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1.
Erzs bet Ill s Etelka Tomb cz 《Colloids and surfaces. A, Physicochemical and engineering aspects》2003,230(1-3):99-109
The ionic strength dependence of humic acid (HA) adsorption on magnetite (Fe3O4) was investigated at pH 5, 8 and 9, where variable charged magnetite is positive, neutral and negative, respectively. The adsorption studies revealed that HA has high affinity to magnetite surface especially at lower pH, where interacting partners have opposite charges. However, in spite of electrostatic repulsion at pH 9 notable amounts of humate are adsorbed. Increasing ionic strength enhances HA adsorption at each pH due to charge screening. The dominant interaction is probably a ligand-exchange reaction, nevertheless the Coulombic contribution to the organic matter accumulation on oxide surface is also significant under acidic condition. The results from size exclusion chromatography demonstrate that the smaller size HA fractions enriched with functional groups are adsorbed preferentially on the surface of magnetite at pH 8 in dilute NaCl solution. 相似文献
2.
Báthori M Pongrácz Z Tóth G Simon A Kandra L Kele Z Ohmacht R 《Journal of chromatographic science》2002,40(7):409-415
A new ecdysteroid glycoside, 2-deoxy-20-hydroxyecdysone 22-O-beta-D-glucopyranoside, is isolated from the herb Silene italica ssp. nemoralis (Waldst. and Kit.) Nyman. The compound is purified with multistep chromatography, such as classical column chromatography on alumina and droplet countercurrent distribution. Also, it is expanded using twice low-pressure reversed-phase liquid column chromatography. Chromatography in four steps results in the purified 2-deoxy-20-hydroxyecdysone 22-O-beta-D-glucopyranoside. Two other ecdysteroids have also been separated, including the formerly identified integristerone A and 24(28)-dehydromakisterone A. 相似文献
3.
Adams MR Aïd S Anthony PL Averill DA Baker MD Baller BR Banerjee A Bhatti AA Bratzler U Braun HM Breidung H Busza W Carroll TJ Clark HL Conrad JM Davisson R Derado I Dhawan SK Dietrich FS Dougherty W Dreyer T Eckardt V Ecker U Erdmann M Faller F Fang GY Figiel J Finlay RW Gebauer HJ Geesaman DF Griffioen KA Guo RS Haas J Halliwell C Hantke D Hicks KH Hughes VW Jackson HE Jancso G Jansen DM Jin Z Kaufman S Kennedy RD Kinney ER Kirk T Kobrak HG Kotwal AV Kunori S Lancaster S Lord JJ Lubatti HJ 《Physical review letters》1995,74(9):1525-1529
4.
T.?GrygarEmail author T.?Rojka P.?Bezdi?ka E.?Ve?erníková F.?Kovanda 《Journal of Solid State Electrochemistry》2004,8(4):252-259
Mixed Cu,Mn, Cu,Mn,Al, Cu,Mg,Mn, and Cu,Mg,Mn,Al oxides were obtained by calcination of amorphous basic carbonate (Cu,Mn oxides) or hydrotalcite-like precursors at 300–800 °C. The product composition was characterized by chemical analysis, XRD, and voltammetry of the microparticles. The XRD amorphous portion was detected indirectly by XRD and directly by voltammetry. Tenorite (CuO) and spinels were the main crystalline components of the oxide mixtures. The presence of Al shifted the onset of the crystallization of XRD-detectable tenorite and spinel to temperatures higher by 100–200 °C, and the presence of Mg shifted tenorite crystallization by 100 °C, but voltammetry was able to detect these phases even in XRD-amorphous or nanocrystalline calcines. Voltammetry is hence suitable for analysis of poorly crystalline oxides that can be used in heterogeneous catalysis. 相似文献
5.
A comparison of sequential extraction techniques for determining arsenic fractionation in synthetic mineral mixtures 总被引:6,自引:0,他引:6
The sequential extraction methods according to Tessier et al. [1], Borovec et al. [2], Zhang and Moore [3] and Hall et al. [4] have been tested for their suitability for arsenic fractionation in samples of artificially prepared mineral mixtures. Mixtures containing different amounts of As-containing phases were prepared so that their compositions corresponded to weathering products on As-bearing ore deposits. A comparison of different procedures on simple mineral mixtures containing calcium arsenate (CaHAsO4·H2O), As-bearing goethite (FeOOH) and arsenopyrite (FeAsS) showed that only the results of the Hall method satisfactorily correspond to the expected arsenic distribution. A detailed verification of the Hall method was subsequently carried out on most complex synthetic mineral mixtures with varying amounts of As-containing kaolinite and carbonate, calcium arsenate, As-bearing goethite and arsenopyrite. The results confirm that the Hall method cannot be fully employed for an accurate As speciation but may be applied for a route identification of As distribution between "labile", "medium-labile" and "residual" forms in heavily polluted soils. 相似文献
6.
The polarographic behaviour of 2-nitronaphthalene was investigated by DC tast polarography (DCTP) and differential pulse polarography (DPP), both at a dropping mercury electrode, and differential pulse voltammetry and adsorptive stripping voltammetry, both at a hanging mercury drop electrode. Optimum conditions have been found for the determination of 2-nitronaphthalene by the given methods in the concentration ranges of 2×10–6–1×10–4, 2×10–7–1×10–4, 1×10–8–1×10–4 and 2×10–9–1×10–8 M, respectively. Practical applicability of these techniques was demonstrated by the determination of 2-nitronaphthalene in drinking and river water after its preliminary separation and preconcentration using liquid–liquid and solid-phase extraction with limits of determination of 3×10–10 M (drinking water) and 3×10–9 M (river water). 相似文献
7.
Spevácková V Korunová V Cejchanová M Vobecký M 《Analytical and bioanalytical chemistry》2004,380(2):346-350
A sampling procedure appropriate for the determination of mercury in whole blood was tested by using both inactive controls and a 197Hg mercury radio-indicator. To exclude the influence of the instrumental device (an AMA 254 single-purpose mercury atomic absorption spectrometer) on the determination of mercury in whole blood, the function of the instrument was checked by using rat blood with metabolised 197Hg. The measurement procedure was found to be free of errors. However, the study showed that the material used for the sampling vessels is a crucial parameter for obtaining accurate analytical results. The stability of solutions and samples was tested towards polyethylene (PE) and polypropylene (PP) vessels. PE displayed a time-dependent increase in the mercury content both in the samples and in the blood control material. The probable cause of this increase was direct contamination from the material of the vessel and/or diffusion of mercury from the environment through the vessel walls related to a strong complexing affinity of the sample matrix. This assumption was confirmed by supplying the vessels with the complexing agent Na2EDTA (0.05 mol L–1). Commercial PP vessels for blood sampling (Sarstedt S-Monovette Metall Analytik) did not give rise to statistically significant variations in mercury content in the samples and blood control material over a 30-day period. 相似文献
8.
9.
Barrett B Borek-Dohalský V Fejt P Vaingátová S Huclová J Nemec B Jelínek I 《Analytical and bioanalytical chemistry》2005,383(2):210-217
A validated, highly sensitive, and selective HPLC method with MS–MS detection has been developed for quantitative determination
of azithromycin (AZI) in human Na2EDTA plasma. Roxithromycin (ROX) was used as internal standard. Human plasma containing AZI and internal standard was ultrafiltered
through Centrifree Micropartition devices and the concentration of AZI was determined by isocratic HPLC–MS–MS. Multiple reaction
monitoring mode (MRM) was used for MS–MS detection. The calibration plot was linear in the concentration range 2.55–551.43 ng mL−1. Inter-day and Intra-day precision and accuracy of the proposed method were characterized by R.S.D and percentage deviation,
respectively; both were less than 8%. Limit of quantification was 2.55 ng mL−1. The proposed method was used to determine the pharmacokinetic profile of AZI (250-mg tablets). 相似文献
10.
A novel reversed-phase high-performance liquid chromatographic (RP-HPLC) method was developed and validated for the determination of active component triamcinolone acetonide, its degradation product triamcinolone (occurring in formulation after long-term stability tests) and two preservatives presented in the cream-methylparaben and propylparaben, using hydrocortisone as an internal standard.The chromatographic separation was performed on a Supelco Discovery C18 column; the mobile phase for separation of all compounds consists of a mixture of acetonitrile and water (40:60 v/v). The analysis time was less than 9 min, at a flow rate of 0.6 mL min(-1) and detection at 240 nm. The method was found to be applicable for routine analysis (stability tests, homogeneity) in the pharmaceutical product topical cream Triamcinolon cream 0.1%. 相似文献