全文获取类型
收费全文 | 81篇 |
免费 | 1篇 |
专业分类
化学 | 31篇 |
晶体学 | 6篇 |
数学 | 4篇 |
物理学 | 41篇 |
出版年
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 1篇 |
2014年 | 1篇 |
2013年 | 1篇 |
2012年 | 2篇 |
2011年 | 6篇 |
2010年 | 3篇 |
2009年 | 1篇 |
2008年 | 4篇 |
2007年 | 1篇 |
2006年 | 2篇 |
2005年 | 3篇 |
2004年 | 2篇 |
2003年 | 1篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 5篇 |
1998年 | 2篇 |
1996年 | 1篇 |
1995年 | 6篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1991年 | 1篇 |
1990年 | 1篇 |
1989年 | 1篇 |
1988年 | 4篇 |
1987年 | 6篇 |
1986年 | 6篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有82条查询结果,搜索用时 31 毫秒
1.
2.
3.
Zwanziger JW 《Solid state nuclear magnetic resonance》2005,27(1-2):5-9
Cluster models of boron oxide glasses are studied computationally using density functional theory. It is shown that the isotropic chemical shielding of boron in boroxol rings is about 5 ppm less than for boron in non-ring BO3/2 units, and that the quadrupole coupling in ring sites is about 0.1 MHz larger than in non-ring sites, confirming assignments made in glasses and crystalline model compounds. The chemical shielding anisotropy of these sites is computed and shown to be in agreement with recent experimental measurements. Furthermore, it is shown that the reason for the different responses is not the co-planarity of BO3/2 groups bound in rings, but rather the contraction in the B-O-B bond angle from about 134 degrees in relaxed structures to 120 degrees as found in rings. 相似文献
4.
The two-dimensional anisotropy-correlated NMR (2DAC) spectra of half-integer quadrupolar nuclei may be recorded by using an exchange sequence in conjunction with magic angle spinning (MAS) during evolution and detection, and off-MAS during mixing. Application of this experiment to boron oxides is described, in addition to an analysis of the spin diffusion rates in such materials. 相似文献
5.
6.
7.
MacDonald JL Werner-Zwanziger U Chen B Zwanziger JW Forgeron D 《Solid state nuclear magnetic resonance》2011,40(2):78-83
43Ca and 13C NMR methods were used to study the chemical interaction of poly(ethylene–vinyl acetate) (PEVAc) admixture in commercial-grade white cement. From 43Ca NMR it is shown both that PEVAc induces modest changes in the hydrated cement structure, and that hydrated commercial cement is significantly more complex than models that have been used for its structure in past work. The 13C NMR results show that the PEVAc hydrolysis occurs early in the cement hydration acceleration period, with a rate well-fit by an exponential decay using a time constant of 6±1 days. 相似文献
8.
Using the approach of Rulla (1996 SIAM J. Numer. Anal. 33, 68-87)for analysing the time discretization error and assuming moreregularity on the initial data, we improve on the error boundderived by Barrett and Blowey (1996 IMA J. Numer. Anal. 16,257-287) for a fully practical piecewise linear finite elementapproximation with a backward Euler time discretization of amodel for phase separation of a multi-component alloy. 相似文献
9.
Analytical and Bioanalytical Chemistry - 相似文献
10.
A non-compact lattice model of quantum chromodynamics is studied numerically. Whereas in Wilson's lattice theory the basic variables are the elements of a compact Lie group, the present lattice model resembles the continuum theory in that the basic variables A are elements of the corresponding Lie algebra, a non-compact space. The lattice gauge invariance of Wilson's theory is lost. As in the continuum, the action is a quartic polynomial in A, and a stochastic gauge fixing mechanism - which is covariant in the continuum and avoids Faddeev-Popov ghosts and the Gribov ambiguity — is also transcribed to the lattice. It is shown that the model is self-compactifying, in the sense that the probability distribution is concentrated around a compact region of the hyperplane div A = 0 which is bounded by the Gribov horizon. The model is simulated numerically by a Monte Carlo method based on the random walk process. Measurements of Wilson loops, Polyakov loops and correlations of Polyakov loops are reported and analyzed. No evidence of confinement is found for the values of the parameters studied, even in the strong coupling regime. 相似文献