Kinetic study of oxidative coupling of methane over Mn and/or W promoted Na_2SO_4/SiO_2 catalysts

A comprehensive kinetic model for oxidative coupling of methane(OCM)over Mn and/or W promoted Na2SO4/SiO2 catalysts was developed based on a micro-catalytic reactor data.The methane conversion and ethylene,ethane,carbon monoxide and carbon dioxide selectivities were obtained in a wide operating condition range of 750 - 825-C,CH4/O2=2.5 - 10 and contact time=267 - 472 kg s m-3.Reaction networks of six models with different rate equation types were compared together.The kinetic rate parameters of each reaction network were estimated using linear regression or genetic algorithm optimization method(GA).A reaction network suggested by Stansch et al.for OCM was found to be the best one and was further used in this work.The suggested model could predict the experimental results of OCM reaction within a deviation range of ± 20%.     

Blind separation of image sources via adaptive dictionary learning

Sparsity has been shown to be very useful in source separation of multichannel observations. However, in most cases, the sources of interest are not sparse in their current domain and one needs to sparsify them using a known transform or dictionary. If such a priori about the underlying sparse domain of the sources is not available, then the current algorithms will fail to successfully recover the sources. In this paper, we address this problem and attempt to give a solution via fusing the dictionary learning into the source separation. We first define a cost function based on this idea and propose an extension of the denoising method in the work of Elad and Aharon to minimize it. Due to impracticality of such direct extension, we then propose a feasible approach. In the proposed hierarchical method, a local dictionary is adaptively learned for each source along with separation. This process improves the quality of source separation even in noisy situations. In another part of this paper, we explore the possibility of adding global priors to the proposed method. The results of our experiments are promising and confirm the strength of the proposed approach.     

Estimative current mode control technique for DC-DC converters operating in discontinuous conduction mode

A new control technique for DC-DC converters is introduced and applied to a boost converter operating in discontinuous conduction mode (DCM). In contrast to conventional control methods, the principal idea of the proposed control scheme is to obtain samples of the required signals and estimate the required switch-on time. The proposed technique is applicable to any converter operating in DCM, including power factor correctors (PFC), however, this letter mainly focuses on boost topology. In this letter, the main mathematical concept of a new control algorithm is introduced, as well as the robustness investigation of the proposed method with simulation and experimental results.     

Pulse regulation control technique for flyback converter

Pulse regulation, a fixed frequency control technique, is introduced and applied to flyback converter operating in discontinuous conduction mode (DCM). The control parameters are designed in a way that the converter operates as close as possible to the critical conduction mode. In contrast to the conventional pulsewidth modulation control scheme, the principal idea of pulse regulation is to achieve output voltage regulation using high and low-power pulses. Pulse regulation is simple, cost effective, and enjoys a fast dynamic response. The proposed technique is applicable to any converter operating in DCM. However, this work mainly focuses on flyback topology. In this paper, the main mathematical concept of the new control algorithm is introduced and simulations as well as experimental results are presented.     

Pulse Train control technique for flyback converter

Pulse Train/spl trade/ control technique is introduced and applied to flyback converter operating in discontinuous conduction mode (DCM). In contrast to the conventional pulse width modulation (PWM) control scheme, the principal idea of Pulse Train is to achieve output voltage regulation using high and low power pulses. The proposed technique is applicable to any converter operating in DCM. However, this work mainly focuses on flyback topology. In this paper, the main mathematical concept of the new control algorithm is introduced and simulations as well as experimental results are presented.     

Application of a nanostructured supramolecular solvent for the microextraction of diphenylamine and its mono‐nitrated derivatives from unburned single‐base propellants

A supramolecular solvent made up of nano‐sized inverted hexagonal aggregates of 1‐octanol is proposed for the microextraction of diphenylamine and its mono‐nitrated derivatives in unburned single‐base propellants. The procedure included the extraction of sub‐gram quantities (30 mg) of homogenized propellant with 1.5 mL of the supramolecular solvent. Several conditions affecting extraction efficiency, for example the concentrations of the major components of the supramolecular solvent (tetrahydrofuran and alkanol), alkanol type, solvent pH, and extraction time, were investigated and optimized. The main forces for the microextraction of analytes in the nanostructured supramolecular solvent include both dispersion and hydrogen bond interactions. This mixed‐mode mechanism resulted in high extraction efficiencies reaching low method detection limits (0.005–0.012 mg/g) without the need for extract evaporation. Under the optimum conditions, recoveries in samples ranged between about 82.6 and 98.7%. Compared to the reference method, the proposed method is simple and rapid, delivering accurate and precise results, and can be applied for routine determination of diphenylamine and its derivatives in propellants. The precision of the method, expressed as relative standard deviation, was about 4.3–10.9%.     

Current Sensing for Automotive Electronics—A Survey

Current sensing is widely used in power electronic applications such as dc-dc power converters and adjustable-speed motor drives. Such power converters are the basic building blocks of drivetrains in electric, hybrid, and plug-in hybrid electric vehicles. The performance and control of such vehicles depend on the accuracy, bandwidth, and efficiency of its sensors. Various current-sensing techniques based on different physical effects such as Faraday's induction law, Ohm's law, Lorentz force law, the magnetoresistance effect, and the magnetic saturation effect are described in this paper. Each technique is reviewed and examined. The current measurement methods are compared and analyzed based on their losslessness, simplicity, and ease of implementation.     

Double-Input DC–DC Power Electronic Converters for Electric-Drive Vehicles—Topology Exploration and Synthesis Using a Single-Pole Triple-Throw Switch

Hybridizing energy systems using storage devices has gained popularity in transportation and distributed electric power generation applications. Traditionally, several independent power electronic converters (PECs) were utilized in such practices. Due to their reduced part count, double-input (DI) PECs prove to be a promising choice in hybridizing energy systems. A few topologies for multi-input converters have been reported in the literature; however, there is no systematic approach to synthesize them. Furthermore, all possible topologies are not completely explored, and it is difficult to derive new converters from existing topologies. Therefore, in this paper, a systematic approach to derive DI converters by using a single-pole triple-throw switch as a building block is presented.      

Pulse regulation control technique for integrated high-quality rectifier-regulators

The pulse regulation control scheme is presented and applied to the boost integrated flyback rectifier/energy storage dc/dc (BIFRED) converter as the most popular member of the integrated high-quality rectifier-regulators (IHQRR). In contrast to the conventional control techniques, the principal idea of pulse regulation is to regulate the output voltage using a series of high- and low-power pulses generated by the current of the input inductor, which is operating in discontinuous conduction mode (DCM). Analysis of the BIFRED converter operating in DCM is presented. Fundamentals of pulse regulation as well as its stability analysis and the estimation of the output voltage ripple are introduced. Experimental results on a prototype converter are also presented to validate the analytical and simulation results.     

Theoretical study of metal‐free organic dyes based on different configurations for efficient dye‐sensitized solar cells

Considering different solar dyes configuration, four novel metal‐free organic dyes based on phenoxazine as electron donor, thiophene and cyanovinylene linkers as the ‐conjugation bridge and cyanoacrylic acid as electron acceptor were designed to optimize open circuit voltage and short circuit current parameters and theoretically inspected. Density functional theory and time‐dependent density functional theory calculations were used to study frontier molecular orbital energy states of the dyes and their optical absorption spectra. The results indicated that D2‐4 dyes can be suitable candidates as sensitizers for application in dye sensitized solar cells and among these three dyes, D3 showed a broader and more bathochromically shifted absorption band compared to the others. The dye also showed the highest molar extinction coefficient. This work suggests optimizing the configuration of metal‐free organic dyes based on simple D‐ ‐A configuration containing alkyl chain as substitution, starburst conformation, and symmetric double D‐ ‐A chains would produce good photovoltaic properties.