chidume [C.E. Chidume, Picard iteration for strongly accretive and strongly pseudo-contractive Lipschitz maps, ICTP Preprint no. IC2000098; C.E. Chidume, Iterative Algorithms for Non-expansive Mappings and Some of Their Generalizations, in: Nonlinear Analysis and Applications: To V. Lakshmikantham on his 80th Birthday, vol. 1, 2, Kluwer Acad. Publ, Dordrecht, 2003, pp. 383–429], and Liu [L. Liu, Approximation of fixed points of a strictly pseudo-contractive mapping, Proc. Amer. Math. Soc. 125 (2) (1997) 1363–1366], and some other known results. The technique of the proof, presented in this paper, is different from the technique used by Chidume. 相似文献