Cu (II)‐β‐cyclodextrin complex stabilized on magnetic nanoparticles: A retrievable hybrid promoter for green synthesis of spiropyrans

The magnetic core of manganese ferrite (MnFe₂O₄) nanoparticles has a significant stability in comparison with ferrite (Fe₃O₄) nanoparticles. The unique supramolecular properties of β‐cyclodextrin (β‐CD), such as hydrophobic cavity, hydrophilic exterior and ‐OH functional groups, make it a good candidate for functionalization and catalytic application. So, a surface‐modified magnetic solid support with the Cu (II)‐β‐CD complex was prepared. The structure of nanoparticles was characterized by Fourier transform‐infrared spectroscopy, X‐ray powder diffraction, thermogravimetric analysis, vibrating‐sample magnetometry, inductively coupled plasma‐optical emission spectrometry and scanning electron microscope analyses. The catalytic activity of these nanoparticles was investigated in the synthesis of spiropyrans and high yields of desired products obtained under green media. Some advantages of this novel catalyst for this reaction are high yields, short reaction times, green solvent and conditions, easy workup procedure, negligible copper leaching, reusability without a significant diminish in catalytic efficiency, and simple separation of nanocatalyst by using an external magnet alongside the environmental compatibility and sustainability.     

Preparation and characterization of a novel organic–inorganic hybrid nanostructure: application in synthesis of spirocompounds

Research on Chemical Intermediates - Immobilization and heterogenization of acidic/basic groups or organic tags on inorganic supports have found many important applications in recent years. In this...     

An analytical methodology for assessment of smart monitoring impact on future electric power distribution system reliability

Smart grid is referred to a modernized power grid which can mitigate fault detection and allow self‐healing of the system without the intervention of operators. This article proposes an innovative analytical formulation using Markov method to evaluate electric power distribution system reliability in smart grids, which incorporates the impact of smart monitoring on the overall system reliability. An accurate reliability model of the main network components and the communication infrastructure have been also considered in the methodology. The proposed approach was applied to a well‐known test bed (Roy Billinton Test System) and various reliability case studies with monitoring provision and monitoring deficiency are analyzed. This article involves the developing possibilities of communication technologies and next‐generation control systems of the entire smart network based on the real‐time monitoring and modern control system to achieve a reliable, economical, safe, and high efficiency of electricity. The implementations indicate that using an appropriate set of the smart grid monitoring devices for power system components can virtually influence all the reliability indices although the amount of improvement varies between techniques. The proposed approach determined that smart monitoring for which components of the electric power distribution systems are tailored and deduce to major economical benefits. The described approach also reveals which reliability indices drastically influenced using monitoring. © 2014 Wiley Periodicals, Inc. Complexity 21: 99–113, 2015     

Turbulent Convective Heat Transfer and Pressure Drop of Graphene–Water Nanofluid Flowing Inside a Horizontal Circular Tube

Turbulent convective heat transfer of graphene–water nanofluids with various concentrations inside a uniformly heated circular tube is studied experimentally. For this purpose, experiments are conducted to measure thermal conductivity, viscosity, pressure drop, and heat transfer coefficient. Results show enhancement of thermal conductivity and moderate increment of viscosity with addition of low amounts of nanoparticles. Moreover, heat transfer coefficient shows relatively high augmentation, and pressure drop remains unchanged. The maximum enhancements are 10.30%, 4.95%, and 6.04% for thermal conductivity, viscosity, and heat transfer coefficient, respectively. UV–Vis spectroscopy results show that the nanofluids are highly stable.     

Total Synthesis of Tri-, Hexa- and Heptasaccharidic Substructures of the O-Polysaccharide of Providencia rustigianii O34

A general and efficient strategy for synthesis of tri-, hexa- and heptasaccharidic substructures of the lipopolysaccharide of Providencia rustigianii O34 is described. For the heptasaccharide seven different building blocks were employed. Special features of the structures are an α-linked galactosamine and the two embedded α-fucose units, which are either branched at positions-3 and -4 or further linked at their 2-position. Convergent strategies focused on [4+3], [3+4], and [4+2+1] couplings. Whereas the [4+3] and [3+4] coupling strategies failed the [4+2+1] strategy was successful. As monosaccharidic building blocks trichloroacetimidates and phosphates were employed. Global deprotection of the fully protected structures was achieved by Birch reaction.     

Synthesis of spiro[benzopyrazolonaphthyridine-indoline]-diones and spiro[chromenopyrazolopyridine-indoline]-diones by one-pot, three-component methods in water

The synthesis of spiro[benzo[h]pyrazolo[3,4-b][1,6]naphthyridine-7,3′-indoline]-2′,6(5H)-diones and spiro[chromeno[4,3-b]pyrazolo[4,3-e]pyridine-7,3′-indoline]-2′,6(6aH,10H)-diones via a one-pot, three-component reaction of 4-hydroxycoumarin or 4-hydroxy-1-methylquinolin-2(1H)-one, isatins and 1H-pyrazol-5-amines in water is reported.     

Square Monopole Antenna Application in Localization of Tumors in Three Dimensions by Confocal Microwave Imaging for Breast Cancer Detection: Experimental Measurement

In this paper, application of a designed antenna for microwave imaging is evaluated. In previous research, application of an UWB antenna for microwave imaging was investigated. To the best of the author’s knowledge, the designed antenna was the smallest UWB antenna designed at the time of publication, for breast cancer detection. The smaller size antennas can cause more clutter in the image while, on the other hand, make it possible to use more antennas in the array at the same surface. Therefore, the smaller size of the antenna makes microwave imaging more challenging. Simulation results showed successful detection of 10 mm and 5 mm tumors by 16 UWB antennas with the hemispherical arrangement. For signal processing, the Delay-Multiply-and-Sum Algorithm is used for image reconstruction. In this paper results of two experimental microwave imaging is presented. Two tumors at different locations are placed and microwave imaging is performed. The experimental proves that the designed antenna in an array of 16 antennas is capable of detecting the 5 mm tumor in different location.

     

Pyrrole adsorption on aluminum nitride nanotubes on DFT data

The adsorption behavior of pyrrole molecule with external surface of (5.0) on zigzag aluminum nitride nanotube (AlNNT) was studied using density functional theory calculations. It was found that the adsorption energy (E_ad) of pyrrole on the surface of pristine nanotubes is about–11.99 kcal/mol. However, when nanotubes have been doped with P atom, the adsorption energy of pyrrole was increased. Calculation showed that for the phosphorus-doped nanotube the adsorption energy range is about–9.04 to?12.80 kcal/mol. AlNNT is a suitable adsorbent for pyrrole, so it can be used in adsorption and separation processes involving pyrrole. The doped AlNNT can potentially be used for pyrrole sensors for detection in environmental systems.