蔗糖酯示波极谱分析法的研究

蔗糖酯分子在碱性条件下，加热水解为蔗糖和硬酯酸，在ｐＨ＞１０的ＮＨ＿３·Ｎ＿２Ｏ－（ＮＨ＿３）＿３Ｃ＿６Ｈ＿５Ｏ＿７体系中，于示波极谱仪上，峰电位─０．９１Ｖ处出现一灵敏度高和稳定性好的极谱图，其浓度从０．０２～０．２８ｍｇ／ｍＬ与峰电流呈线性关系，最低检出限为０．００４ｍｇ／ｍＬ，相对标准偏差为１．３％。     

Characteristics of Sb_6Te_4/VO_2 Multilayer Thin Films for Good Stability and Ultrafast Speed Applied in Phase Change Memory

The Sb_6Te_4/VO_2 multilayer thin films are prepared by magnetron sputtering and the potential application in phase change memory is investigated in detail. Compared with Sb_6Te_4, Sb_6Te_4/VO_2 multilayer composite thin films have higher phase change temperature and crystallization resistance, indicating better thermal stability and less power consumption. Also, Sb_6Te_4/VO_2 has a broader energy band of 1.58 eV and better data retention(125℃ for 10 y). The crystallization is suppressed by the multilayer interfaces in Sb_6Te_4/VO_2 thin film with a smaller rms surface roughness for Sb_6Te_4/VO_2 than monolayer Sb_4Te_6. The picosecond laser technology is applied to study the phase change speed. A short crystallization time of 5.21 ns is realized for the Sb_6Te_4(2 nm)/VO_2(8 nm)thin film. The Sb_6Te_4/VO_2 multilayer thin film is a potential and competitive phase change material for its good thermal stability and fast phase change speed.     

椭圆芯保偏光纤模间干涉的研究

对椭圆芯保偏光纤的模间干涉现象进行了仿真研究,得到了其干涉输出光强分布同模间相位差之间的关系.将一种椭圆芯保偏光纤进行等面积矩形变换后,通过马卡梯里近似方法对两个低阶模式LP01模和LPeven11模的传输特性及传播常数进行了数值计算,得到了归一化传播常数和归一化截止频率之间的关系.通过实验得到了两个模式之间干涉模斑远场图样,表明椭圆芯保偏光纤的模间干涉特性可以应用于应力、电压等的测量.模间干涉将传感臂和参考臂集于一根光纤中,具有很好的抗环境干扰能力.     

垃圾渗出液中微量蒽的高效液相色谱法测定

用反相高效液相色谱法定量测定垃圾渗出液中微量的蒽，线性范围为1－100mg/L，最小检测质量浓度为0．05mg/L，实际样品分析相对标准偏差为3．1％（n＝3），回收率90％－105％，结果令人满意。     

企业数字化档案安全应用管理的探讨

随着信息化时代的快速发展,各种计算机技术以及电子信息技术的应用使得很多工作的信息化程度都逐渐提高。在企业档案管理中,数字化档案成为档案管理的一种新模式。档案管理模式也由传统的管理方式向现代化进行转变。但是数字化档案的应用的过程中还是存在一些安全问题。本文浅述企业的数字化档案在应用过程中的安全问题以及相应的应对措施。     

Bending characteristics of dual-hole PM-PCF based on LP01 and LP11 modal interference

The bending characteristics of dual-hole polarization maintaining photonic crystal fiber (PM-PCF) are demonstrated in this paper. The modal interference is induced by the LP01 mode and LP11 mode propagating in a single PM-PCF with the same polarization direction. Simulation results demonstrate that the bending radius induces the phase difference between LP01 mode and LP11 mode, which leads to the change of light interference intensity on the fiber output facet. The relationship between bending radius and normalized interference intensity with three different bending angles is discussed, where the bending angle is defined as the angle between hole axis and the x axis. The bending sensitivity is obtained to be about -188.78/m around the bending radius of 1.5 cm with the bending angle of 90°. The bending characteristics can contribute for online bending detection in widespread areas.     

Influence of disorder and deformation on the optical properties of two-dimensional photonic crystal waveguide

We investigate the effect of disorder and mechanical deformation on two- dimensional photonic crystal waveguide. The dispersion characteristics and transmittance of the waveguide are studied by using the finite element method. Results show that the geometric change of the dielectric material perpendicular to the light propagation direction has a larger influence on the waveguide characteristics than that parallel to the light propagation direction. Mechanical deformation has an obvious influence on the performance of the waveguide. In particular, longitudinal deformed structure exhibits distinct optical characteristics from the ideal one. Studies on this work will provide useful guideline to the fabrications and practical applications based on photonic crystal waveguides.     

GC-MS联用分析火龙果花提取液的化学成分

采用GC/MS分析火龙果花无水乙醇、CH2Cl2提取液的化学成分.从无水乙醇和CH2C12提取液中分别分离出60和54个峰,经NIST数据库检索、与标准谱图比较共鉴定出49个化学组分.结果表明,火龙果花中含有维生素E,脂肪酸,烃类和β-谷甾醇、豆甾醇、菜油甾醇等甾醇类化合物.     

双偏振微结构光纤光栅的折射率传感特性分析

研究了微结构光纤(MOF)布拉格光栅(FBG)的双偏振折射率传感特性。利用有限元方法对保偏微结构光纤(PM-MOF)的传输特性进行了分析,计算了传输特性曲线,分析了该种光纤单模传输的范围。同时结合耦合模理论,仿真了该种光纤均匀布拉格光栅在充入不同介质时的反射谱,得到两个偏振模LP0x1和LP0y1的中心波长差与介质折射率的关系曲线,通过特性曲线拟合出相应公式。同时,仿真了该光纤光栅的温度特性,研究结果表明,两个偏振模中心波长对温度响应相似,因此利用双偏振差分的方式来探测,具有较强的抗干扰能力,这一特性为光纤生物传感器的应用提供了理论依据。     

裂解气相色谱-质谱联用法分析卷烟燃吸产物

应用带有吸附阱的CDS 5200型热裂解仪,在不同的裂解温度条件下对卷烟样品进行裂解处理,所得裂解产物直接引入仪器进行气相色谱-质谱分析,检测其中的特征组分、烟碱、新植二烯及有害物质,所测得结果与按标准GB/T 19609-2004方法测得的结果作比较。结果表明:①有害物质的裂解释出量随裂解温度降低而明显下降;②半挥发性烟碱的裂解释出量与常态卷烟吸燃温度相近的裂解温度下不存在相关性;③非挥发性的新植二烯的裂解释出量随裂解温度升高而降低;④在常态卷烟吸燃温度下,所测得的烟碱及新植二烯的释出量基本相同;⑤主流烟气中烟碱主要通过蒸馏而并非通过裂解释出;⑥卷烟吸燃温度的降低有利于减少有害物质的释出;⑦所提出的裂解处理方法作为卷烟燃吸产物的模拟分析是可行的。