Generation of UV laser light by stimulated Raman scattering in D2, D2/Ar and D2/He using a pulsed Nd:YAG laser at 355nm

A pulsed Nd:YAG laser at 355nm is used to pump Raman cell filled with D_2, D_2/Ar and D_2/He. With adequately adjusted parameters, the maximum photon conversion efficiency of the first-order Stokes light (S_1, 396.796nm) reaches 33.33% in D_2/Ar and the stability of S_1 in pure D_2 is fairly high, the energy drift being less than 10% when the pump energy drifts in the range of 5%. The conversion efficiency and stability, which are functions of the composition and pressure of the Raman medium and the energy of pump laser, are investigated. The result has been used to optimize the laser transmitter system for a differential absorption lidar system to measure NO_2 concentration profiles.     

农药甲霜灵对映体的高效液相色谱分离及手性拆分热力学研究

以正己烷 异丙醇为流动相 ,在纤维素 三 (3 ,5 二甲基苯基氨基甲酸酯 ) (CDMPC)涂敷型手性固定相上 ,对农药甲霜灵外消旋体进行了拆分 ,考察了流动相组成、柱温等对甲霜灵对映体的保留和分离的影响 ;对甲霜灵R、S对映体与固定相之间的保留和分离的热力学机理进行了讨论     

ALTERATION IN CHROMATIN CONFORMATION OF PROLIFERATING AND DIFFERENTIATING ENZYME GENES IN NORMAL MOUSE LIVER AND ASCITES HEPATOMA CELLS AND ITS RELATION TO THE GENE EXPRESSION OF ENZYMES

Nuclei from the normal mouse liver were partially digested with micrococcal nuclease, followed by DNA extraction, agarose gel clectrophoresis and dot blot hybridization with ~(32)P-labeled cDNA probes of CPS_1 and ACT complex, It was clearly shown that the CPS_1 genes were distributed on the monomer, dimer. and trimer of nucleosomes, while the genes coding for ACT complex were distributed on the condensed oligonucleosomes. An opposite manner of distribution of CPS_1 and ACT complex genes was, however, noted in the case of ascites hepatoma cells, in which the specific activity of ACT was 13 times higher than that in the normal liver, while that of CPS_1 was remarkably reduced. Similar patterns of change in mRNA level of CPS_1 and ACT complex were observed in the normal mouse liver and ascites hepatoma cells, indicating a close relationship between chromatin structure and gene expression of these enzymes.     

增塑剂对1,1,1-三[1′-(2′-氧杂-4′-氧代-5′-氮杂-5′-甲基)十二烷基]丙烷PVC膜钠离子电极性能的影响

以1,1,1-三[1′-(2′-氧杂-4′-氧代-5′-氮杂-5′-甲基)十二烷基]丙烷(即ETH 227,Fluka No.71732)为中性载体的钠离子选择电极由于具有较强的抗钾离子干扰的能力,因而颇受注意。Guggi等首先用邻硝基苯辛醚和癸二酸二丁酯增塑,以合成的ETH227制成了K_((Na)~+,K~+)~(pot),<<10~(-2)的PVC膜钠离子电极.Jenny等以癸二酸二异辛酯为增塑剂,     

一种高性能的金属探测门信号处理电路的设计

设计了基于正交解调和窄带滤波技术的信号处理电路,它使用模拟开关作为乘法器,实现解调,并使用一种性能优异的窄带滤波电路对解调结果进行滤波和放大.整个电路具有高增益、高灵敏度、强抗干扰能力、低成本等优点,可有效提高金属探测门的性能.     

瑞利激光雷达探测大气温度算法分析

介绍了瑞利激光雷达的基本结构,描述了使用瑞利散射激光雷达探测平流层和中间层低部大气温度的数据处理方法,构建同时包含标准大气模式温度信息和实际探测背景噪声的模拟数据,对此模拟数据进行背景扣除、平滑去噪、参考点选取等计算分析,探讨提高温度反演精度的实用算法。并应用此数据处理方法对瑞利激光雷达的实际测量数据进行了计算处理,将计算结果与模式CIRJA86、HALOE卫星数据进行对比分析,反演高度30～45km时误差1—3K,45～65km误差大约在2—5K,65—70km误差〈10K。     

2001年合肥上空大气臭氧的分布特征分析

对L625差分吸收激光雷达2001年的臭氧观测数据进行了处理和分析,观测结果表明:合肥上空高度5～45 km区间,臭氧厚度0.264×10-5 km,峰值高度海拔24.9 km,峰值大小4.3677×1012 cm-3.不同高度的臭氧数密度具有明显的季节特征,35 km、30 km和25 km高度的臭氧数密度变化特征表现为夏季数密度高,冬季数密度低.20 km、15 km和10 km高度的臭氧数密度的变化特征表现为冬春季数密度高,秋季数密度低.臭氧层峰值高度夏秋季高,冬春季低.     

单波长与双波长探测平流层臭氧的比较

本文利用安微光机的多波长紫外差分吸收激光雷达∧［1］的探测结果,在平流层背景气溶胶情况下,比较单波长（308nm）距离差分方法和双波长（308-355nm）差分方法受气溶胶和温度影响的结果,比较结果表明：单波长距离差分方法受温度变化和气溶胶的不均匀影响较大,双波长差分方法受影响较小,两种方法的处理结果有明显差异,30天的平均结果表明,在19km以下,单波长结果与双波长结果相差较大;在19～35km高度区间,单波长结果与双波长结果的相对误差小于12%。     

激光光源粒子计数器响应曲线对粒子折射率敏感度及多值性的分析

采用激光作光源的光学粒子计数器(L_OPC)克服了白炽灯作光源时使用寿命短、发光强度不稳定、需要经常标定的缺点,但激光波长的单一也带来了一些问题,如响应曲线对折射率敏感度的变化和多值性等问题。利用Mie散射理论,通过数值模拟实验,对L_OPC的这些问题进行了分析,提出了L_OPC实验样机的设计参数。