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排序方式: 共有1127条查询结果,搜索用时 15 毫秒
1.
2.
Convective heat transfer from an array of small, cylindrical bodies of arbitrary shape in an unbounded, two-dimensional domain is a singular perturbation problem involving an infinite logarithmic expansion in the small parameter ε, representing the order of magnitude of the size of the bodies. Using the method of matched asymptotic expansions, we formulate a hybrid asymptotic-numerical method to solve for the dimensionless, steady-state temperature. We assume that the velocity field of the fluid surrounding the bodies is arbitrary but known. From our asymptotic solution for an arbitrary velocity field, we present the results for two special cases: a uniform flow field and a simple shear flow field. We demonstrate the asymptotic results of the hybrid method through a number of examples and, in a particular case, we compare these results to an exact analytical solution. 相似文献
3.
Jan Annaert Griselda Deelstra Michèle Vanmaele 《Insurance: Mathematics and Economics》2007,41(3):299-316
In this paper, we elaborate a formula for determining the optimal strike price for a bond put option, used to hedge a position in a bond. This strike price is optimal in the sense that it minimizes, for a given budget, either Value-at-Risk or Tail Value-at-Risk. Formulas are derived for both zero-coupon and coupon bonds, which can also be understood as a portfolio of bonds. These formulas are valid for any short rate model that implies an affine term structure model and in particular that implies a lognormal distribution of future zero-coupon bond prices. As an application, we focus on the Hull-White one-factor model, which is calibrated to a set of cap prices. We illustrate our procedure by hedging a Belgian government bond, and take into account the possibility of divergence between theoretical option prices and real option prices. This paper can be seen as an extension of the work of Ahn and co-workers [Ahn, D., Boudoukh, J., Richardson, M., Whitelaw, R., 1999. Optimal risk management using options. J. Financ. 54, 359-375], who consider the same problem for an investment in a share. 相似文献
4.
David J. Aitken Dominique Guillaume Henri-Philippe Husson Angle Chiaroni Claude Riche 《Journal of heterocyclic chemistry》1991,28(3):705-709
The title compound, containing a new heterocyclic skeleton, was identified by X-ray crystallography as the product of condensation of (R)-phenylglycinol with an excess of formaldehyde. The molecule adopts a rigid double twist-chair conformation in both solid and solution states. 相似文献
5.
Michèle Audin 《manuscripta mathematica》2007,124(4):533-550
In this paper, we investigate symplectic manifolds endowed with a Morse–Bott function with only two critical submanifolds,
one of which is Lagrangian while the other one is symplectic. 相似文献
6.
Jan-Martin Heldt Michèle Salmain Gérard Jaouen 《Journal of organometallic chemistry》2004,689(25):4775-4782
The first poly(amidoamine) (PAMAM) dendrimers tethered with both (η5-cyclopentadienyl) rhenium tricarbonyl (CpRe(CO)3) units and polyethylene glycol (PEG) chains were prepared and characterized by combining NMR spectroscopy and Fourier-transform IR spectroscopy. Grafting of CpRe(CO)3 units was achieved by reductive amination of formyl-CpRe(CO)3 with the peripheral amines of generation 3 and 4 PAMAMs to yield dendrimers labeled with a variable number of CpRe(CO)3 units, ranging from 8 to 14 for PAMAM-G3 and 17-30 for PAMAM-G4. PEG chains of different lengths were then attached to some of the remaining peripheral amines, and their respective ability to improve the solubility of the metallodendrimers in aqueous buffered media was evaluated. These metallodendrimers represent new infrared probes designed to be coupled to immunological reagents for the amplification of the IR signal in carbonyl metallo immunoassay (CMIA). 相似文献
7.
Gisèle Cory-Goulard 《Czechoslovak Journal of Physics》1986,36(8):971-975
Experimental measurements and theoretical calculations are discussed for theA = 3 nuclei. With the sum rule formalism, the need for a better bound state is investigated. Some reactions on3He and3H like electron scattering, photodisintegration,-capture involve transitions to the continuum but with the work developed by Merkuriev, Gignoux and Laverne (1976) some progress is possible. The same realisticNN interactions used for calculating the bound state wave function of the three nucleon system are incorporated in the scattering equations based on the Faddeev approach.Presented at the symposium Mesons and Light Nuclei, Bechyn, Czechoslovakia, May 27–June 1, 1985. 相似文献
8.
Colette Deschamps-Vallet Jean-Baptiste Ilots Michle Meyer-Dayan Darius Molho 《Journal of heterocyclic chemistry》1982,19(1):97-101
3-Phenyl-1-benzopyrylium percholorates 1a, 1i react exculusively at C-2 with ethanol and isopropyl alcohol, affording mixed acetals 2a, 3a, 3i . Aqueous ammonia gives symmetrical secondary amines 4a, 4b or bis(3-phenyl-2H-1-benzopyran-2-yl)amines, while with aqueous aliphatic amines (40%) bis-acetals 5a, 5b or 2,2′-oxy-bis(3-phenyl-2H-1-benzopyrans) are characterized. In some other acidic conditions, 5a and 5b are also obtained. 相似文献
9.
Peter Lindemann Silvia E. Braslavsky Marie-Michle Cordonnier Lee H. Pratt Kurt Schaffner 《Photochemistry and photobiology》1993,58(3):417-424
Abstract–Thc kinetics of the microsecond phototransformation intermediates of 124 kDa Avena phytochrome (17001,2) were studied in the prcsence of bound monoclonal antibodies at various temperatures. A global analysis was applied to the decays at all wavelengths at each temperature in order to derive the rate constants and the decay-associated spectra of the three decay components. Monoclonal antibodies bound to specific epitopes altered the Arrhenius parameters of both 17001,2 decay components. The strongest influence on these parameters was observed with OAT 8 (epitope between residues 624 and 686), which decreased by more than 50% the activation parameters of both components. This decrease is interpreted to result from an increased flexibility induced by this antibody in the ground state or in the transition state of bonds changing during the decay of both 1700 transients. Thus, the OAT 8 cpitope appears to be functionally important during the decay of the 17001,2 intermediates. For the case of 11001 bound OAT 23 and OAT 25 (epitopes between residues 1 and 66) reduced even further the relatively small flexibility of these bonds in the red light-absorbing form of phytochrome (P1) without antibodies, as reflected by the high preex-ponential factors for its decay. This resulted also in higher activation energies for this decay in the presence of the antibodies. Thus, the amino-terminus should act as a rigid spacer of the chromophore cavity without affecting it during the microsecond transformation, because the Arrhenius parameters for these decays are similar to those for small phytochrome. The possible implications of the influence of the various antibodies on the bleaching remaining after the decay of 17001,2 are discussed. 相似文献
10.
Vincent Lapinte Laurent Fontaine Vronique Montembault Irne Campistron Danile Reyx 《Journal of molecular catalysis. A, Chemical》2002,190(1-2):117-129
ROMP and retro-acyclic diene metathesis (ADMET) were used for the synthesis of new functional polymers and functional oligomers, respectively. Purely exo and enantiomerically pure norbornene and 7-oxanorbornene derivatives were prepared using stereospecific synthesis, effective fractionation and high yield condensation reactions. Successful ROMPs of those monomers were performed using either the new carbenic Schrock’s or Grubb’s catalysts or in some cases a classical bicomponent catalyst. New functional polymers such as optically active poly(norbornene-2-carboxylic acid), reactive poly(norbornene-2-azlactone), and side-chain liquid crystal polyoxanorbornenes were fully characterized. On the other hand, successful depolymerizations of 1,4-polyisoprene and of epoxidized 1,4-polybutadiene via cross-metathesis with 4-octene were performed using a stabilized bicomponent catalyst and the Grubb’s catalyst, respectively. Conditions for the controlled synthesis of epoxidized oligobutadienes and of epoxydienic monomers via retro-ADMET were clearly defined. 相似文献