One-Pot,Fluoride-Promoted Wittig Reaction

A one-pot, fluoride-promoted Wittig reaction was developed. The reactions of ethyl α-bromoacetate with aliphatic, aromatic, and heteroaromatic aldehydes in the presence of tri-n-butylphosphine and tetrabutylammonium fluoride produced α,β-unsaturated esters in good to excellent yields and E-stereoselectivity. Under the same conditions, reactions of ethyl α-bromopropionate, α-bromo acetonitrile, and α-bromoacetophenone with aliphatic and aromatic aldehydes in the presence of tri-n-butylphosphine and tetrabutylammonium fluoride produced the expected α,β-unsaturated derivatives in good E-stereoselectivity. The protocol was extended to semistabilized ylides and applied to the synthesis of some combretastatin analogs.     

Cooperative and Reliable ARQ Protocols for Energy Harvesting Wireless Sensor Nodes

One class of wireless sensor networks makes use of sensor nodes that recharge their batteries by harvesting energy from the surrounding environment. Being continuously recharged, the battery does not need to be replaced regularly and the sensor node is maintenance-free. A key module in such sensor network solutions is the data link automatic repeat request (ARQ) protocol, which must be designed to reliably deliver sensor nodes data at the minimum energy cost. With this objective in mind, two ARQ protocol classes are compared. In one class, each sensor node operates individually. In the other, the concept of cooperative communications is adopted, whereby neighboring sensor nodes help each other during the retransmission process. It is shown that the use of cooperative ARQ protocols in energy harvesting sensor networks enables sensor nodes to balance their energy consumption to match their own battery recharge rate. In turn, a balanced energy consumption-to-recharge rate ratio has the potential to improve the network throughput. Both classes of ARQ protocols are analyzed and compared. Estimated throughput gains are discussed under various network scenarios.     

Atmospheric Pressure Plasma Discharge for Polysiloxane Thin Films Deposition and Comparison with Low Pressure Process

An atmospheric pressure dielectric barrier plasma discharge has been used to study a thin film deposition process. The DBD device is enclosed in a vacuum chamber and one of the electrodes is a rotating cylinder. Thus, this device is able to simulate continuous processing in arbitrary deposition condition of pressure and atmosphere composition. A deposition process of thin organosilicon films has been studied reproducing a nitrogen atmosphere with small admixtures of hexamethyldisiloxane (HMDSO) vapours. The plasma discharge has been characterized with optical emission spectroscopy and voltage-current measurements. Thin films chemical composition and morphology have been characterized with FTIR spectroscopy, atomic force microscopy (AFM) and contact angle measurements. A strong dependency of deposit character from the HMDSO concentration has been found and then compared with the same dependency of a typical low pressure plasma enhanced chemical vapour deposition process.     

Dynamic provisioning of availability-constrained optical circuits in the presence of optical node failures

This paper investigates what impact optical node failures may have on wavelength-division-multiplexed networks, in which reliable end-to-end optical circuits are provisioned dynamically. At the node level, the optical cross-connect (OXC) equipment availability measure is estimated using proven component level availability models. At the network level, end-to-end optical circuits are provisioned only when the level of connection availability required by the application can be guaranteed. With the objective of yielding efficient utilization of the network resources, i.e., fibers and OXCs, circuit redundancy is achieved by means of shared path protection (SPP) switching, in combination with differentiated reliability (DiR). The resulting optimal routing and wavelength assignment problem is proven to be NP-complete. To produce suboptimal solutions in polynomial time, a heuristic technique is presented, which makes use of a time-efficient method to estimate the end-to-end circuit availability in the presence of multiple (link and node) failures. Using the proposed heuristic, a selection of representative OXC architectures and optical switching technologies is examined to assess the influence of the node equipment choice on the overall network performance.     

Multi layer structure for encapsulation of organic transistors

A novel encapsulation structure to protect organic thin film transistors against oxygen and moisture contaminations is presented. The sealing architecture is comprised of three-layers: aluminum oxide deposited by means of Atomic Layer Deposition is the actual capping layer, while cross-linked poly-vinylphenol and poly-vinylphenol prevent the contamination/damage of the underlying organic semiconductor during the oxide growth. The process has negligible impact on device mobility but it enables poly-3-hexylthiophene based transistors to operate with an on/off ratio in excess of 10³ even after 100 days of continuous ambient air exposure.     

Slot Routing as a Solution for Optically Transparent Scalable WDM Wide Area Networks*

All-optical Wavelength Division Multiplexing (WDM) backbones are believed to be a fundamental component in future high speed networks. Currently, the most pursued approach for Wide Area Networks (WANs) is wavelength routing, in which communication circuits are established between node pairs by means of lightpaths (paths of light) spanning one or more fiber-optic links. This approach has, however, two drawbacks. Since the number of wavelengths and links in a network is finite, not all node pairs can be connected via a dedicated lightpath directly. Consequently, some node pairs will communicate using a concatenation of lightpaths, which requires electronic switching of in transit information, loosing the advantages of optical transparency. Secondly, typically some form of (electronic) traffic grooming will be necessary to make efficient use of the fixed lightpath capacity. This paper proposes to design all-optical WANs using a novel approach, called photonic slot routing. With photonic slot routing, entire slots, each carrying multiple packets on distinct wavelengths, are switched transparently and individually, using available fast and wavelength non-sensitive devices. The advantage of using photonic slot routing is threefold. All node pairs in the network communicate all-optically. Traffic aggregation necessary to efficiently use the capacity of the wavelength channels is optically achieved. The solution is practical as it is based on proven optical technologies. In addition, through the use of wavelength non-sensitive devices the proposed WAN design yields intrinsic scalability in the number of wavelengths.     

The multi-hop multi-rate wavelength division multiplexing ring

Transparency of the optical layer offers the possibility to design a network that operates at varying transmission bit rates. While variable bit rate interfaces are being tested and will soon provide the possibility to optimally select the transmission rate for each optical channel, the potential advantages of relying upon multiple transmission rates in the optical network have yet to be fully explored. In this paper, we define the concept of multi-hop and multi-rate (M&M for short) network in which the tributary signal is transmitted over a concatenation of optical channels, with each optical channel operating at its own transmission rate. The optimal rate of each optical channel is determined by a number of factors including the end node's interface, amount of multiplexed traffic and cost of the network components. The potential advantages provided by the M&M network when compared to first generation optical networks (i.e., SONET/SDH), to single- and multi-hop (constant bit rate) optical networks, are discussed in general and demonstrated numerically in a WDM ring. Presented results show that the network cost reduction achieved by the M&M design is a function of the cost ratio between the optical bandwidth (wavelengths) and the optical terminals     

Expression of AMPA and NMDA receptor subunits in the cervical spinal cord of wobbler mice

Background  

The localisation of AMPA and NMDA receptor subunits was studied in a model of degeneration of cervical spinal motoneurons, the wobbler mouse. Cervical regions from early or late symptomatic wobbler mice (4 or 12 weeks of age) were compared to lumbar tracts (unaffected) and to those of healthy mice.