全文获取类型
收费全文 | 545篇 |
免费 | 6篇 |
国内免费 | 6篇 |
专业分类
化学 | 307篇 |
力学 | 2篇 |
综合类 | 7篇 |
数学 | 20篇 |
物理学 | 129篇 |
无线电 | 92篇 |
出版年
2023年 | 5篇 |
2021年 | 3篇 |
2014年 | 5篇 |
2013年 | 3篇 |
2012年 | 36篇 |
2011年 | 73篇 |
2010年 | 13篇 |
2009年 | 6篇 |
2008年 | 48篇 |
2007年 | 50篇 |
2006年 | 42篇 |
2005年 | 44篇 |
2004年 | 25篇 |
2003年 | 35篇 |
2002年 | 16篇 |
2001年 | 30篇 |
2000年 | 20篇 |
1999年 | 12篇 |
1998年 | 3篇 |
1997年 | 2篇 |
1996年 | 7篇 |
1995年 | 2篇 |
1994年 | 5篇 |
1993年 | 1篇 |
1992年 | 4篇 |
1991年 | 2篇 |
1990年 | 4篇 |
1989年 | 9篇 |
1988年 | 2篇 |
1987年 | 11篇 |
1986年 | 1篇 |
1985年 | 5篇 |
1984年 | 2篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1977年 | 1篇 |
1972年 | 2篇 |
1971年 | 1篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1962年 | 1篇 |
1961年 | 1篇 |
1960年 | 1篇 |
1959年 | 2篇 |
1956年 | 1篇 |
1955年 | 2篇 |
1954年 | 3篇 |
1953年 | 1篇 |
排序方式: 共有557条查询结果,搜索用时 421 毫秒
1.
摩托罗拉L7因其性价比较高拥有众多的拥护者。但是对于新手来讲。如何安装驱动和怎样解决驱动安装过程中出现的问题。是一件令人点头烂额的事。电脑上只有安装了L7驱动,才能更好地使用L7手机的各种实用软件,以实现诸如可以提高耳机听歌音量、突破摄像时间长度限制等多种功能。下面就详细谈一谈怎样在电脑上成功安装L7驱动。[编者按] 相似文献
2.
Bortoletto D Goldberg M Horwitz N Mestayer MD Moneti GC Sharma V Shipsey IP Skwarnicki T Csorna SE Letson T Brock IC Ferguson T Artuso M Bebek C Berkelman K Blucher E Byrd J Cassel DG Cheu E Coffman DM Crawford G DeSalvo R DeWire JW Drell PS Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Kowalewski R Kreinick DL Kubota Y Lewis JD Mistry NB Mueller J Namjoshi R Nandi S Nordberg E O'Grady C Peterson D Pisharody M Riley D Sapper M Silverman A Stone S Worden H 《Physical review letters》1989,62(21):2436-2439
3.
Alam MS Katayama N Kim IJ Li WC Lou XC Sun CR Bortoletto D Goldberg M Horwitz N Mestayer MD Moneti GC Sharma V Shipsey IP Skwarnicki T Csorna SE Letson T Brock IC Ferguson T Artuso M Bebek C Berkelman K Blucher E Byrd J Cassel DG Cheu E Coffman DM Crawford G DeSalvo R DeWire JW Drell PS Ehrlich R Galik RS Gittelman B Gray SW Halling AM Hartill DL Heltsley BK Kandaswamy J Kowalewski R Kreinick DL Kubota Y Lewis JD Mistry NB Mueller J Namjoshi R Nandi S Nordberg E O'Grady C Peterson D Pisharody M 《Physical review D: Particles and fields》1989,40(11):3790
4.
Appleby I Boulton LT Cobley CJ Hill C Hughes ML de Koning PD Lennon IC Praquin C Ramsden JA Samuel HJ Willis N 《Organic letters》2005,7(10):1931-1934
Two methods to produce (2S)-5-amino-2-(1-n-propyl-1H-imidazol-4-ylmethyl)-pentanoic acid were investigated. Diastereoisomeric salt resolution, using the quinidine salt, gave the desired intermediate in 98% ee and 33% yield. Asymmetric hydrogenation of various substrates gave high conversions, with up to 83% ee. Integration of these two approaches via asymmetric hydrogenation of a quinidine salt substrate followed by crystallization provided the desired intermediate in 94% ee and 76% yield. 相似文献
5.
6.
Junker J Reif B Steinhagen H Junker B Felli IC Reggelin M Griesinger C 《Chemistry (Weinheim an der Bergstrasse, Germany)》2000,6(17):3281-3286
The structure of a catalytic intermediate with important implications for the interpretation of the stereochemical outcome of the palladium complex catalyzed allylic substitution with phosphino-oxazoline (PHOX) ligands is determined by liquid state NMR. The complex displays a novel structure that is highly distorted compared with other palladium eta2-olefin complexes known so far. The structure has been determined from nuclear overhauser data (NOE), scalar coupling constants, and long range projection angle restraints derived from dipole dipole cross-correlated relaxation of multiple quantum coherence. The latter restraints have been implemented into a distance geometry protocol. The projection angle restraints yield a higher precision in the determination of the relative orientation of the two molecular moieties and are essential to provide an exact structural definition of the olefinic part of the catalytic intermediate with respect to the ligand. 相似文献
7.
Key aspects of the microenvironment surrounding the Fe center in the nitrosyl adduct of iron phthalocyanine, [Fe(Pc)(NO)], have been elucidated from the analysis of the Fe K-edge extended X-ray absorption fine structure (EXAFS) of the material adsorbed on the surface of a high area carbon electrode recorded in situ, in 0.5 M H(2)SO(4). Statistical best fits to the EXAFS data place the Fe center in a five-coordinated square pyramidal configuration shifted away from the Pc plane toward the axially bound NO bent at an angle of ca. 40 degrees with respect to the normal to the Pc plane. This environment is analogous to that of Fe in the nitrosyl adduct of crystalline [Fe(TPP)], where TPP = meso-tetraphenylporphyrinato(2-), determined from X-ray diffraction. 相似文献
8.
高压断路器分合闸线圈电流波形中包含着丰富的断路器操动机构和控制回路的状态信息,分析分合闸线圈电流的特性对断路器的状态监测、故障诊断具有重要意义。文中提出一种基于变分模态分解(VMD)模态分量的高压断路器分合闸线圈电流特征值提取方法;通过变分模态分解算法对分合闸线圈电流进行分解,并确定有效反映线圈电流关键信息的模态分量;随后采用削波方式处理模态分量以提取线圈电流波形关键时间点及对应电流特征值。基于断路器实验平台采集的数据样本的实验验证结果表明,该方法能够准确有效地提取分合闸线圈电流关键特征值。 相似文献
9.
The present work describes a selective, rapid and economical method for the determination of cobalt using the 2-(2-benzothiazolylazo)-p-cresol (BTAC) as a spectrophotometric reagent associated with a solid extraction on polyurethane foam. The BTAC reacts with Co(II) in the presence of Triton-X100 surfactant forming a green complex with maximum absorption at 615 nm. The reaction is used for cobalt determination within a pH range of 6.50-7.50, with an apparent molar absorptivity of 1.62 x 10(4) L mol(-1) cm(-1). Beer's Law is obeyed for a concentration of at least 1.60 microg ml(-1). A selective procedure is proposed for cobalt determination in the presence of Fe(II), Hg(II), Zn(II) and Cu(II) up to milligram levels using masking agents. Polyurethane foam is used for the preconcentration and separation of cobalt from thiocyanate media and this procedure is applied to its determination in nickel salts and steel alloys. 相似文献
10.
de Loos F Reynhout IC Cornelissen JJ Rowan AE Nolte RJ 《Chemical communications (Cambridge, England)》2005,(1):60-62
A series of mono-functionalized metallo-porphyrin polystyrenes have been synthesized using atom transfer radical polymerization and their self-assembling behavior was studied by electron microscopy showing that the polystyrene tail-length influences the aggregate architecture. 相似文献