Role of molecular symmetries in magneto-spatial dispersional change of the refractive index in fluids

Variations in refractive index due to the (B⁰ · k) effect are calculated for a circularly polarized light wave. The effect is related with the mechanism of nonlinear electron distortion in a field B⁰ described by an i-tensor of rank 4 and the reorientation mechanism represented by the product of two c-tensors, of ranks 3 and 1. The magnetic classes of molecules admitting of these mechanisms are determined.     

Uncertainty analysis of the standard delay-and-sum beamformer and array calibration

Beamforming has become an ubiquitous task in aeroacoustic noise measurements for source localization and power estimation. The standard delay-and-sum (DAS) beamformer is the most commonly used beamforming algorithm due to its simplicity and robustness and also serves as the basis for more sophisticated algorithms, such as the deconvolution approach for the mapping of acoustic sources (DAMAS). The DAS data reduction equation is a function of many parameters including the microphone locations, microphone transfer functions, temperature and the cross-spectral matrix (CSM), where each one of these parameters has a unique uncertainty associated with it. This paper provides a systematic uncertainty analysis of the DAS beamformer and Dougherty's widely used calibration procedure under the assumption that the underlying mathematical model of incoherent, monopole sources is correct. An analytical multivariate method based on a first-order Taylor series expansion and a numerical Monte-Carlo method based on assumed uncertainty distributions for the input variables are considered. The uncertainty of calibration is analyzed using the Monte-Carlo method, whereas the uncertainty of the DAS beamformer is analyzed using both the complex multivariate and the Monte-Carlo methods. It is shown that the multivariate uncertainty analysis method fails when the perturbations are relatively large and/or the output distribution is non-Gaussian, and therefore the Monte-Carlo analysis should be used in the general case. The calibration procedure is shown to greatly reduce the uncertainties in the DAS power estimates. In particular, 95 percent confidence intervals for the DAS power estimates are presented with simulated data for various scenarios. Moreover, the 95 percent confidence intervals for the integrated DAS levels at different frequencies are computed using experimental data. It is shown that with experimental data, the 95 percent confidence intervals for the integrated power levels are within of the mean levels when the component uncertainties are set at low but achievable values.     

Vinyl Cation Stabilization by Silicon Enables a Formal Metal‐Free α‐Arylation of Alkyl Ketones

The ability of silicon to stabilize vinyl cationic species leads to a redox arylation of alkynes whereby the stringent limitations of reactivity and regioselectivity of alkyl‐substituted alkynes are lifted. This allows the synthesis of a range of α‐silyl‐α′‐arylketones under mild conditions in good to excellent yields and with high functional group tolerance, whereby the silicon moiety in the final products can either be removed for a formal acetone monoarylation transform, or capitalized upon for subsequent electrophilic substitutions at either side of the carbonyl group.     

新开花粉蛋白的盐酸胍去折叠过程

本文利用荧光光谱和园二色光谱了新开花粉蛋白的盐酸胍去折叠过程。结果显示：新开花粉蛋白的盐酸胍去折叠是一个只包含天然蛋白和变性终态的二态过程,与已经报道的天花粉蛋白的盐酸胍去折叠的过程不同。     

Review of nanofluids for heat transfer applications

Research on nanofluids has progressed rapidly since its enhanced thermal conductivity was first repotted about a decade ago,though much controversy and inconsistency have been reported,and insufficient understanding of the formulation and mechanism of nanofluids further limits their applications.This work presents a critical review of research on heat transfer applications of nanofluids with the aim of identifying the limiting factors so as to push forward their further development.     

CD40mAb adjuvant induces a rapid antibody response that may be beneficial in post-exposure prophylaxis

Active vaccination can be effective as a post-exposure prophylaxis, but the rapidity of the immune response induced, relative to the incubation time of the pathogen, is critical. We show here that CD40mAb conjugated to antigen induces a more rapid specific antibody response than currently used immunological adjuvants, alum and monophosphoryl lipid A™.     

CeO<Subscript>2</Subscript> nanoparticle-modified electrode as a novel electrochemical interface in the quantification of Zn<Superscript>2+ </Superscript>ions at trace level: application to real sample analysis

A simple strategy has been proposed to quantify Zn²⁺ ions using CeO₂ nanoparticle-modified glassy carbon electrode. The CeO₂ nanoparticles were prepared by sucrose-nitrate decomposition method, and it was characterized by X-ray diffraction (XRD), FT-IR, TEM, and surface area analyzer. The synthesized CeO₂ nanoparticles were used as modifier molecules as a thin film on glassy carbon electrode (GCE) in the trace level quantification of Zn²⁺ by using cyclic voltammetry (CV) and differential pulse anodic stripping voltammetry (DPASV) techniques. The fabricated sensor exhibited a good analytical response towards Zn²⁺ ions. The modified electrode showed a wide linearity in the concentration range 20–380 μg L^?1 with a limit of detection 0.36 μg L^?1. The proposed electrochemical sensor was successfully applied to trace level Zn²⁺ quantification from real sample matrices.     

FTIR光谱法研究天花粉蛋白的热去折叠过程

本文利用ＦＴＩＲ光谱技术和计算机辅助解析技术（二阶导数、去卷积和曲线拟合）研究了天花粉蛋白的热诱导去折叠过程。结果表明：在２５～８５℃温度范围内,天花粉蛋白的热去折叠是一个不可逆的分子间聚集的过程;二级结构随温度的变化暗示了折叠中间体的存在。