Dual cocatalysts decorated three dimensionally ordered mesoporous g-C3N4 with homogeneous wall thickness for enhanced photocatalytic performance

Making several components be more intimate interfacial contacts in the photocatalyst is an efficient strategy to improve the separation and transfer of photogenerated charge carries and enhance the photocatalytic performance in the visible light region. In this work, a promising photocatalyst was fabricated by loading of Au nanoparticles and Cd_(0.58)Zn_(0.42)S nanoparticles onto the three dimensionally ordered mesoporous g-C₃N₄ material (Au/3DOM CN/Cd_(0.58)Zn_(0.42)S) via two-step synthesis method to significantly intensify the transfer capability of charge. The results of characterization demonstrate that Au/3DOM CN/Cd_(0.58)Zn_(0.42)S photocatalyst possesses the intimate interfacial contacts of three components and homogeneous wall thickness of 3DOM g-C₃N₄ framework, and these properties give Au/3DOM CN/Cd_(0.58)Zn_(0.42)S photocatalyst an ability that it can harvest a wider range of visible light and endow it superior photocatalytic activities for hydrogen evolution from water splitting and RhB degradation. Finally, a possible mechanism was proposed based on the photoelectrochemical measurement. This work would provide a new strategy to design and fabricate g-C₃N₄-based with 3DOM architecture materials with superior photocatalytic activity.     

输电线路爆破除冰动态特性

为研究输电线路爆破除冰效果及动态特性,进行了50 m孤立档输电线路爆破除冰模型实验,采用人工覆冰方式,通过引爆预设在输电线下侧的导爆索去除部分线路覆冰,测量了爆破除冰过程中三种输电线档中位移和端部动张力,并将爆破载荷简化为三角波载荷,利用有限元软件ABAQUS对实验工况进行了模拟验证;进一步利用模拟方法研究了爆破除冰量为20%时除冰位置对跳跃幅值和动张力的影响。结果表明:对于雨凇,爆破作用只会引起输电线爆破区域的覆冰脱落;爆破除冰时跳跃幅值和动张力幅值均大于相同位置自然脱冰,而随除冰位置的变化趋势与自然脱冰相似;与导线相比,地线光缆的跳跃幅值受爆破作用影响更显著。     

关于求解线性规划问题的分解筛选法

本文举例证明了文［１］［２］提出的求解一般线性规划问题的分解筛选法是错误的。     

Optimizing electronic structure and charge transport of sulfur/potassium co‐doped graphitic carbon nitride with efficient photocatalytic hydrogen evolution performance

Recently, graphitic carbon nitride (CN) has been widely investigated for solar energy conversion through water splitting, but its low photocatalytic activity needs to be further improved and optimized. Herein, S/K co‐doped CN photocatalysts have been fabricated by condensation of thiourea and dithiooxamide followed by post‐treatment in molten salt. As evidenced by XRD patterns and UV–vis DRS plots, the engineering crystalline and electronic structure of all as‐prepared samples have been explored through tailoring the mass ratio of thiourea and dithiooxamide as well as ratio of molten salt/the precursor. After optimization, the as‐prepared S/K co‐doped CN photocatalysts with needle‐like nanorods structure exhibit excellent hydrogen evolution rate of 1962.10 μmol^?1 g^?1 h^?1. While its photocatalytic activity is lower than that of pure CN by molten salt treatment (K‐doped CN) (2066.40 μmol^?1 g^?1 h^?1), which results from that the K content of S/K co‐doped CN photocatalyst is lower than that of K‐doped CN. Moreover, compared with K‐doped CN, S/K co‐doped CN photocatalyst possesses higher photocatalytic performance when irradiated by a light source (λ > 520 nm). This might be ascribed to the fact that the introduction of sulfur can expand light absorption region (λ > 520 nm), whereas K cannot improve light absorption of CN in this wavelength region. Furthermore, DFT calculation reveals that both S and K atoms can offer more electrons to band gap, leading to the formation of metallic‐character band structure. In addition, K atom can intercalate in the interlayer of CN and bridge the adjacent two layers, leading to the formation of charge delivery channels. These results demonstrate that S/K co‐doped CN photocatalysts facilitate the separation and transport of photogenerated charge carries, resulting in the efficient photocatalytic activity for hydrogen evolution. Besides, a competition between sulfur and potassium atom during the synthesis process is also discussed in details.     

Fabrication of AgI/MIL‐53(Fe) Composites with Enhanced Photocatalytic Activity for Rhodamine B Degradation under Visible Light Irradiation

AgI/MIL‐53(Fe) composites were fabricated through a simple solution method, and their photocatalytic activities on Rhodamine B (RhB) degradation were investigated. The results demonstrated that the introduction of AgI into the MIL‐53(Fe) was beneficial to the enhanced visible light response. Under visible light irradiation, almost 100 % RhB was bleached over AgI/MIL‐53(Fe) composites after 180 min. The promising photocatalytic performance was ascribed to three points: the existence of AgI helped to generate easily the electrons and holes in the composites; an intimate interfacial contact between MIL‐53 (Fe) and AgI offered the path for the charge carries transport; MIL‐53 (Fe) could fast transfer the excited electrons due to its inherent nature. Thus, these results were responsible for the effective inhibition of charge carrier recombination, resulting in an improved photocatalytic activity.     

Needs and trends in rational synthesis of zeolitic materials

Zeolites are an important class of materials which are widely used in industry as catalysts, adsorbents and ion-exchangers. Their superior properties are closely related to their unique porous framework structure, as well as composition and morphology. The ever-growing needs for zeolitic materials in applications inspire us to think of the rational synthesis of zeolites with desired structures and properties. However, rationalization of zeolitic materials remains one of the most challenging issues in the zeolite research field due to their unclear formation mechanism. Despite this, many efforts have been devoted to synthesize zeolites in a more rational way. In this tutorial review, first, we demonstrate how the geometrical characteristics of zeolite frameworks affect the catalytic performances of the resulting materials; then, we present recent advances in synthetic innovations to target materials, and we further highlight the developments in computer simulations toward ab initio design and synthesis; finally, the future perspective on the rational synthesis of zeolitic materials with desired functions and structures will be described.     

Faithful Multihop Two-Qubit Transmission Through GHZ-GHZ Channel

Quantum teleportation is an important method for transmitting quantum states between two quantum communication nodes. In this paper, we propose a low-latency quantum communication scheme based on Greenberger-Horne-Zeilinger (GHZ) state. To implement two-qubit transmission, the source and all intermediate nodes perform quantum measurements simultaneously and the measurement results are transmitted to the destination node through classical channel independently. The destination node performs appropriate unitary operation on its particles to recover the original two-qubit state based on received measurement results. Our scheme effectively reduces the end-to-end quantum communication delay.