Effect of pH, temperature and solvent mole ratio on solubility of disodium 5′-guanylate in water + ethanol system

Solubility of disodium 5′-guanylate in water + ethanol binary solvent mixtures was determined by a gravimetric method in the temperature range from 283.15 K to 323.15 K, pH range from 8 to 10 and at different water/ethanol mole ratios. The effects of pH, temperature and water/ethanol mole ratio on the solubility were investigated in detail. The modified Apelblat model and the combined nearly ideal binary solvent (CNIBS)/Redlich-Kister model were selected to correlate the experimental data. The results showed that the experimental data was satisfactorily correlated by the (CNIBS)/Redlich-Kister model, but for the modified Apelblat model, the correlation was not so satisfactory in some cases.     

Response improvement for In2O3-TiO2 thick film gas sensors

In₂O₃ is introduced into TiO₂ by sol-gel method to improve the response/recovery rate and expand the operating temperature, when the In₂O₃-TiO₂ mixed system is exposed to H₂/O₂. The sensor is fabricated by thick film technology. Influence of In₂O₃ on the film phase composition, microstructure and sensing characteristics is discussed. Dynamic response properties show that the operating temperature of the mixed system is at 500-800 °C, which is about 600-800 °C for pure TiO₂. Response time of the sensor is about 200-260 ms (millisecond) while recovery time is in a narrow range of 60-280 ms at 600-800 °C. The promoting mechanism is suggested to arise from the introduction of In₂O₃ and grain size effect of the sensing film. Then In₂O₃-TiO₂ thick films are surface-modified by Pt using chloroplatinic acid. The promoting effect of Pt dispersed on the mixed system is also investigated.     

SHARP CRITERIONS OF GLOBAL EXISTENCE AND COLLAPSE FOR COUPLED NONLINEAR SCHRODINGER EQUATIONS

In this paper, a series of sharp criterions of global existence and collapse for coupled nonlinear Schr6dinger equations are derived out in terms of the characteristics of the ground state and the local theories. And the conclusion that how small the initial data are, the global solutions exist is proved.     

表面活性肽的研究进展

表面活性肽(Surfactin)是由枯草芽孢杆菌(Bacillus subtilis)发酵产生的一系列具有相似基本结构的环状脂肽。与合成的表面活性剂相比,Surfactin的优势在于,其是以碳氢化合物等可再生能源为原料、采用微生物发酵技术产生的纯天然产品,具有表面活性大、环境无污染、易生物降解、抑菌作用良好等优异特性,符合现代绿色化学发展理念,在多个领域应用广泛。本文详细介绍了Surfactin的基本结构、主要特性、生产工艺、纯化方式以及应用,并对Surfactin下一步的研究工作进行了展望,为今后关于Surfactin的进一步研究提供了便利。     

泡沫金属在冲击载荷下的动态压缩行为

基于微CT扫描影像信息,建立泡沫金属材料二维细观有限元模型,考虑不规则胞孔的不均匀分布,根据实验结果拟合孔壁材料的弹塑性本构参数。研究了泡沫金属在不同加载速度下的压缩变形机理,重点讨论泡沫金属中弹塑性波的传播、惯性效应和从冲击端传递到静止端的应力变化特征。对于相对密度为0.3的泡沫铝,弹性波速约为5 km/s,与孔壁材料的弹性波速相当,塑性波速表现为随着加载速度的增大而增大。在加载速度为50~100 m/s间变形模式从准静态模式转变为动态模式,未发现明显的临界速度,动态锁死应变随着加载速度的增大而增大。由于塑性波发生反射,试件会发生二次压缩过程,相应地,静止端产生二次应力平台。受惯性作用的影响,二次应力平台也随着加载速度的增大而提高。     

基于纳米二氧化硅与MCM-41的两种多相钯催化剂的合成及其在Suzuki反应中的应用

含氮膦配体的钯配合物被负载于纳米二氧化硅和MCM-41表面。由此得到的两种新型多相钯催化剂SiO2@PNPPdCl2（1）和MCM-41@PNPPdCl2（2）均通过SEM（EDX）、TEM（SAED）、XRD、FT-IR、ICP-MS和TGA等手段进行全面表征。微观结构表明,这两种纳米颗粒具有完全不同的结构,1为不规则球体,2具有蜂窝孔状结构。本文进一步研究了纳米粒子1和2在Suzuki偶联反应中以乙醇和水为溶剂的温和条件下的催化性能。研究显示两种催化剂均具有较好的基团耐受性,循环利用四次的平均产率分别为81%(1)和89%(2)。它们的催化性能也略有不同,催化剂1的催化速率高于2,催化剂2具有较好的循环利用性能。     

Adsorption and diffusion of H2O molecule on the Be(0001) surface: A density-functional theory study

Using first-principles calculations, we systematically study the adsorption behavior of a single molecular H₂O on the Be(0001) surface. We find that the favored molecular adsorption site is the top site with an adsorption energy of about 0.3 eV, together with the detailed electronic structure analysis, suggesting a weak binding strength of the H₂O/Be(0001) surface. The adsorption interaction is mainly contributed by the overlapping between the s and pz states of the top-layer Be atom and the molecular orbitals 1b₁ and 3a₁ of H₂O. The activation energy for H₂O diffusion on the surface is about 0.3 eV. Meanwhile, our study indicates that no dissociation state exists for the H₂O/Be(0001) surface.