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Spontaneous vesicle formation was observed in aqueous mixtures of partially hydrolyzed polyacrylamide and single-tailed cationic surfactants. The influences of pH, addition of long-chain alcohols, variation of hydrocarbon chain length, and head group size of the cationic surfactants were investigated systematically. It was found that 30-50% hydrolyzed degree of polyacrylamide and cationic surfactants with 10 or 12 methylene groups are suitable for vesicle formation in the mixed aqueous systems at pH 9.2. Addition of long-chain alcohols was found to be helpful for vesicle formation in some cases. The vesicle stability was also investigated at various temperatures and amounts of ethanol addition. Copyright 2001 Academic Press. 相似文献
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Dibenzyl sulphones can be prepared from the corresponding benzyl halide under mild, economic and efficient conditions, using either sodium dithionite / Aliquat, or sodium formaldehyde sulphoxylate /potassium carbonate in the absence of solvent. 相似文献
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By J. W. WHITE ZHU PENG-WEI J. E. EPPERSON D. WOZNIAK R. G. SNYDER 《Molecular physics》2013,111(6):1017-1024
Isotopic sensitivity is reported in both the formation and the above ambient temperature annealing behaviour of lamellar microphases in C30:C36 paraffin solid solutions. The time resolved small angle neutron scattering from a 1:1 C30H62:C36D74 mixture and its complementary pair 1:1 C D :C H has been studied. Upon quenching such mixtures from the melt; the solid solution so formed nucleates spontaneously to a ‘long period’ microphase. The two systems differ in that for 1:1 C30D62:C36H74 there is also strong diffraction at Q = 0·136 A-1 associated with C36H74 enrichment of the solid solution or a separate phase. Both processes are sensitive to the isotopic composition of the mixture. For both systems the long period scattering from a quenched liquid mixture develops in periods of hours at ambient temperature. Heating the aged microphase structures to temperatures above about 43°C causes them to disappear, but again isotropic sensitivity is noted. It is concluded that the effects are largely kinetic in origin, in agreement with earlier IR studies on intralamellar microaggregation in this system. 相似文献
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We derive a class of localized solutions of a 2+1 nonlinear Schrödinger (NLS) equation and study their dynamical properties. The ensuing dynamics of these configurations is a superposition of a uniform, "center of mass" motion and a slower, individual motion; as a result, nontrivial scattering between humps may occur. Spectrally, these solutions correspond to the discrete spectrum of a certain associated operator, comprised of higher-order meromorphic eigenfunctions. 相似文献
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ISO 14644-1洁净室空气洁净度等级标准的特点 总被引:2,自引:0,他引:2
对洁净室空气洁净度等级标准的国际标准ISO14644—1与美国标准FS209E的主要不同点进行列举并对IS014644—1在等级依据公式及表达格式方面的特点进行对比分析。 相似文献
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介质阻挡放电与脉冲电晕放电净化气态污染物的试验研究 总被引:5,自引:0,他引:5
利用自行研制的介质阻挡及脉冲电晕放电低温等离子体发生器对空气中氨、硫化氢、甲苯等5种气态污染物进行净化,并探讨了两种放电方式的原理和特点。试验结果表明:与介质阻挡放电相比,脉冲电晕放电具有更好的净化效果。 相似文献
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