An innovative semianalytical technique for ceramic evaluation at microwave frequencies

We have developed an innovative semianalytical technique for various substrate material characterization. The developed technique is a measurement procedure and data-reduction formulation that takes into consideration the radiation loss in a resonant structure, allowing for a more effective means of dielectric- and conductor-loss determination for a microstrip ring resonator and its substrate material. We separate dielectric and conductor loss precisely, evaluate the contribution of each term in the overall loss performance, and analytically predict the error in their respective predicted value.     

Direct observation of charge-carrier capture in an array of self-assembled InAs/GaAs quantum dots

In this work, charge-carrier capture by an array of self-assembled InAs/GaAs quantum dots was directly observed for the first time by capacitance recharge. It is proposed to process the obtained transient-capture data by a similar method to that used for emission, by the box-car method. The capture activation energies are determined and compared with the emission activation energies.     

Efficient asymmetric epoxidation of alpha,beta-unsaturated ketones using a soluble triblock polyethylene glycol-polyamino acid catalyst

[reaction: see text]. Polyethylene glycol (PEG)-bound poly-L-leucine acts as a THF-soluble catalyst for the Juliá-Colonna asymmetric epoxidation of enones. Excellent enantioselectivities may be obtained even with short chain length polyleucine. FT-IR investigations have determined that the catalytically active polyleucine components of these copolymers have an alpha-helical structure.     

An NMR study of proton exchange in the system p-nitrosophenol—p-quinone monooxime

The solvent used was dimethylformamide at neutral and alkaline pH. The equilibrium constants are determined by spectrophotometry. The rate of proton exchange has been measured as a function of temperature and concentration. The rate constants and activation energies have been measured; for uncatalyzed exchange k_n=(1.5±0.5) ·· 10³ M^–1 sec^–1, E=8±1 kcal/mole, while base-catalyzed exchange has k=(0.3±0.1) · 10⁶ M^–1 sec^–1 and E=6±1 kcal/mole.We are indebted to A. I. Brodskii for assistance in this work, and to V. I. Oshkaderov and L. A. Kichakova for recording the NMR spectra.     

Electrical conductivity and phase transitions of the solid electrolyte system (Cs1−yRby)Cu4Cl3(I2−xClx)

Results of electrical conductivity measurements, thermal analysis, and X-ray diffraction studies indicate the existence of four phases, between 295 K and the melting points, in the system (Cs_1?yRb_y)Cu₄Cl₃I₂. These phases are designated α, á β, γ in order of decreasing temperature. The α phase is isostructural with α-RbAg₄I₅; the á phase is also cubic and very likely belongs to space groupP2₁3, a subgroup ofP4₁32 andP4₃32 to which the α phase belongs. There is a high probability that the á → α transition is continuous. The á → α transition is not discernible in the conductivity measurements or thermal analysis; therefore the line of á-α transitions is presently unknown. The β phase transforms to the á and the γ phase transforms to the β phase wheny ≤ 0.36; the γ phase transforms to the α phase wheny ≥ 0.36. That is, there is a triple point aty = 0.36, T = 399K. The γ-β, β-α′, and γ-α transitions are all hysteretic and are therefore first order. The conductivities of the β phases are relatively low and the enthalpies of activation relatively high. The conductivity of the β phase decreases with increasingy. The β phase probably belongs to space groupR3, in which the Cu⁺ ions can be ordered. The α and á phases are the true solid electrolytes; the conductivities are high, >0.73 Ω^?1cm^?1 at 419 K, and the enthalpies of activation of motion of the Cu⁺ ions low, 0.11 eV.In the system CsCu₄Cl₃(I_2?xCl_x), 0 ≤ x ≤ 0.25, the Cl^? for I^? substitutions affect the transitions to only a small extent relative to the stoichiometric compound. The β phase occurs for allx and transforms to á.     

An NMR study of hydrogen exchange in p-hydroxybenzoic acid

The compound has been used over a temperature range in dimethylsulfoxide, with trichloroacetic acid and triethylamine as catalysts. The rate constant for uncatalyzed bimolecular exchange at 25 C is k_N=131 M^–1 sec^–1; the constant for acid-catalyzed exchange is k_A=0.9 · 10⁴ M^–1 sec^–1; and that for base-catalyzed exchange is k_B=0.5 · 10⁴ M^–1 sec^–1. The activation energy for uncatalyzed exchange is 5.75 kcal/mole. The exchange rates in dimethylformamide and acetone are higher, on account of differences in the hydrogen bond. The exchange rates of the isomers fall in the sequence ortho > para > meta, which is due to conjugation and intramolecular hydrogen bonding. The exchange mechanism is discussed. Simple relationships in dimensionless parameters are given for calculating the exchange rate from the shape of the NMR signal.     

Fourier analysis on the Heisenberg group. I. Schwartz space

We derive a usable characterization of the group FT (Fourier Transform) of Schwartz space on the Heisenberg group $\text{H}$ⁿ, in terms of certain asymptotic series. To accomplish this we study in detail the FT of multiplication and differentiation operators on $\text{H}$ⁿ, the relation of multiple Fourier series to the FT, and the process of group contraction on $\text{H}$ⁿ. We use our characterization to solve a form of the division problem for convolution of $\text{H}$ⁿ, which has application to Hardy space theory.     

Atomic dipole approximation and energies of interactions between purine and pyrimidine bases. I. Electrostatic interactions of adenine with uracil,thymine, thiouracils,dihydrouracil, and 5-fluorouracil

The atomic dipole approximation has been employed to calculate the energies of electrostatic interaction between adenine and various pyrimidine derivatives. Minima of the interaction energy for various planar configurations were determined. Inclusion of the “monopole–dipole” and “dipole–dipole” terms in the multipole expansion improves considerably the agreement with experimental data. The effect of sulfur substitution has been investigated in detail. Formation of N? H…?S hydrogen bonds is less favorable than of N? H…?O bonds, due largely to the lower atomic dipole of the sulfur atom resulting from the shift of the π-electron charge toward the neighboring carbon. The results are relevant to the interactions of thiouracils in nucleic acids.     

Spin reorientation in silicon-substituted yttrium iron garnet

Mössbauer spectroscopy of a silicon substituted YIG containing 0.3 Si⁴⁺ per formula unit has shown that a spin reorientation, from [111] to [100], occurs between 265 and 80 K. The transitions occur by way of the magnetic space groups $\text{R}\text{3}\text{c}\text{′ →}\text{F}\text{2′}\text{d}\text{′}\text{→}\text{I}\text{4}{}_1\text{ac}\text{′}\text{d}\text{′}$. The broad spin reorientation is mainly a consequence of the persistence of a nonuniform distribution of Fe²⁺ ions over the octahedral sites.