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以柠檬酸为螯合剂利用快速湿化学法合成了具有α-NaFeO2型层状结构的LiNi0.33-xMn0.33Co0.33AlxO2(x=0.00,0.01,0.02, 0.04)正极材料,并通过X-射线衍射、充放电测试、循环伏安和交流阻抗对材料的结构和电化学性能进行了系统研究。XRD结果表明此方法合成的材料具有很好的层状结构且阳离子的混排度随着Al3+含量的增加而下降。电化学测试表明,LiNi0.31Mn0.33Co0.33Al0.02O2具有很好的电化学性能和和循环性能,1C放电倍率下首次放电比容量达到176.9 mAh·g-1,且Al3+的掺杂能有效提高电荷在电极界面间转移并抑制了在高压循环过程中电荷转移阻抗的增加。 相似文献
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近年来,"数字矿山"概念的提出为煤炭工业的两化融合指出了具体实现途径。"数字矿山"其核心是在统一的时间坐标和空间框架下,以计算机及其网络为手段,将海量异质的矿山信息进行全面、高效、有序的管理和整合。作为"数字矿山"的基础平台和实现手段,计算机网络在"数字矿山"的建设中起着至关重要的作用。本文以"三网合一"在榆林神华郭家湾煤矿的现阶段具体应用为例,简要介绍了"三网合一"网络技术在矿区网络平台搭建中的建设以及应用。 相似文献
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We present a design for tunable directional beaming through a subwavelength metallic double slit surrounded by dielectric surface-relief gratings.On-axis and off-axis beaming can be switched by controlling the incident angle to asymmetrically excite surface plasmon polaritons(SPPs) that are subsequently coupled out to propagating beams by the two gratings on the left and the right sides of the double slit.Furthermore,the division of optical power into two off-axis beaming directions can be tuned smoothly by varying the incident angle while keeping the total power almost unchanged.The mechanism of this effect is analyzed theoretically and verified using rigorous numerical simulations. 相似文献
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A simple and repeatable method to fabricate high-aspect-ratio(HAR) and high-quality microgrooves in silica is reported. The method consists of two steps:(1) formation of laser-modified regions by femtosecond Bessel beam irradiation, and(2) removing laser-modified regions through HF etching. Uniform, straight microgrooves can be fabricated and the highest aspect ratio that can be reached is ~52. The phenomenon is attributed to the uniform energy distribution in the long propagation distance, which leads to the long and uniform laser-modified regions and subsequent HF acid etching of laser-modified regions with high selectivity. This method will have potential applications in fabrication of HAR microgrooves in transparent materials. 相似文献
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