The ability of malic acid to control calcium carbonate morphology has been investigated by aging calcium chloride solution in the presence of urea in a 90 °C bath. Malic acid favors the formation of calcite. A transition from single block to aggregate with special morphology occurs upon increasing malic acid concentration. The morphological development of CaCO3 crystal obviously depends on the starting pH. CaCO3 crystal grows from spindle seed to dumbbell in the pH regime from 7 to 11; while it evolves from spindle seed, through peanut, to sphere at pH=11.5. Both dumbbell and sphere consist of rods that are elongated along c-axis and capped with three smooth, well-defined rhombic {1 0 4} faces. A tentative growth mechanism is proposed based on the fractal model suggested by R. Kniep and S. Busch [Angew. Chem. Int. Ed. Engl. 35 (1996) 2624]. 相似文献
Carbon quantum dots (CQDs) co-doped with N, P and S derived from expired milk was prepared by a simple hydrothermal method. By dipping pure cotton face towel (PCFT) into CQDs ink, a flexible all-biomass CQDs/PCFT sensor was prepared for the first time. Due to the heteroatom doping, extremely small particle size of CQDs and excellent permeability of CQDs/PCFT film, the flexible CQDs/PCFT sensor showed the high sensitivity and bending stability. In the range of 0–60° bending states, the responses of CQDs/PCFT sensor to four target analytes changed by less 5.0%. After 3000 bending of 60°, the maximum change of the response to the target analytes was only 6.4%. Interestingly, due to the abundant functional groups and defects of CQDs, the flexible CQDs/PCFT sensor displayed sensing curves of different shapes for different target analytes. In this way, by establishing a database of sensing curves of target analytes, multiple analytes can be detected discriminatively by relying only on single sensor with the help of image recognition. This work provided a reference for the development of cotton fiber based all biomass flexible gas sensor.
This paper presents a Bell-dual-basis-based quantum watermarking protocol composed of three major algorithms: watermark embedding and extracting and the intercepting test. The first two are completed by using the entanglement swapping property of Bell dual basis and the test is accomplished through IBF protocol to guarantee its bottom security. The watermarking protocol is mainly designed for the protection of digital copyright in the existence of classical information. This design finds that the quality of digital contents is not damaged with its zero-watermark attributes when embedding watermarks. 相似文献
In this paper, a platinum coating was deposited on titanium alloy substrate by a double glow plasma. Phase and microstructure of platinum coating were examined by X-ray diffraction and scanning electron microscopy, respectively. The microhardness of the coating was estimated by nanoindentation instrument. The adhesive force between the coating and the substrate was performed with scratch tester. The electrochemical behavior of the platinum coating in 3.5 wt % sodium chloride solution was investigated by potentiodynamic polarization. The results indicated that an adherent platinum coating could be successfully obtained on titanium alloy substrates. Compared with the titanium alloy substrate, the platinum coating had a relative low corrosion current density and high corrosion potential. It indicated that the platinum coating had a better corrosion resistance than the titanium alloy substrate. 相似文献
In this study, a series of tetrafluoroborates with non-π-conjugated [BF4] tetrahedra are investigated systematically by first-principles calculations. Theoretical studies demonstrate that tetrafluoroborates with alkali and/or alkaline-earth metals are more favorable for deep-ultraviolet transmission and are comparable to the classical deep-ultraviolet (deep-UV) material, MgF2. Furthermore, bandgap decrease with the increasing of ionic radii in alkali and/or alkaline-earth metals. Introducing highly polarizable cations with d10-configuration or cations with lone pair electrons into the structure will decrease the bandgaps. The birefringence and second harmonic generation effects are not large enough in tetrafluoroborates because polarizability anisotropy and hyperpolarizability in non-π-conjugated [BF4] tetrahedra are much smaller than those in π-conjugated groups. However, the second harmonic generation effect for [BF4] tetrahedra has a higher contribution in comparison with that due to birefringence. To effectively synthesize the borate fluorides or fluorooxoborates in the deep-UV region, raw materials with B−F bonds are preferred. 相似文献
On a lattice with 2+1-flavor dynamical domain-wall fermions at the physical pion mass,we calculate the decay constants of D_s* , D* ,and φ .The lattice size is 48^3×96 ,which corresponds to a spatial extension of -5.5 fm,with a lattice spacing of a\approx a≈0.114 fm.For the valence light,strange,and charm quarks,we use overlap fermions at several mass points close to their physical values.Our results at the physical point are fD=213(5) MeV, fDs=249(7) MeV, fD*=234(6) MeV, fDs*=274(7) MeV,and fDs=241(9) MeV.The couplings of D* and D_s* to the tensor current( fVT )can be derived from ratios fD*^T/fD*=0.91(4) and fDs*^T/fDs*=0.92(4) ,respectively,which are the first lattice quantum chromodynamics(QCD)results.We also obtain ratios fD*/fD=1.10(3) and fDs*/fDs=1.10(4) ,which reflect the size of heavy quark symmetry breaking in charmed mesons.Ratios fDs/fD=1.16(3) and fDs*/fD*=1.17(3) can be taken as a measure of SU(3)flavor symmetry breaking. 相似文献
The strangeonium-like ss^-g hybrids are investigated from lattice QCD in the quenched approximation.In the Coulomb gauge,spatially extended operators are constructed for 1^--and(0,1,2)^-+states with the color octet ss^-component being separated from the chromomagnetic field strength by the spatial distance r,whose matrix elements between the vacuum and the corresponding states are interpreted as Bethe-Salpeter(BS)wave functions.In each of the(1,2)^-+channels,the masses and the BS wave functions are reliably derived.The 1^-+ground state mass is approximately 2.1-2.2 GeV,and that of 2^-+is approximately 2.3-2.4 GeV,whereas the mass of the first excited state is approximately 1.4 GeV higher.This mass splitting is much larger compared to that expected based on the phenomenological flux-tube model or constituent gluon model for hybrids,which is usually a few hundred MeV.The BS wave functions with respect to r exhibit clear radial nodal structures of a non-relativistic two-body system,which imply that r is a meaningful dynamical variable for these hybrids and motivate a color halo picture of hybrids,in which the color octet ss^-is surrounded by gluonic degrees of freedom.In the 1^--channel,the properties of the lowest two states are consistent with those ofФ(1020)andФ(1680).We did not obtain convincing information with respect toФ(2170).However,we argue that regardless of whetherФ(2170)is a conventional ss^-meson or a ss^-g hybrid in the color halo scenario,the ratio of partial decay widthsΓ(Фη)andΓ(Фη')observed by BESIII can be understood based on the mechanism of hadronic transition of a strangeonium-like meson in addition toη-η'mixing. 相似文献
MgO:Eu3+ nanocrystals with average diameter around 15 nm were prepared via a facile combustion method under a weak reductive atmosphere
at temperature as low as 300°C. The photoluminescence spectra showed that the MgO:Eu3+ nanocrystals emit white light, the hypersensitive transition (5D0→7Fj of Eu3+) emission was prominent in the emission spectra resulting from the noinversion symmetry local site at which Eu3+ ions were located. Two kinds of luminescence sites of Eu3+ are identified by means of the fluorescence decay and site-selective spectroscopy. The excitation and absorption spectra
indicated that the absorption of surface state decreased with the increase of Eu3+ concentration, meaning that the surface defect decreased through Eu3+ doping for some of them located at the disordered sites near the surface or absorbed at the surface of MgO host. Meanwhile,
absorptivity and CIE chromaticity coordinates of all samples were measured; the results were in accordance with the excitation
and absorption spectra and photoluminescence spectra, respectively. 相似文献