Fuzzy Good Congruences on Left Semiperfect Abundant Semigroups

Motivated by studying fuzzy congruences in groups, semigroups, and ordered semigroups, and as a continuation of N. Kuroki and Y. Tan's works in regular semigroups in terms of fuzzy subsets, in this article we introduce the notions of a fuzzy good congruence relation, a fuzzy cancellative congruence relation on abundant semigroups, and give some properties, and characterizations of fuzzy good congruences on such semigroups. Furthermore, we characterize fuzzy good congruences of left semiperfect abundant semigroups, and get sufficient and necessary conditions for an abundant semigroup to be left semiperfect.     

Energy efficient routing with delay guarantee for sensor networks

The paper presents a routing algorithm that maximizes the lifetime of a sensor network in which all data packets are destined for a single collection node. Lifetime is maximized by adjusting the number of packets traversing each node. The adjustment is carried out by transmitting over alternative routes. The first part of the paper assumes that the worst case delay resulting from energy efficient routing is less than the maximum tolerable value. Ignoring the delay constraint of the network, the routes are selected as the solution to a linear programming (LP) problem in which the objective is to maximize the minimum lifetime of each node. The solution is implemented in a centralized algorithm, and then approximated by an iterative algorithm based on least cost path routing, in which each step is implemented efficiently in a distributed manner. The second part of the paper incorporates delay guarantee into energy efficient routing by constraining the length of the routing paths from each sensor node to the collection node. Simulations reveal that the lifetime of the network increases significantly by optimal routing, and including delay constraint in energy efficient routing improves the network performance since the delay of the network keeps increasing as the delay constraint is relaxed beyond the value at which the optimal lifetime is achieved. Research supported by National Science Foundation under Grant CMS-0408627 and California Department of Transportation. Sinem Coleri Ergen received the BS degree in electrical and electronics engineering from Bilkent University, Ankara, Turkey, in 2000, and the M.S. and Ph.D. degrees in electrical engineering and computer sciences from University of California Berkeley (UCB), in 2002 and 2005. Since January 2006, she has been a postdoctoral researcher in electrical engineering at UCB. Her research interests are in wireless communications and networking with a current focus on energy efficient system design for sensor networks. She is a member of the Sensor Networks for Traffic Monitoring project at UCB. She received Regents Fellowship from University of California Berkeley in 2000. Pravin Varaiya is Nortel Networks Distinguished Professor in the Department of Electrical Engineering and Computer Sciences at the University of California, Berkeley. From 1975 to 1992 he was also Professor of Economics at Berkeley. From 1994 to 1997 he was Director of the California PATH program, a multi-university research program dedicated to the solution of Californias transportation problems. His current research is concerned with communication networks, transportation, and hybrid systems. He has taught at MIT and the Federal University of Rio de Janeiro. Varaiya has held a Guggenheim Fellowship and a Miller Research Professorship. He received an Honorary Doctorate from LInstitut National Polytechnique de Toulouse, and the Field Medal of the IEEE Control Systems Society. He is a Fellow of IEEE and a member of the National Academy of Engineering. He is on the editorial board of several journals, including “Discrete Event Dynamical Systems” and “Transportation Research—C”. He has co-authored three books and more than 250 technical papers. The second edition of “High-Performance Communication Networks” (with Jean Walrand) was published by Morgan-Kaufmann in 2000. “Structure and interpretation of signals and systems" (with Edward Lee) was published by Addison-Wesley in 2003. Varaiya is a member of the Board of Directors of Sensys Networks.     

Twin probes as a novel tool for the detection of single-nucleotide polymorphisms

Single-nucleotide polymorphisms (SNPs) are the most common form of DNA sequence variation. There is a strong interest from both academy and industry to develop rapid, sensitive and cost effective methods for SNP detection. Here we report a novel structural concept for DNA detection based on fluorescence dequenching upon hybridization. The so-called "twin probe" consists of a central fluorene derivative as fluorophore to which two identical oligonucleotides are covalently attached. This probe architecture is applied in homogeneous hybridization assays with subsequent fluorescence spectroscopic analysis. The bioorganic hybrid structure is well suited for sequence specific DNA detection and even SNPs are identified with high efficiency. Additionally, the photophysical properties of the twin probe were investigated. The covalent attachment of two single stranded oligonucleotides leads to strong quenching of the central fluorescence dye induced by the nucleobases. The twin probe is characterized by supramolecular aggregate formation accompanied by red-shifted emission and broad fluorescence spectra.     

New Weight Function for Adapting Handover Margin Level over Contiguous Carrier Aggregation Deployment Scenarios in LTE-Advanced System

Wireless Personal Communications - In this paper, an Adaptive Handover Margin algorithm based on Novel Weight Function (AHOM-NWF) is proposed through Carrier Aggregation operation in Long Term...     

Covalent Organic Framework‐Supported Molecularly Dispersed Near‐Infrared Dyes Boost Immunogenic Phototherapy against Tumors

Photodynamic therapy (PDT) mediated by near‐infrared (NIR) dyes is a promising cancer treatment modality; however, its use is limited by significant challenges, such as hypoxic tumor microenvironments and self‐quenching of photosensitizers. These challenges hamper its utility in inducing immunogenic cell death (ICD) and triggering potent systemic antitumor immune responses. This study demonstrates that molecular dispersion of NIR dyes in nanocarriers can significantly enhance their ability to produce reactive oxygen species and potentiate synergistic PDT and photothermal therapy against tumors. Specifically, NIR dye indocyanine green (ICG) can be spontaneously adsorbed to covalent organic frameworks (COFs) via π–π conjugations to prevent intermolecular stacking interactions. Then, ICG‐loaded COFs are ultrasonically exfoliated and coated with polydopamine (PDA) to construct a new phototherapeutic agent ICG@COF‐1@PDA with enhanced efficacy. In conjunction with ICG@COF‐1@PDA, a single round of NIR laser irradiation can induce obvious ICD, elicit antitumor immunity in colorectal cancer, and yield 62.9% inhibition of untreated distant tumors. ICG@COF‐1@PDA also exhibits notable phototherapeutic efficacy against 4T1 murine breast to lung metastasis, a spontaneous metastasis mode for triple‐negative breast cancers (TNBCs). Overall, this study reveals a novel nanodelivery system for molecular dispersion of NIR dyes, which may present new therapeutic opportunities against primary and metastatic tumors.     

Threshold collision-induced dissociation of diatomic molecules: a case study of the energetics and dynamics of O2- collisions with Ar and Xe

The energetics and dynamics of collision-induced dissociation of O2- with Ar and Xe targets are studied experimentally using guided ion-beam tandem mass spectrometry. The cross sections and the collision dynamics are modeled theoretically by classical trajectory calculations. Experimental apparent threshold energies are 2.1 and 1.1 eV in excess of the thermochemical O2- bond dissociation energy for argon and xenon, respectively. Classical trajectory calculations confirm the observed threshold behavior and the dependence of cross sections on the relative kinetic energy. Representative trajectories reveal that the bond dissociation takes place on a short time scale of about 50 fs in strong direct collisions. Collision-induced dissociation is found to be remarkably restricted to the perpendicular approach of ArXe to the molecular axis of O2-, while collinear collisions do not result in dissociation. The higher collisional energy-transfer efficiency of xenon compared with argon is attributed to both mass and polarizability effects.     

Photoelectron imaging study of the effect of monohydration on O2 - photodetachment

The photodetachment of the O(2)(-).H(2)O cluster anion at 780 and 390 nm is investigated in comparison with O(2)(-) using photoelectron imaging spectroscopy. Despite the pronounced shift in the photoelectron spectra, the monohydration has little effect on the photoelectron angular distributions: for a given wavelength and electron kinetic energy (eKE) range, the O(2)(-).H(2)O angular distributions are quantitatively similar to those for bare O(2)(-). This observation confirms that the excess electron in O(2)(-).H(2)O retains the overall character of the 2ppi(g) HOMO of O(2)(-). The presence of H(2)O does not affect significantly the partial wave composition of the photodetached electrons at a given eKE. An exception is observed for slow electrons, where O(2)(-).H(2)O exhibits a faster rise in the photodetachment signal with increasing eKE, as compared to O(2)(-). The possible causes of this anomaly are (i) the long-range charge-dipole interaction between the departing electron and the neutral O(2).H(2)O skeleton affecting the slow-electron dynamics; and (ii) the s wave contributions to the photodetachment, which are dipole-forbidden for pi(g)(-1) transitions in O(2)(-), but formally allowed in O(2)(-).H(2)O due to lower symmetry of the cluster anion and the corresponding HOMO.     

Collision-induced dissociation of HS-(HCN): unsymmetrical hydrogen bonding in a proton-bound dimer anion

The energy-resolved competitive collision-induced dissociation of the proton-bound complex [HS.H.CN](-) is studied in a guided ion beam tandem mass spectrometer. H(2)S and HCN have nearly identical gas-phase acidities, and therefore, the HS(-) + HCN and the CN(-) + H(2)S product channels exhibit nearly the same threshold energies, as expected. However, the HS(-) + HCN channel has a cross section up to a factor of 50 larger than CN(-) + H(2)S at higher energies. The cross sections are modeled using RRKM theory and phase space theory. The complex dissociates to HS(-)+ HCN via a loose transition state, and it dissociates to CN(-) + H(2)S via a tight transition state. Theoretical calculations show that the proton-transfer potential energy surface has a single minimum and that the hydrogen bonding in the complex is strongly unsymmetrical, with an ion-molecule complex of the form HS(-)..HCN rather than CN(-)..H(2)S or an intermediate structure. The requirement for proton transfer before dissociation and curvature along the reaction path impedes the CN(-) + H(2)S product channel.     

基于二阶循环统计量的MPSK信号频偏估计算法

本文利用接收信号(为二阶周期平稳信号)的二阶循环平稳特性推导了一种开环频偏估计算法,此算法的特点为:(1)接收信号为MPSK调制信号;(2)频偏估计过程不需要训练序列;(3)适用于任何分布的加性平稳噪声(白噪声及有色噪声)。文章对提出算法的性能进行了分析,并运用蒙特卡洛(MonteCarlo)方法对算法的性能进行仿真。     

Synthesis and anticonvulsant activity of some new arylidenehydrazides and 4-thiazolidinones

Summary A number of N,N-bis(arylidene)mono(1-methylpropyl)malonic acid dihydrazides (3a–c), 1,1-bis[[(2-aryl-4-thiazolidinone-3-yl)amino]carbonyl]-2-methylbutanes (4a–e), and 1,1-bis[[(3-alkyl/aryl-4-thiazolidinone-2-yl)hydrazono]carbonyl]-2-methylbutanes (6a–i) have been synthesized, characterized and evaluated for anticonvulsant activity. All tested compounds showed significant activity (10 to 60% protection) against pentylenetetrazole induced seizures.

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Synthese einiger neuer Arylidenhydrazide und 4-Thiazolidinone sowie Untersuchung ihrer krampflösenden Eigenschaften

Zusammenfassung Eine Reihe von N,N-Bis(aryliden)mono(1-methylpropyl)malonsäure dihydraziden, (3a–c), 1,1-Bis[[2-Aryl-4-thiazolidinon-3-yl)amino]carbonyl]-2-methylbutanen (4a–e) und 1,1-Bis[[3-alkyl/aryl-4-thiazolidinon-2-yl)hydrazono]carbonyl]-2-methylbutanen (6a–i) wurden hergestellt, charakterisiert und auf ihre antikonvulsive Wirkung geprüft. Alle getesteten Substanzen zeigen relevante Aktivitäten gegen durch Pentilentetrazol induzierte Krämpfe (10–60% Schutz).