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1.
2.
Nanosized Fe0.2Ni0.8 particles were prepared by reducing their salts with sodium borohydride (NaBH4) in cationic water-in-oil (w/o) microemulsions of water/cetyl-trimethyl-amonium bromide (CTAB) and n-butanol/isooctane at 25 °C. According to the TEM and X-ray diffraction analyses, the synthesized particles were around 4–12 nm in size. Due to their nanodimensions, the particles had a primitive cubic (pc) structure rather than the body-centered cubic (BCC) structure of the bulk material. An examination of the synthesis from the reverse micelle reveals that the morphology of the iron–nickel alloy nanoparticles depends mainly on the microemulsion's composition. The magnetization of the nanoparticles was much lower than that of the bulk material, reflecting the influence of the nanodimensions on the particles’ magnetizations. 相似文献
3.
E. Liénard G. Ban J. Blieck D. Durand F. Duval X. Fléchard M. Herbane M. Labalme Y. Lemière F. Mauger A. Méry O. Naviliat-Cuncic D. Rodríguez J. C. Thomas 《Hyperfine Interactions》2006,172(1-3):29-33
We report on the status of the LPCTrap experiment, devoted to measure the β–ν angular correlation in the pure Gamow–Teller
decay of 6He. This measurement is motivated by the search for the presence of tensor type contributions to the weak interaction. The
6He ions are confined in a novel transparent Paul trap. The β particles and the recoil ions are detected in coincidence to
deduce the angular correlation parameter. The commissioning run performed in 2005 has given the proof of principle of this
experiment. Up to 105 coincidences were recorded during a second run in 2006. 相似文献
4.
本文根据光传输理论导出介导消光系数,折射率与介质电磁参数,光波频率,电偶极子浓度及迁移率等的关系,分析了光激发与增加气敏介质的氧吸附的规律,结合实验说明气敏薄膜的光学变化机制。 相似文献
5.
Hoang The Ban Kei Nishii Yasuo Tsunogae Takeshi Shiono 《Journal of polymer science. Part A, Polymer chemistry》2007,45(13):2765-2773
This article reports a synthetic method for a norbornene–ethylene–styrene (N‐E‐S) terpolymer, which has not been well investigated so far, via incorporation of styrene (S) into vinyl‐type norbornene–ethylene (N‐E) copolymers catalyzed by a substituted ansa‐fluorenylamidodimethyltitanium [Me2Si(3,6‐tBu2Flu)(tBuN)]TiMe2 catalyst ( I ) activated with a [Ph3C][B(C6F5)4]/Al(iBu)3 cocatalyst at room temperature in toluene. The resulting terpolymerization product contained the targeted N‐E‐S terpolymer and the contaminated homopolymers, which were then able to be completely removed by solvent fractionation techniques. While homopolystyrene was easily extracted by fractionation with methylethylketone as a soluble part, homopolyethylene and a trace amount of homopolynorbornene could be perfectly separated by fractionation with chloroform as insoluble parts. The detail characterizations of a chloroform‐soluble polymer with gel permeation chromatography, nuclear magnetic resonance, and differential scanning calorimetry analyses proved that it contained a true N‐E‐S terpolymer with long N‐E sequences incorporated with isolated or short styrene sequences. The homogeneity of the morphology together with a single glass transition temperature that proportionally decreased with the increase of the styrene contents indicated that the N‐E‐S terpolymer obtained in this work is a random polymer with an amorphous structure. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 2765–2773, 2007 相似文献
6.
Curran猜想的解答 总被引:2,自引:0,他引:2
本文确定了能作为有限群自同构群的P-群的最佳下最,彻底解决了Curran在1989年提出的关于此最佳下界的三个猜想。 相似文献
7.
高含量钒的钼钒磷杂多化合物的合成和性质研究 总被引:2,自引:0,他引:2
本工作改进了文献[4]报导的几种原料同时混合、加热煮沸合成的方法采用分步加入原料,控制反应温度、多次重结晶的方法合成了6、7、8个钒原子取代的钼钒磷杂多酸铵;并以铵盐为原料,用离子交换、冷冻分离和真空抽吸相结合的提纯方法制备了未见文献报导的相应的固体杂多酸;H5[PMo5V7O37.5]·xH2O,H6[PMo4V8O37.5]·xH2O。通过元素组成分析确定了它们的组成。这些杂多酸在水溶液、非水溶液中的电位滴定表明,杂多阴离子在分解前没有发生自电离、水解等情况,它们在水溶液中是稳定的。酸的碱度分别为5、5、6。通过纸上色谱实验,讨论了杂多酸的分解过程。由热重分析和溶解性实验得到它们的分解温度,本文还讨论了这些化合物的红外、紫外光谱,x光粉末衍射及极谱性质。光谱结果表明,它们可能具有Keggin结构,由导数脉冲极谱得到它们的峰电位。 相似文献
8.
9.
Hiroyuki Asanuma Sumie Gotoh Takeshi Ban Makoto Komiyama 《Journal of inclusion phenomena and macrocyclic chemistry》1997,27(3):259-264
Poly(2-vinyl-4,6-diamino-1,3,5-triazine) efficiently binds nucleic acid bases and nucleosides in water by using complementary hydrogen bonding. The binding activity decreases in the order: U, T > A C, G. The corresponding monomer shows virtually no activity, indicating a predominant role of polymer effect for the molecular recognition in water. 相似文献
10.
T. Suzuki M. Aida Y. Ban Y. Fujii M. Hara T. Mitsugashira 《Journal of Radioanalytical and Nuclear Chemistry》2003,255(3):581-583
The separation of trivalent actinides and lanthanides was studied by using newly developed tertiary pyridine-type anion-exchange resin embedded in silica beads. Chromatographic elution experiments were carried out by using a packed column of the new resin and methanol-hydrochloric acid solution as an effluent. We confirmed that the actinides were eluted well from the elution bands of lanthanides. Actinides and lanthanides were eluted according to the reverse order of their atomic number. 相似文献