Application of convolutional error correcting codes in ultrawideband M-ary PPM signaling

The interference issues related to ultrawideband (UWB) radio pose tight restrictions on the maximum data rate of UWB radio telecommunication systems. A possible solution is to reduce the required signal to interference ratio (SIR) that gives satisfactory performance to the UWB system. In this letter, we propose coded M-ary UWB radio communication systems. Two classes of convolutional codes, namely, low-rate superorthogonal codes and high-rate punctured codes are considered for this purpose. Simulation results on the bit error rate of the proposed system indicates that the system is capable to work in lower SIR's and therefore supports higher data transmission rates in a real interference environment compared to the previously proposed UWB communication systems.     

Frame time-hopping patterns in multirate optical CDMA networks using conventional and multicode schemes

A class of generalized optical orthogonal codes (OOCs), namely, frame time-hopping (FTH) patterns with an extremely large cardinality, are studied for implementing multirate and multiservice (MR/MS) optical CDMA (OCDMA) networks. Conventional MR/MS methods, namely variable spreading rate and parallel mapping, are considered. Using FTH patterns, the problem of low OOC code cardinality in conventional MR/MS schemes is removed. Moreover, several new multicode methods, using subcode concatenation scheme, are proposed for MR/MS OCDMA. The proposed multicode schemes present flexibility for supporting MR/MS applications such as lower implementation complexity and cost, less need for service synchronization, and finally lower link power budget. Multiple-access performances of the systems are evaluated using saddle-point approximation methods considering photodetector shot-noise, dark current, and circuit thermal noise. The results show that the conventional parallel mapping outperforms the other schemes in high received powers, and the proposed multicode method, using Walsh subcode along with difference modulation, presents the best performance in low received powers for the cases considered.     

Determination of pKa values for (E)-2-hydroxy-5-(aryldiazenyl) benzaldehydes in dimethyl sulfoxide: Cyclic voltammetry and density functional theory calculations

The (E)-2-hydroxy-5-(aryldiazenyl) benzaldehydes (azo dyes 1–4 ) were synthesized in high purity. As they are insoluble in water, the usual analytical methods cannot be utilized to determine their pK_a values. Cyclic voltammetry was experimentally used to determine their pKa values in DMSO solvent. In addition, computational methods and a conductor-like screening model (COSMO) were used to calculate the solvent effect. , , K_exchange, and pK_a values were estimated for the azo dyes being studied using the BP86, TPSS, B3LYP, PBE0, TPSSh, and PW6B95 density functionals in def2-TZVP basis sets. The obtained mean absolute deviations (MADs) indicate that the results of BP86, PBE0, and PW6B95 functionals are in good agreement with experimental values.     

Effects of Thermally Induced Roton-Like Excitation on the Superfluid Density of a Quasi-2D Dipolar Bose Condensed Gas

Using the Green's function approach, the density–density correlation function and the dielectric function in the random-phase approximation for a quasi-two-dimensional (quasi-2D) dipolar Bose gas are derived. From the pole of the density correlation function, by considering thermally induced roton-like excitations, the excitation spectrum of the system is calculated. It is shown that the position and depth of the roton minimum of the excitation spectrum are tunable by changing the temperature. To show how the position of the roton minimum influences the phenomenon of superfluidity, the superfluid density of the system is obtained and it is shown that the interplay of the thermal rotonization, contact and dipole–dipole interaction (DDI) can affect the superfluid fraction of a quasi-2D Bose gas. It is found that contact, DDI interactions, and thermally induced rotons enhance the fluctuations and reduce the superfluid density. In the absence of DDI and thermally induced rotons, the usual T³ dependence of superfluid density in 2D is obtained and the correction T⁴ term arises from DDI. It is shown that if the roton minimum is close to zero, the thermally induced rotons change the linear temperature dependence of the superfluid fraction, leading to a transition to nontrivial supersolid phase.     

Synthesis and Characterization of Novel Poly-thiophene-nanoporous Silica and its Application for Mercury Removal from Waste Waters

In this work, MCM-41 (Mobil Composition of Matter number 41) nanoporous silica has been synthesized and characterized by X-ray powder diffraction and IR spectroscopy. In the next step, poly-thiophene was coated on the nanoporous silica in order to increase its surface area. This composite was characterized by X-Ray powder diffraction, High resolution transmission electronic microscopy micrograph (HRTEM), elemental analysis (CHNS) and Thermal analysis (TG/DTA). The application of this composite was investigated in mercury ions removal from waste water prior to determination by inductively coupled plasma atomic emission spectroscopy (ICP-OES). In order to investigate the effect of nanoporous structure on the efficiency of this composite, the same composite without porous structure has been synthesized and the results were compared.     

Frame time-hopping fiber-optic code-division multiple access using generalized optical orthogonal codes

A new spreading technique for intensity modulation direct detection fiber-optic code-division multiple-access (FO-CDMA) communication systems is proposed. This new spreading technique is based on generalized optical orthogonal codes (OOC) with large cardinality and minimal degradation in performance when compared with a more optimum system, namely, an optical CDMA system using OOC with autocorrelation and cross-correlation value bounded by one, i.e., OOC (/spl lambda/=1). To obtain the performance of such systems, we use a communication scheme, namely, frame time-hopping (FTH)-CDMA with random coding. Systems with generalized OOC patterns and random time-hopping coding are close in structure and performance. Furthermore, the performance of such systems is near the performance of optical CDMA with optimum but low cardinality OOC (/spl lambda/=1), which further renders the practicality of the proposed technique with very large cardinality. Two new receiver structures for FO-CDMA, namely, chip-level detector with optimum comparator threshold and correlation receiver with an electrical hard limiter, are also proposed. The performance analysis for a binary pulse position FTH-FO-CDMA network is considered for the correlation receiver, chip-level detector, correlation receiver with an optical hard limiter, optimum receiver, and the two newly proposed receiver structures. The results also show that a chip-level detector with optimum comparator threshold is superior to a chip-level detector for received low signal powers, and predict that the performance of the correlation receiver with an electrical hard limiter is superior to all other considered receiver structures, e.g., requiring one third of transmission power to achieve a desired bit error rate when compared with other receiver structures.     

Traffic of leukocytes in microfluidic channels with rectangular and rounded cross-sections

Traffic of leukocytes in microvascular networks (particularly through arteriolar bifurcations and venular convergences) affects the dynamics of capillary blood flow, initiation of leukocyte adhesion during inflammation, and localization and development of atherosclerotic plaques in vivo. Recently, a growing research effort has been focused on fabricating microvascular networks comprising artificial vessels with more realistic, rounded cross-sections. This paper investigated the impact of the cross-sectional geometry of microchannels on the traffic of leukocytes flowing with human whole blood through a non-symmetrical bifurcation that consisted of a 50 μm mother channel bifurcating into 30 μm and 50 μm daughter branches. Two versions of the same bifurcation comprising microchannels with rectangular and rounded cross-sections were fabricated using conventional multi-layer photolithography to produce rectangular microchannles that were then rounded in situ using a recently developed method of liquid PDMS/air bubble injection. For microchannels with rounded cross-sections, about two-thirds of marginated leukocytes traveling along a path in the top plane of the bifurcation entered the smallest 30 μm daughter branch. This distribution was reversed in microchannels with rectangular cross-sections--the majority of leukocytes traveling along a similar path continued to follow the 50 μm microchannels after the bifurcation. This dramatic difference in the distribution of leukocyte traffic among the branches of the bifurcation can be explained by preferential margination of leukocytes towards the corners of the 50 μm mother microchannels with rectangular cross-sections, and by the additional hindrance to leukocyte entry created by the sharp transition from the 50 μm mother microchannel to the 30 μm daughter branch at the intersection. The results of this study suggest that the trajectories of marginated leukocytes passing through non-symmetrical bifurcations are significantly affected by the cross-sectional geometry of microchannels and emphasize the importance of using microfludic systems with geometrical configurations closely matching physiological configurations when modeling the dynamics of whole blood flow in the microcirculation.     

Flow irregularity and wear optimization in epitrochoidal gerotor pumps

The Gerotor pumps have a vast number of applications in industries and automobiles. The flow rate irregularity and wear rate proportional factor influence on the lifetime of the Gerotor pumps. In this paper, the optimization problem cost functions and constraints have been developed according to volumetric, dynamic and geometric properties. In order to have general optimum solution and reduce number of design variables, all variables have changed to non-dimensional variables by using the outer rotor lobe center radius which causes the non-dimensional cost functions too. The multi-objective optimization problem has been changed to single objective optimization problem by using a multi-objective optimization classical method. The single objective optimization problem has been solved by using of a mixed integer nonlinear optimization algorithm. The optimization programming has been implemented for several values of number of the outer rotor teeth, non-dimensional displacement and rotors width. On the other hand the influence of varied parameter such as number of outer rotors teeth, the value of non-dimensional displacement and non-dimensional rotor width have been surveyed on each of cost functions. The results show in constant input torque, as using greater number of outer rotor teeth up to critical value improves the wear of teeth. Also optimum value of flow rate irregularity in odd values of outer rotor teeth is smaller than even ones. At last for having better comparison, two sample commercial pumps have been optimized. The results show both wear rate proportional factor and flow irregularity have been significantly improved.