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排序方式: 共有1831条查询结果,搜索用时 15 毫秒
1.
2.
Neutron activated reference materials have been analyzed using a standard Ge(Li)-detector with 17% relative efficiency, a very large Ge-detector with 96% relative efficiency, and a well-type Ge detector. Sensitivities are presented, and usefulness of these systems for NAA is compared on the basis of performance, economics and complexity. 相似文献
3.
Macomber RS Constantinides I Bauer JK Smith G Button A Lindstrom DO 《The Journal of organic chemistry》1996,61(2):727-734
The reaction of the title diketone (3) with phenyl Grignard produces (with rate constant k(1)) the conjugate base (6-M) of 10-hydroxy-10-phenylcyclooctadecanone (6), which is subsequently converted (with rate constant k(2)) to the conjugate base of the title diol, as a mixture of the cis (7, 55%) and trans (8, 45%) isomers. The ratio k(2)/k(1), 2.2 +/- 0.4, indicates that the carbonyl group in 6-M is 4.4 times as reactive as each carbonyl in 3. Competition experiments further demonstrate that the relative rates (per carbonyl) for addition of phenylmagnesium bromide to 3, 10-methylenecyclooctadecanone (11), and cyclopentadecanone (12) are 1.0:0.60:1.92. Possible reasons for this order of reactivity are discussed. Diols 7 and 8 undergo facile double dehydration to form the title diene 13, which is predicted by molecular mechanics calculations to be the most stable of the four possible symmetrical diene isomers. The structures of 7, 8, and 13 were secured by single-crystal X-ray studies. 相似文献
4.
Hollman AM Bhattacharyya D 《Langmuir : the ACS journal of surfaces and colloids》2004,20(13):5418-5424
In this study, highly permeable ion-selective membranes are prepared via immobilization of polyelectrolyte multilayer networks within the inner pore structure of a microporous (pore size = 0.2 microm) support. Electrostatic layer-by-layer assembly is achieved through alternate adsorption of cationic and anionic polyelectrolytes under convective flow conditions. To initiate pore assembly, the first layer consists of covalently bound charged polypeptides (poly(L-glutamic acid) (PLGA) or poly(L-lysine) (PLL)) establishing a charged support for subsequent adsorption. Nonstoichiometric immobilization of charged multilayers within a confined pore geometry leads to an enhanced volume density of ionizable groups in the membrane phase. This overall increase in the effective charge density allows for Donnan exclusion of ionic species (especially divalent co-ions) using microporous materials characterized by permeability values that exceed conventional membrane processes. Multilayer assemblies are fabricated using both PLGA/PLL and synthetic polyelectrolytes (poly(styrenesulfonate)/poly(allylamine)) in an attempt to compare the level of adsorption and separation properties of the resulting materials. The role of salt concentration in the carrier solvent on overall polyelectrolyte adsorption was examined to determine its effect on both solute (Cl-, SO4(2-), As(V)) and water transport. Constriction of the pore size induced by multilayer propagation was monitored through permeability measurements and dextran rejection studies at each stage of the deposition process. 相似文献
5.
R. M. Lindstrom R. Zeisler M. Rossbach 《Journal of Radioanalytical and Nuclear Chemistry》1987,112(2):321-330
Guided beams of cold neutrons being installed at a number of research reactors may become increasingly available for analytical research. A guided cold beam will provide higher neutron fluence rates and lower background interferences than in present facilities. In an optimized facility, fluence rates of 109 n·cm–2·s–1 are obtainable. Focusing a large area beam onto a small target will further increase the neutron intensity. In addition, the shift to lower neutron energy increases the effective cross sections. The absence of fast neutrons and gamma rays permits detectors to be placed near the sample without intolerable background, and thus the efficiency for counting prompt gamma rays can be much higher than in present systems. Measurements made at the hydrogen cold source of the FRJ-2 (DIDO) reactor at the KFA provide a numerical evaluation of the improvements in PGAA with respect to signal-to-background ratios of important elements and matrices. 相似文献
6.
In o,o'-dihydroxyazo-dye metal-ion indicators, one hydroxyl group is 10(4) times more acidic than the other. The location of the more acidic group has been a mystery. By methylation of the acidic group, reduction of the monomethylated compound, isolation and characterization of the split methoxyamine and hydroxyamine, the location of the acidic group has been established. Indicators examined include Calmagite, Eriochrome Black T, Eriochrome Blue Black R and 4-(2-pyridylazo)resorcinol (PAR). 相似文献
7.
Haifang Liu Yuanqiang Sun Zhaohui Li Ran Yang Jie Yang Aaron Albert Aryee Xiaoge Zhang Jia Ge Lingbo Qu Yuehe Lin 《中国化学快报》2019,30(9):1647-1651
Intracellular pH plays a significant role in various biological processes, including cell proliferation, apoptosis, metabolism, enzyme activity and homeostasis. In this work, a novel design strategy for the preparation of pH responsive carbon dots (CDs-pH) for ratiometric intracellular imaging was reported. By using SciFinder database, fluorescent CDs-pH with the required pKa value of 6.84 were rationally designed, which is vital important for precise sensing of intracellular pH. As a result, the synthesized CDs-pH demonstrated robust ability to test pH fluctuations within the physiological range of 5.4-7.4. The CDs-pH was further utilized for fluorescent ratiometric imaging of pH in living HeLa cells, effectively avoided the influence of autofluorescence from native cellular species. Moreover, real-time monitoring of intracellular pH fluctuation under heat shock was successfully realized. This SciFinder-guided design strategy is simple and flexible, which has a great potential to be used for the development of other types of CDs for various applications. 相似文献
8.
9.
Calmagite was introduced in 1960 as a stable substitute for Eriochrome Black T in EDTA titrations of calcium plus magnesium. The colour changes were the same but somewhat sharper. Indicator stock solutions were stable indefinitely. The new indicator was designed as an indicator and not as a wool dye. Azo dye impurities which may be present in some commercial supplies tend to lengthen the end-points. A simple means of removing these impurities to yield crystalline indicator has been developed. The effects of sulphonation on the performance of azo dyes as indicators have been studied. 相似文献
10.
Alexander R. Giaquinto Richard E. Lindstrom James Swarbrick Antonio LoSurdo 《Journal of solution chemistry》1977,6(10):687-701
Solubility and apparent molar volume data are used to demonstrate effects of amide alkylation on amide-water interactions at 25° C. Precise measurements were made of the apparent molar volumes of the amides in binary amide-water mixtures using a dilatometric technique. The results show that the apparent molar volumes of alkyl-substituted amides in water pass through a minimum at an amide concentration which varies inversely with the degree of alkylation. Further studies showed that the solubilities of methyl paraben (methyl-p-hydroxybenzoate) and naphthalene in various amide-water solvent systems increased in characteristic fashion with amide alkylation. 相似文献