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1.
Efficient synthesis of ferrocenylenones using a Friedel-Crafts acylation reaction is described. Acryloyl, methacryloyl, crotonoyl, cinnamoyl, and β-methylcrotonoyl chlorides react with ferrocene in the presence of a Lewis acid (EtAlCl2 or EtAlCl2-Me3Al) to give the corresponding ferrocenylenones (acryloyl, methacryloyl, crotonoyl, cinnamoyl, and methylcrotonoylferrocenes) in good isolated yields. Besides ferrocenylenones, chloroactylferrocene is also synthesised by this method. 相似文献
2.
Barbara Dogan Hans-Dieter Beckhaus Hermann Birkhofer Christoph Rüchardt 《欧洲无机化学杂志》1990,123(6):1365-1368
Effects of Substituents on the Strength of C - C Bonds, 81. - Heats of Formation and Strain of 1,1,2,2-Tetraethylethylene Glycol Dimethyl Ether and D,L .-1,2-Dimethyl-l,2-diphenylethylene Glycol Dimethyl Ether The heats of combustion of the title compounds 1 and 2 were measured calorimetrically with the result (kcal mol -1, s. d. in parentheses) ΔH°c = − 1880.1 (± 0.6) and − 2373.3 (± 1.4). The heat of vaporisation of 1 ΔHv = 14.3 (± 0.3) and the heat of sublimation of 2 ΔHsub = 27.2 (± 0.5) were derived from their temperature dependance of the vapor pressure. The latter were determined between 30 and 80°C using a flow method. The resulting standard heats of formation ΔH°t(g) = −122.4 (± 0.7) and −43.8 (±1.5) for 1 and 2 correspond to a strain enthalpy (s) of 15.9 and 8.0 kcal mol-1, respectively. The steric strain of the dimethoxyethanes 1 and 2 is about one fourth lower than the strain of the corresponding dimethylethanes 3 and 4 bearing the same substituents. Thus, a methoxy group causes less steric stress than a methyl group. 相似文献
3.
Conditions influencing the extent of P-C(aryl) vs P-C(alkyl) bond cleavage in the reaction of Ph(2)P(CH(2))(2)PPh(2) with lithium in THF have been investigated. The results complement and elucidate earlier work; they indicate that the mechanism of P-C bond cleavage in tertiary phosphines of this type involves a thermodynamic equilibrium between P-C(aryl) and P-C(alkyl) cleaved radicals and anions, followed by reaction and stabilization of these as lithium salts. The addition of water to the reaction mixture causes a reestablishment of the cleavage equilibrium prior to the formation of the secondary phosphines. A mechanism involving competitive release of leaving groups as the thermodynamically most stable anion or radical has been proposed. The preparation of (R, R)-(+/-)/(R, S)-PhP(H)(CH(2))(2)P(H)Ph by this route has been optimized. 相似文献
4.
5.
In many wireless sensor network (WSN) applications, the location of a sensor node is crucial for determining where the event or situation of interest occurred. Therefore, localization is one of the critical challenges in WSNs. Mobile anchor node assisted localization (MANAL) is one of the promising solutions for the localization of statically deployed sensors. The main problem in MANAL localization is that the path planning of the mobile anchor (MA) node should be done so that the localization error in the network will be minimal and that all unknown nodes in the network are covered. This paper proposes a new path planning approach called nested hexagons curves (NHexCurves) for MANAL. NHexCurves guarantees that it will receive messages from at least three non-collinear anchors to locate all unknown nodes in the network. The proposed model has compared six different path planning schemes in the literature using weighted centroid localization (WCL). In these comparisons, first of all, localization errors of the models are compared using some statistical concepts. Second, the variation of the localization error according to parameters such as resolution (R) and the standard deviation of noise (σ) is observed. Then, with similar approaches, the standard deviation of errors, localization ratio, scalability performances, and finally, path lengths of the models are examined. The simulation results show that the NHexCurves static path planning model proposed in this study stands out compared to other models with high localization error and localization ratio performance, especially at low resolutions, due to its path design. At the same time, the lowest error values according to σ are obtained with the proposed model among all models considered. 相似文献
6.
Savas Lemiye Atabek Arslan Cagrialp Hacioglu Fırat Dogan Mehmet 《Journal of Thermal Analysis and Calorimetry》2018,134(3):1657-1666
Journal of Thermal Analysis and Calorimetry - In the current study, huntite and hydromagnesite (HH) was used as flame-retardant additive in linear low-density polyethylene (LLDPE). The effect of HH... 相似文献
7.
The aldol reactions of 2‐arylimino‐3‐aryl‐thiazolidine‐4‐ones with benzaldehyde carried out at ?78 °C were found to produce sec‐carbinols. Intramolecular hydrogen bonding within the aldol products forming a six‐membered ring enabled the assignment of stereochemistries of the major and minor diastereomers via analysis of the syn and anti 3JH,H 1H NMR coupling constants. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
8.
Hilal Goktas Dogan Mansuroglu Betul Atalay Sinan Bilikmen Ismet Kaya 《Plasma Chemistry and Plasma Processing》2012,32(1):35-44
The synthesis of polyfluorene (PF) thin films by simultaneously superposing a continuous and pulsed discharge and the characterizations
of these samples are presented. The double discharge plasma system is constructed by superposing two discharges; namely, a
low pressure dc glow one and a high current pulsed one. The fluorene monomer in powder form was vaporized in the system at
argon plasma without any modification, at 0.5 mbar operating pressure. The structure of the thin films was investigated via
XPS, UV–visible, FTIR, XRD and SEM. The FTIR and the UV–visible results revealed that the fluorene structure was retained
at the produced samples. Semi-conducting behavior was established, and upon the iodine doping, the optical energy band gap
(E
g
) dropped down from 3.7 to 2.4 eV. The morphology of the synthesized PF thin films was amorphous, with granular structures
of different sizes depending on the location of the substrate. 相似文献
9.
J. D. Theis S. Dasari J. A. Vrana P. J. Kurtin A. Dogan 《Journal of mass spectrometry : JMS》2013,48(10):i-i
Shotgun proteomics technology has matured in the research laboratories and is poised to enter clinical laboratories. However, the road to this transition is sprinkled with major technical unknowns such as long‐term stability of the platform, reproducibility of the technology and clinical utility over traditional antibody‐based platforms. Further, regulatory bodies that oversee the clinical laboratory operations are unfamiliar with this new technology. As a result, diagnostic laboratories have avoided using shotgun proteomics for routine diagnostics. In this perspectives article, we describe the clinical implementation of a shotgun proteomics assay for amyloid subtyping, with a special emphasis on standardizing the platform for better quality control and earning clinical acceptance. This assay is the first shotgun proteomics assay to receive regulatory approval for patient diagnosis. The blueprint of this assay can be utilized to develop novel proteomics assays for detecting numerous other disease pathologies. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
10.
Surface tensions of some Pb-free solder systems such as Ag–Bi–Sn with cross-sections Ag/Bi = 1/1, Ag/Bi = 1/2, Ag/Bi = 2/1, In–Sn–Zn with cross-sections Sn/In = 1/1, Sn/In = 1/3 and (Ag7Cu3)100?x Snx with cross-section Ag/Cu = 7/3 are calculated from the sub-binary surface tension data using the models, such as the Muggianu, Kohler, Toop models, Butler’s equation and Chou’s General Solution Model (GSM) at 873, 923 and 1073 K, respectively. The surface tension of In–Sn–Zn increases wavily with increasing amount of Zn and it is found that the best models are the GSM for both cross-sections in question while GSM becomes the best model for (Ag7Cu3)100?x Snx alloy in the whole experimental range. Moreover, the surface tension of (Ag7Cu3)100?x Snx decreases slightly with increasing amount of Sn. The Muggianu, Butler and Butler models are determined as the best models for the cross-sections in the order given above for entire measurement range, respectively, and the surface tension of Ag–Bi–Sn decreases slightly with an increasing amount of Bi and Ag but increases with increasing Sn in liquid alloys. 相似文献