基于IABC-SVR算法的拉曼光谱定量分析山羊血清蛋白含量

提出了一种基于拉曼光谱和改进人工蜂群算法优化支持向量机回归（IABC-SVR）算法快速定量检测山羊血清蛋白含量的方法。传统人工蜂群算法在数据区域规模较大时,收敛速度逐渐减慢, 出现效率低、精准度下降、局部最优解概率高等问题。所提出的算法解决了这些问题,使算法在进化前期避免陷入局部最优解,在进化中后期能够保持解的全局搜索能力。常规测定血清蛋白总量的方法通常采用凯氏定氮法、双缩脲法等,但存在时效慢、污染样本等缺点。采用拉曼光谱法进行检测,具有快速、无损的优点。以山羊血清为分析对象,按一定体积比配置35组待测样本,用拉曼光谱仪采集拉曼光谱,光谱采集范围为300~1 300 cm-1,采用基线矫正去除荧光背景,使用Savitzky-Golay光谱平滑法对原始光谱进行平滑处理,归一化处理光谱数据,并对拉曼光谱特征峰进行归属。实验结果表明,拉曼光谱能够表征血清中主要化学集团的信息,且由于官能团浓度差异,光谱特征峰强度随浓度变化明显,因此基于特征峰信息可以测定血清蛋白总量。实验中,以购买的山羊血清蛋白含量为基准,通过配置样本的体积比得到各组待测血清样本的蛋白含量,配置的单个液体样本体积为3 mL,随机选取8组实验样本作为模型测试集,剩余27组作为模型训练集。以经过处理的光谱特征峰强度和对应的血清蛋白含量分别作为模型的输入值及输出值,建立IABC-SVR,ABC-SVR和BP三种算法的定量模型,对测试集血清蛋白总量进行预测。最后通过均方差(MSE),相关系数（r）与建模时间分别进行对比,结果表明通过IABC-SVR建立的山羊血清蛋白定量矫正模型效果最佳,模型的相关系数为0.990 27,均方误差为0.244 3,建模时间为1.9 s,预测值方差均小于0.001 g·mL-1,预测准确率为99.8%。实验结果表明,应用激光拉曼光谱技术结合IABC-SVR算法,对快速定量检测山羊血清蛋白含量,具有较高的准确率和稳定性。     

待熔光子晶体光纤中的热传导特性

在光子晶体光纤(PCF)的熔接过程中,由于包层空气孔结构的存在,同在熔接过程中存在着潜在的空气孔形变,使得加热过程更为复杂.对待熔的光子晶体光纤的热传导特性进行了研究,以二氧化碳激光作为熔接热源,根据传热学及能量守恒定律建立三维对称的热传导模型,进而对光子晶体光纤熔接的瞬态传热过程进行仿真分析和实验研究.分析表明,该模型可以很好地确定影响光子晶体光纤熔接过程中热传导特性的各个主要因素,为最终确定最佳熔接条件建立理论基础.     

Study on polarization properties of graphene coated D-shaped fiber

The optical properties of graphene coated D-shaped single mode fiber and photonic crystal fiber are numerically analyzed. Enhancement of the graphene-light interaction is found in graphene coated D-shaped photonic crystal fiber,which introduces a tunable polarization of the D-shaped fiber by changing the chemical potential of the coated graphene.An optimal polarizer model is demonstrated with the extinction ratio of 66.26 dB/mm and the insertion loss of 9.4 dB/mm.The modulator extinction ratios of the TE mode and TM mode are 11.5 dB and 5 dB, respectively, with a device length of100 μm. This paper provides a theoretical reference for the optical property research of the graphene fiber.     

纳米银溶胶和微腔型光纤SERS基底的制备及其性能比较

通过化学法制备了纳米银溶胶基底和微腔型光纤表面增强拉曼散射(SERS)基底,其中光纤SERS基底的微腔结构是通过氢氟酸(H F)腐蚀得到的.实验采用湿法检测,首先将纳米银溶胶基底与罗丹明6G(R6 G)混合,找到增强效果最强时的裸光纤微腔结构,在此结构的基础上采用溶胶自组装法制备银纳米颗粒包覆的光纤SERS基底,通过控...     

Refractive index insensitive temperature sensor based on waist-enlarged few mode fiber bitapers

A refractive index insensitive temperature sensor based on waist-enlarged few mode fiber (FMF) bitapers is presented. The first section of FMF is spliced between two single-mode fibers. In fusion process, the waist-enlarged FMF bitapers can be obtained by large current discharging repeatedly. The refractive index and temperature sensing mechanisms are analyzed. For the sensors with different sizes, the refractive index and temperature experiments have been performed. The results show that in the refractive index ranges of 1.335 0—1.346 6 and 1.348 2—1.419 3, the refractive index insensitivity is verified. In a temperature range of 31.9—90 °C, the sensor sensitivity can be up to 85.57 pm/°C. In addition, it has a compact structure. Therefore, the sensor can avoid the cross sensitivity for measuring the refractive index and temperature simultaneously.     

基于粗锥结构级联LPFG的双包层光纤多参量传感器

提出了一种基于模间干涉的测量温度、折射率和轴向应变的光纤传感器.在单模光纤与双包层光纤熔接点处形成粗锥,再与两个周期不同的长周期光纤光栅级联,由于模场失配,激发高阶模,形成三个谐振峰,且对不同参量有不同的灵敏度响应,通过解调三个谐振峰的波长漂移,利用系数灵敏度矩阵,可以测量温度、折射率和轴向应变.实验结果表明,温度在2...     

Numerical and experimental analysis of long period gratings in wavelength scale elliptical microfibers

We report the fabrication of long-period gratings(LPGs) in elliptical microfibers with femtosecond laser. Based on the numerical analysis of the modes and the mode coupling condition of elliptical microfibers, an LPG is fabricated with a very short pitch of 10 μm by periodically modifying the fiber surface, which demonstrates very strong polarization-dependent resonances, a very low temperature sensitivity of a few picometers in air, and high temperature sensitivity of-1.62 nm/?C in refractive index oil.     

Periodical rocking long period gratings in PANDA fibers for high temperature and refractive index sensing

We report periodical rocking long period gratings (PR-LPGs) in PANDA fibers fabricated with CO2 laser. The PR-LPGs achieve very high coupling efficiency of 19 dB with 12 periods and a 3.5° twist angle in just one scanning cycle, which is much more effective than the conventional CO2 laser fabrication technique. This type of LPGs exhibits polarization-selective resonance dips which demonstrate different sensitivities to environmental parameters. The high temperature and external refractive index sensitivities are measured simultaneously, so it can be used as a wavelength-selective polarization filter and sensor. This work has been supported by the National Natural Science Foundation of China (No.61605168), the Natural Science Foundation of Hebei Province (No.F2016203392), the College and University Natural Science Foundation of Hebei Province (No.QN2016078), the Science and Technology Project of Qinhuangdao City (No.201601B050), and the Intramural Doctoral Foundation of Yanshan Universtiy (No.B1011). E-mail:jinwa@ysu.edu.cn      

光子晶体光纤熔接过程中的空气孔力学特性

在光子晶体光纤(PCFs)的熔接过程中,熔接能量和加热时间的控制是避免空气孔塌陷的关键所在.应用经典力学理论,提出了一种光子晶体光纤熔接过程中力学特性的数学模型,对熔接过程中光子晶体光纤空气孔的畸变情况及畸变对光纤模场分布变化引起的熔接损耗进行了分析.分析结果表明,通过控制熔接能量和熔接时间可以控制光子晶体光纤空气孔的畸变情况.根据理论分析结果,进行熔接实验,分析空气孔畸变引起的损耗情况.实验结果与理论值有很好的一致性.     

大孔柚子型微结构光纤探针的表面增强拉曼散射性能研究

随着光纤制备工艺以及纳米材料制备技术的发展,光纤探针已成为一种新型的表面增强拉曼散射(SERS)基底,通过在普通单模光纤或多模光纤上制备不同的结构并修饰相应的纳米材料,可以得到多种类型的光纤表面增强拉曼散射探针,并实现较好的检测效果。但受限于光纤本身的结构,普通光纤仅能利用端面或侧表面提供拉曼检测的“热点”区域,限制了其SERS性能的进一步提高。因此制备了大孔柚子型微结构光纤(MSF)表面增强拉曼散射(SERS)探针,其中大孔柚子型MSF SERS探针结构通过一段阶跃多模光纤与柚子型微结构光纤熔接制得。实验分别对自制的纳米银溶胶基底以及大孔柚子型MSF SERS探针的SERS性能进行检测。采用溶胶自组装法制备负载银纳米颗粒的MSF SERS探针,通过控制自组装时间制备不同光纤SERS探针(Ag/MSF-x,其中x为自组装时间,分别为15、 30、 45、 60 min)。采用溶液检测方法,利用Ag/MSF-x探针对10^-3 mol·L^-1的亚甲基蓝(MB)探针分子进行检测,通过比较相同条件下的增强效果筛选得到Ag/MSF-45探针。为进一步检...