ANT-colony based disjoint set assortment in wireless sensor networks

Wireless Networks - Wireless sensor network (WSN) consists of small sized devices containing different sensors to monitor physical, environmental and medical conditions during surveillance of...     

ROMBERG方法的改进

本文研究了全部根构成一个等比数列的多项式的性质，并将所得的结果用到数值积分的Ｒｏｍｂｅｒｇ方法＾「１」，得到了相应遥改进。     

A simplified proof of the representation of functionals of diffusions

A simple proof is given for the stochastic integral representation of a Fréchet differentiable functional of the paths of a given diffusion process. The proof begins when the functional depends on one coordinate, then passes to (by appropriate conditioning) a perhaps more difficult case—when the functional depends on a finite number of coordinates—and finally, by approximation, to the general case.     

Phenyliodine(III) Diacetate/I2-Mediated Domino Approach for Pyrrolo[1,4]Thiazines and 1,4-Thiazines by a One-Pot Morin Rearrangement of N,S-Acetals

An efficient domino transformation using a phenyliodine(III) diacetate (PIDA)/I₂ combination towards Morin 1,4-thiazine compounds has been developed starting from N,S-acetals. The latter leads to “one-step” regioselective methylene insertion without the need for traditional sulfoxide intermediates in good yields. The reaction involves easily accessible N,S-acetals obtained from cost-effective basic ketones and cysteamine as starting materials. This process ultimately leads to 1,4-thiazines related to natural product and fused derivatives necessary for further QSAR study.     

Concerning the maximum frequency limits of Gunn operators

The length of the transit region of a Gunn diode determines the natural frequency at which it operates in fundamental mode－the shorter the device, the higher the frequency of operation. The long-held view on Gunn diode design is that for a functioning device the minimum length of the transit region is about 1.5 μm, limiting the devices to fundamental mode operation at frequencies of roughly 60 GHz. The authors posit that this theoretical restriction is a consequence of limits of the hydrodynamic models by which it was determined. Study of these devices by more advanced Monte Carlo techniques, which simulate the ballistic transport and electron-phonon interactions that govern device behaviour, offers a new lower bound of 0.5 μm, which is already being approached by the experimental evidence shown in planar and vertical devices exhibiting Gunn operation at 0.6 μm and 0.7 μm. It is shown that the limits for Gunn domain operation are determined by the device length required for the transferred electron effect to occur(approximately 0.15 μm, which as demonstrated is largely field independent) and the fundamental size of the domain(approximately 0.3 μm). At this new length, operation in fundamental mode at much higher frequencies becomes possible－the Monte Carlo model used predicts power output at frequencies over 300 GHz.     

A Common Conformation of Stabilized Triphenyl Phosphonium Ylidic Diesters with Bulky Alkoxy Groups

The phosphonium ylidic diesters, methyl and ethyl isopropyl and, methyl and ethyl t-butyl triphenylphosphoranylidene malonates, 1a,b and 2a,b , respectively, have the syn-anti conformation in solution, as in the crystal, and the bulkier alkoxy group is oriented towards phosphorus. The ¹ H NMR spectra show that in 1a,b , the isopropyl group is oriented towards the face of a phenyl group, consistent with π shielding in the ¹ H signals, and examination of the ¹ H coupled ¹³ C NMR spectra allows assignment of the acyl carbon signals. Computed bond lengths and angles for isolated molecules are similar to those in the crystal, and the geometry and the NMR spectra indicate extensive ylidic resonance. Estimated partial atomic charges on the ester oxygens are more negative when they are oriented towards, rather than away from, phosphorus.