Radiometrische Bandwaage mit Rechnerschaltkreis zur Signalaufbereitung

Es wird eine radiometrische Bandwaage zur Koksaustragsmengen-Messung in BHT-Kokereien beschrieben. Voranstellend werden einige analytische Ausdrücke zur theoretischen Behandlung dieses Bandwaagentyps mitgeteilt. Die Waage zeichnet sich durch hohe Stabilität der Anzeige, durch die Möglichkeit des routinemäßigen Umsetzens von Meßstelle zu Meßstelle innerhalb kurzer Zeit und durch einen relativ kleinen Wägefehler (Meßunsicherheit ≦ 2,9%) aus. Die Signalaufbereitung innerhalb der Elektronik erfolgt durchgängig digital unter Verwendung eines Rechnerschaltkreises.     

Measurement of odour permeability of polypropylene packaging films at low odourant levels

An apparatus has been designed to measure the permeability coefficients of packaging films to odours at low odour concentration gradients. Use of the apparatus is illustrated by comparison between the permeation behaviour of coextruded and coated polypropylene packaging films, using the test odourants benzyl acetate, 2-methoxyphenol and limonene. For the coextruded films, permeability coefficients decrease logarithmically with concentration at odour levels in the parts per million range. The coated films exhibit more complex behaviour; at low concentrations extremely long induction periods occur prior to odourant detection, whilst at higher odourant levels the barrier coatings become less effective and the permeability coefficients approach those of coextruded film.     

Manipulations of listeners' echo perception are reflected in event-related potentials

To gain information from complex auditory scenes, it is necessary to determine which of the many loudness, pitch, and timbre changes originate from a single source. Grouping sound into sources based on spatial information is complicated by reverberant energy bouncing off multiple surfaces and reaching the ears from directions other than the source's location. The ability to localize sounds despite these echoes has been explored with the precedence effect: Identical sounds presented from two locations with a short stimulus onset asynchrony (e.g., 1-5 ms) are perceived as a single source with a location dominated by the lead sound. Importantly, echo thresholds, the shortest onset asynchrony at which a listener reports hearing the lag sound as a separate source about half of the time, can be manipulated by presenting sound pairs in contexts. Event-related brain potentials elicited by physically identical sounds in contexts that resulted in listeners reporting either one or two sources were compared. Sound pairs perceived as two sources elicited a larger anterior negativity 100-250 ms after onset, previously termed the object-related negativity, and a larger posterior positivity 250-500 ms. These results indicate that the models of room acoustics listeners form based on recent experience with the spatiotemporal properties of sound modulate perceptual as well as later higher-level processing.     

Gamma-spectroscopic investigations on 67Ge

By γ-γ coincidence measurements following the ⁵⁷Fe(¹²C, 2nγ) reaction at E_12C = 40 MeV several new states above 1.5 MeV excitation energy in ⁶⁷Ge have been established. Spin and parity assignments on the basis of the angular distribution, linear polarization and γ-ray yield function indicate very similar structures in ^{67, 69}Ge. The positive-parity states can be followed up to the $\text{17}\text{2}{}^{\mathrm{+}}$ state at E_x = 3.07 MeV followed by a sequence of negative-parity high-spin states at nearly the same excitation energy relative to the $\text{9}\text{2}{}^{\mathrm{+}}$ single-particle state as in the neighbouring nucleus ⁶⁹Ge where these states were found to have strong single-particle admixtures. A reinvestigation of the spin of the E_x = 2.75 MeV level in ⁶⁹Ge resulting in a change of its spin from $\text{15}\text{2}{}^{\mathrm{+}}\text{to}\text{17}\text{2}{}^{\mathrm{+}}$ and for all spins above, removed the discrepancy concerning the spin assignments of corresponding levels in ^{67, 69}Ge. The excitation pattern of the Ge isotopes with 34 ≦ N ≦ 39 clearly indicate same structures probably due to the strong competition between collective and single-particle excitations along the whole chain similar to the results for the Zn isotopes.     

C–H⋅<Emphasis Type="Italic">s</Emphasis>O hydrogen bond networks in <Emphasis Type="Italic">E</Emphasis>- and Z-unsaturated esters of C-glycosides

Methyl E(Z)-4,7 anhydro-5-benzamido-6,8-di-O-benzoyl-2,3,5-trideoxy-d-allo-oct-2-enoate have been synthesized like intermediates and isolated as single crystals during the synthesis of pyrazole-related C nucleosides as synthetic product with cytotoxic activity.¹ Crystal structures of E(Z) isomers were determined by X-ray analysis. E isomer crystallizes in the triclinic crystal system, space group P1, a = 5.319(1) Å, b = 10.758(2) Å, c = 12.229(2) Å, α = 72.38(2)^∘, β = 89.97(2)^∘, γ = 87.07(2)^∘, D_x = 1.320 Mgm⁻³ and Z isomer in the orthorhombic crystal system, space group P2₁2₁2₁, a = 5.1297(13) Å, b = 19.667(5) Å, c = 25.871(6) Å, D_x = 1.348 Mgm⁻³. The molecular structure was solved by direct method on the basis of 2609 and 2727 unique reflections recorded at the temperature 293 K (E-isomer) and 173 K (Z-isomer) up to the final R-factor 0.0378 and 0.0435, respectively. C–H⋅sO contact networks were analyzed and the correlation established between the existence of the weak C–H⋅sO hydrogen bonds and the melting point of the single crystals.     

Efficient Reverse Intersystem Crossing in Carbene-Copper-Amide TADF Emitters via an Intermediate Triplet State

The mechanism behind reverse intersystem crossing (rISC) in metal-based TADF emitters is still under debate. Thermal rISC necessitates small singlet/triplet energy gaps as realized in donor-acceptor systems with charge-transfer excited states. However, their associated spin-orbit couplings are too small to account for effective rISC. Here, we report the first nonadiabatic dynamics simulation of the rISC process in a carbene-copper(I)-carbazolyl TADF emitter. Efficient rISC on a picosecond time scale is demonstrated for an initial triplet minimum geometry that exhibits a perpendicular orientation of the ligands. The dynamics involves an intermediate higher-lying triplet state of metal-to-ligand charge transfer character (³MLCT), which enables large spin-orbit couplings with the lowest singlet charge transfer state. The mechanism is completed in the S₁ state, where the complex can return to a co-planar coordination geometry that presents high fluorescence efficiency.     

Spin state transition in LaCoO3 studied using soft x-ray absorption spectroscopy and magnetic circular dichroism

Using soft x-ray absorption spectroscopy and magnetic circular dichroism at the Co-L(2,3) edge, we reveal that the spin state transition in LaCoO3 can be well described by a low-spin ground state and a triply degenerate high-spin first excited state. From the temperature dependence of the spectral line shapes, we find that LaCoO3 at finite temperatures is an inhomogeneous mixed-spin state system. It is crucial that the magnetic circular dichroism signal in the paramagnetic state carries a large orbital momentum. This directly shows that the currently accepted low- or intermediate-spin picture is at variance. Parameters derived from these spectroscopies fully explain existing magnetic susceptibility, electron spin resonance, and inelastic neutron data.     

Transients from a mixture of [(R(O)Sn)2C(CH3)2]2 and (RCl2Sn)2C(CH3)2 [R = (SiMe3)2CH]: an identification in situ by 1D 119Sn and 2D 1H?119Sn HMQC NMR spectroscopy and electrospray mass spectrometry

The reaction of the 2,2‐bis(organodichlorostannyl)propane [(Me₃Si)₂CH(Cl₂)Sn]₂CMe₂ (A) with the corresponding organotin oxide {[(Me₃Si)₂CH(O)Sn]₂CMe₂}₂ (B) does not provide the corresponding normally expected tetraorganodistannoxane {[(Me₃Si)₂CH(Cl)SnCMe₂Sn(Cl)CH(SiMe₃)₂]O}_n but a complex reaction mixture. One major product, namely the 2,4,6,8‐tetraorgano‐2,6‐dichloro‐1,5,9‐trioxa‐2,4,6,8‐tetrastannabicyclo[3.3.1]nonane derivative [(Me₃Si)₂CHSnCMe₂Sn(Cl)CH(SiMe₃)₂]₂O₃ (C) was identified in situ by 2D ¹H? ¹¹⁹Sn and ¹H? ¹³C heteronuclear multiple quantum coherence and heteronuclear multiple bond correlation NMR spectroscopy as well as electrospray mass spectrometry. Compound C is proposed to be in equilibrium with an ionic species C′, the cation of which has an adamantane‐type structure. Copyright © 2003 John Wiley & Sons, Ltd.