One-Pot Synthesis of Phenytoin Analogs

A series of phenytoin analogs (5,5-diphenylimidazolidine-2,4-dione or 5,5-diphenyl-hydantoin) were synthesized in 65–75% yield from the corresponding substituted benzils. The same products were also obtained directly from -hydroxy ketones via one-pot procedure.     

A 0.2-W Heterostructure Barrier Varactor Frequency Tripler at 113 GHz

We present a high-power InAlAs/InGaAs/InP heterostructure barrier varactor (HBV) frequency tripler. The HBV device topology was designed for efficient thermal dissipation and high efficiency. To verify simulations, the device was flip-chip soldered onto embedding microstrip circuitry on an aluminum nitride substrate. This hybrid circuit was then mounted in a waveguide block without any movable tuners. From the resulting RF measurements, the maximum output power was 195 mW at 113 GHz, with a conversion efficiency of 15%. The measured 3-dB bandwidth was 1.5%     

PSIM-based modeling of automotive power systems: conventional, electric, and hybrid electric vehicles

Automotive manufacturers have been taking advantage of simulation tools for modeling and analyzing various types of vehicles, such as conventional, electric, and hybrid electric vehicles. These simulation tools are of great assistance to engineers and researchers to reduce product-development cycle time, improve the quality of the design, and simplify the analysis without costly and time-consuming experiments. In this paper, a modeling tool that has been developed to study automotive systems using the power electronics simulator (PSIM) software is presented. PSIM was originally made for simulating power electronic converters and motor drives. This user-friendly simulation package is able to simulate electric/electronic circuits; however, it has no capability for simulating the entire system of an automobile. This paper discusses the PSIM validity as an automotive simulation tool by creating module boxes for not only the electrical systems, but also the mechanical, energy-storage, and thermal systems of the vehicles. These modules include internal combustion engines, fuel converters, transmissions, torque couplers, and batteries. Once these modules are made and stored in the library, the user can make the car model either a conventional, an electric, or a hybrid vehicle at will, just by dragging and dropping onto a schematic blank page.     

Modeling and analysis of multiconverter DC power electronic systems using the generalized state-space averaging method

This paper presents a modular approach for the modeling and simulation of multiconverter DC power electronic systems based on the generalized state-space averaging method. These systems may consist of many individual converters connected together to form large and complex systems. In addition to simplifying the analysis procedure, by using the proposed method, the time step for analysis of the system can be increased. Therefore, the required computation time and computer memory for complex systems can be reduced considerably. In this paper, after introducing the proposed approach, results of applying the method to a representative system are presented.     

Modeling of power electronic loads in AC distribution systems using the generalized State-space averaging method

Most of the loads in ac distribution systems have positive incremental impedance characteristic. However, power electronic loads, when tightly regulated, sink constant power from the system. Therefore, they have negative incremental impedance characteristic. This can cause negative impedance instability. Power electronic loads usually have a controlled or uncontrolled rectifier at the front end. In this paper, these loads are modeled using the generalized state-space averaging method. An assessment of their effects in ac distribution systems is also presented. Experimental results are presented to verify the proposed analysis.     

Loudness growth observed under partially tripolar stimulation: model and data from cochlear implant listeners

Most cochlear implant strategies utilize monopolar stimulation, likely inducing relatively broad activation of the auditory neurons. The spread of activity may be narrowed with a tripolar stimulation scheme, wherein compensating current of opposite polarity is simultaneously delivered to two adjacent electrodes. In this study, a model and cochlear implant subjects were used to examine loudness growth for varying amounts of tripolar compensation, parameterized by a coefficient sigma, ranging from 0 (monopolar) to 1 (full tripolar). In both the model and the subjects, current required for threshold activation could be approximated by I(sigma)=Ithr(0)(1-sigmaK), with fitted constants Ithr(0) and K. Three of the subjects had a "positioner," intended to place their electrode arrays closer to their neural tissue. The values of K were smaller for the positioner users and for a "close" electrode-to-tissue distance in the model. Above threshold, equal-loudness contours for some subjects deviated significantly from a linear scale-up of the threshold approximations. The patterns of deviation were similar to those observed in the model for conditions in which most of the neurons near the center electrode were excited.     

A coated wire-type lead(II) ion-selective electrode based on a phosphorylated calix[4]arene derivative.

The preparation of a lead-selective electrode based on 5,11,17,23-tetra-tert-butyl-25,26,27,28-tetrakis-(diphenylphosphinoylmethoxy)calix[4]arene (1) as an ionophore is reported. The plasticized PVC membrane containing 30% PVC, 57% ortho-nitrophenyloctylether (NPOE), 4% sodium tetraphenylborate (NaTPB) and 9% ionophore 1 was directly coated on a graphite electrode. It exhibits a nearly Nernstian slope of 28.0 +/- 0.2 mV decade(-1) over a concentration range of 1 x 10(-5) - 1 x 10(-2) mol dm(-3) with a detection limit of 1.4 x 10(-6) mol dm(-3). The response time of the electrode was found to be ca. 17 s. The potential of the sensor was independent of the pH variation in the range 3.5 - 5.0. The selectivity of the electrode performance towards lead ions over Th4+, La3+, Sm3+, Dy3+, Y3+, Ca2+, Sr2+, Cd2+, Mn2+, Zn2+, Ni2+, Co2+, NH4+ Ag+, Li+, Na+ and K+ ions was investigated. The prepared electrode was used successfully as an indicator electrode for a potentiometric titration of a lead solution using a standard solution of EDTA. The applicability of the sensor for Pb2+ measurements in various synthetic water samples spiked with lead nitrate was also checked.     

Four-quadrant position sensorless control in SRM drives over the entire speed range

Proper synchronization of the excitation with respect to the rotor position is essential in optimal control of switched reluctance motor (SRM) drives. To avoid additional cost, size, and unreliability caused by the external position sensors, magnetic status of the SRM can be directly monitored to detect commutation instants. A one-to-one correspondence between magnetic status of the SRM and rotor position removes the need for an explicit access to the rotor position. In order to obtain a good precision over the entire speed range, educated modifications on the structure of the sensorless strategy is necessary. This is due to the impact of the operational regions on dynamic behavior of the SRM. In addition, introduction of SRM technology to industrial and domestic applications has raised the need for four-quadrant operation of the SRM drives. The present paper introduces a range of strategies that are necessary to accommodate this requirement in a sensorless format. Our experimental findings indicate that high-grade sensorless operation in a four-quadrant SRM drive is possible and can be integrated in a variety of applications.     

Making the case for applications of switched reluctance motor technology in automotive products

Switched reluctance machines (SRM) offer attractive attributes for automotive applications. These include robustness to harsh operational conditions, rugged structure, fault resilient performance, and a wide range of speed. The main debate over the adequacy of switched reluctance drives in automotive applications has often focused on efficiency and position sensorless control over the entire speed range, adaptation of control algorithms in the presence of parameter variations, and high levels of acoustic noise and vibration. The present paper demonstrates three key technologies developed over the past few years that have resulted in tangible improvements in the performance of SRM/generators (SRM/G) as related to the above areas of interest. This paper intends to illustrate the new possibilities and remaining challenges in applications of SRM in automotive industry. The proposed technologies have been validated by simulation and experimental results.