UV radiation was applied to degrade cyanobacterial hepatotoxin, microcystin-LR in the presence of phycocyanin as a model natural sensitiser. The concentrations of both the toxin and the pigment used in the experiments were higher by several orders of magnitude than found in the environment. The photoreaction parameters were optimised. The process was found to be of limited use for water treatment due to its low efficacy. Additionally, pronounced UV-induced bleaching of the pigment significantly reducing the photoreaction rates of the toxin was observed for the highest UV radiation intensities applied. 相似文献
By using specific subsequences of two different types of generalized Stern polynomials, we obtain several related classes of finite and infinite continued fractions involving a single term \(z^{t^j}\) in their partial numerators, where z is a complex variable and t is a positive integer. This approach is extended to other, sparser, subsequences of Stern polynomials, based on certain Lucas functions; this then leads to further infinite classes of continued fractions. 相似文献
The oxidation of aniline with silver nitrate in 1 mol L−1 acetic acid at 20 °C yielded a composite of two conducting components, polyaniline and silver; the acceleration with 1 mol% of p-phenylenediamine is needed for efficient synthesis. The yield and molecular weight increased when aniline was copolymerized with 10 mol% p-phenylenediamine. Such product displayed metallic conductivity below 180 K and semiconductor type above this temperature. As the result, the conductivity was the same at 100 and 300 K. The oxidation of p-phenylenediamine alone with silver nitrate also produced a conducting composite having the conductivity of 1,750 S cm−1 despite the assumed nonconductivity of poly(p-phenylenediamine). The present study demonstrates that all oxidations proceeded also in frozen reaction mixtures at −24 °C, i.e., in the solid state. In most cases, molecular weights of polymer component increased, the conductivity of composites with silver improved, to 2,990 S cm−1 for poly(p-phenylenediamine)–silver, and remained high after deprotonation with 1 mol L−1 ammonium hydroxide.
The Quantitative Property-Retention Relation (QPRR) approach was applied to analyze the correlations between the retention parameters of ampholytic, biologically active substances and their physicochemical (predicted/spectral) characteristics. The retention parameters were obtained for polar and semipolar HPLC columns at various compositions of mobile phases and pH conditions. These values are a unique collection of chromatographic parameters that are a measure of lipophilicity and, consequently, can be very helpful in assessing pharmacological potency of the compounds investigated. Three QPRR models that meet the predictive capability criteria were developed. The relationships can be used to gain pharmacologically interesting information on the biologically active ampholytic substances.
Lipophilicity is a very important property of chemical compound taking into consideration in drugs design. Relationships between biological activity, among others lipophilicity, and chemical structure (QSAR) of the compound are very often used by researches. Especially important is the kind of substituents connected to the basic structural fragment and how it changes the lipophilicity of the compound. The aim of this study was to determine the parameters of lipophilicity of quinobenzothiazine derivatives using reversed phase - thin-layer chromatography (RP-TLC), which would enable one to determine the structure–activity relationship. The objective of our work is a series of 15 newly synthetized quinobenzothiazines. They were analyzed by thin-layer chromatography (TLC) with the use of two different mobile phases consisting of methanol or acetone as organic modifiers. For all compounds investigated, the values of lipophilicity obtained from computational method were also determined. Cluster analysis was carried out too for all data of lipophilicity obtained. Low correlation was found between values of experimental lipophilicity and lipophilicity from computational methods for newly synthetized compounds. 相似文献
Modern fuel-injected automobiles use an electronic engine control unit (ECU) that is programmed to ignite the air-fuel mixture in a way that maximizes the torque (TQ) and power output of the engine without compromising its reliability. The ECU achieves this by reading a base value from the primary ignition map (PIM) and then manipulating various other parameters to come up with the final solution. Each input into the final solution comes from a so-called map, which is a 3-D image that represents a set of all the possible values that each parameter can take on. In this paper, we develop a robust methodology using image processing techniques to optimize the PIM for automobiles. The techniques are used to compare, combine, manipulate, and reconstruct various maps. Experiments show that the process yields a gain of about 7 hp and a TQ of 15 ft middotlb measured at the wheels. 相似文献
JPC – Journal of Planar Chromatography – Modern TLC - Fatty acids from pentanoic to tricosanoic have been separated on RP-18 HPTLC plates, with and without concentrating zone, with... 相似文献