排序方式: 共有23条查询结果,搜索用时 15 毫秒
1.
An efficient one-step method for the synthesis of fully substituted thiophenes, from thiomorpholides and α-halo ketones, was developed. A mechanism has also been proposed for the course of reaction. 相似文献
2.
Nitro aromatic compound can be obtained in high yields via nitration of aromatic compound with wet carbon-based solid acid and NaNO_3 under solvent free oxidation at room temperature. 相似文献
3.
Arash Shokrolahi Abbas Zali 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):454-460
Abstract Sulfonated condensed polynuclear aromatic (S-COPNA) resin was found to be a highly efficient, environmentally friendly, recyclable heterogeneous catalyst for the oxidation of alkyl and aryl sulfides to the corresponding sulfoxides or sulfones, in good yields under mild reaction conditions using 30% hydrogen peroxide as an oxidant. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements for the following free supplemental resource: Synthesis of the S-COPNA resin catalyst. Spectroscopic data for compounds. 相似文献
4.
Carbon‐based solid acid was used as a new catalyst for conversion of trimethylsilyl ethers to their corresponding ethers in heterogeneous mixtures. The experiments were done moderately at room temperature, and high yields in suitable times were obtained under these conditions. 相似文献
5.
Hassan Zali Boeini 《合成通讯》2013,43(19):2932-2938
1,3-Dibromo-5,5-diphenylimidazolidine-2,4-dione (N,N’-dibromo phenytoin) was efficiently used for the rapid conversion of thiobenzamides to the corresponding 3,5-diaryl-1,2,4-thiadiazoles in water–wet paste conditions. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications® to view the free supplemental file.
6.
H. Zali Boeini 《Journal of the Iranian Chemical Society》2009,6(3):547-551
A novel and simple method for rapid conversion of thioamides to the corresponding 1,2,4-thiadiazole derivatives was developed. It was shown that, thioamides undergo clean and efficient oxidation and cyclization in their conversion to 1,2,4-thiadiazoles using N-benzyl-DABCO-tribromide in wet solid-solid conditions. 相似文献
7.
Burtovoy V. S. Akimenko S. A. Artamonov A. V. Blik A. M. Brekhovskikh V. V. Gorin A. M. Donskov S. V. Inyakin A. V. Kolosov V. N. Kurshetsov V. F. Lishin V. A. Medynsky M. V. Mikhailov Yu. V. Obraztsov V. F. Polyakov V. A. Romanovsky V. I. Rykalin V. I. Sadovsky A. S. Samoilenko V. D. Stenyakin O. V. Uvarov V. A. Filin A. P. Khaustov G. V. Kholodenko S. A. Tchikilev O. G. Yushchenko O. P. Guschin E. N. Duk V. A. Kravtsov V. I. Kudenko Yu. G. Polyarush A. Yu. Filippov S. N. Khudyakov A. A. Bychkov V. N. Zalikhanov B. Zh. Kekelidze G. D. Lysan V. M. 《Journal of Experimental and Theoretical Physics》2020,131(6):928-939
Journal of Experimental and Theoretical Physics - On the statistics of ~1.7 × 108 interactions of positively charged kaons on copper nuclei, coherent events of the K+π0 system production... 相似文献
8.
Fariba Fathi Laleh Majari‐Kasmaee Ahmad Mani‐Varnosfaderani Anahita Kyani Mohammad Rostami‐Nejad Kaveh Sohrabzadeh Nosratollah Naderi Mohammad Reza Zali Mostafa Rezaei‐Tavirani Mohsen Tafazzoli Afsaneh Arefi‐Oskouie 《Magnetic resonance in chemistry : MRC》2014,52(7):370-376
The present study was designed to search for metabolic biomarkers and their correlation with serum zinc in Crohn's disease patients. Crohn's disease (CD) is a form of inflammatory bowel disease that may affect any part of the gastrointestinal tract and can be difficult to diagnose using the clinical tests. Thus, introduction of a novel diagnostic method would be a major step towards CD treatment. Proton nuclear magnetic resonance spectroscopy (1H NMR) was employed for metabolic profiling to find out which metabolites in the serum have meaningful significance in the diagnosis of CD. CD and healthy subjects were correctly classified using random forest methodology. The classification model for the external test set showed a 94% correct classification of CD and healthy subjects. The present study suggests Valine and Isoleucine as differentiating metabolites for CD diagnosis. These metabolites can be used for screening of risky samples at the early stages of CD diagnoses. Moreover, a robust random forest regression model with good prediction outcomes was developed for correlating serum zinc level and metabolite concentrations. The regression model showed the correlation (R2) and root mean square error values of 0.83 and 6.44, respectively. This model suggests valuable clues for understanding the mechanism of zinc deficiency in CD patients. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
9.
Arash Shokrolahi Abbas Zali Mohammd Mahdavi 《Phosphorus, sulfur, and silicon and the related elements》2013,188(4):535-543
Abstract A simple and efficient procedure has been developed for the synthesis of benzothiazole derivatives in water by the condensation of 2-aminothiophenol with aldehydes in the presence of Sulfonated porous carbon (SPC). This method provides a simple and efficient protocol in terms of mild reaction conditions, clean reaction profiles, small quantity of catalyst, and simple workup procedure. 相似文献
10.
Reza Karimi Shervedani Zeinab RezvaniniaHassan Sabzyan Hassan Zali Boeini 《Analytica chimica acta》2014
Gold electrode surface is modified via covalent attachment of a synthesized thiol functionalized with 8-hydroxyquinoline, p-((8-hydroxyquinoline)azo) benzenethiol (SHQ), for the first time. The behavior of the nanostructured electrode surface (Au–SHQ) is characterized by electrochemical techniques including cyclic and differential pulse voltammetry (CV and DPV), and electrochemical impedance spectroscopy (EIS). The modified surface is stable in a wide range of potentials and pHs. A surface pKa of 6.0 ± 0.1 is obtained for Au–SHQ electrode using surface acid/base titration curves constructed by CV and EIS measurements as a function of pH. These results helped to determine the charge state of the surface as a function of pH. The gold modified electrode surface showed good affinity for sensing the Al(III) ion at pH 5.5. The sensing process is based on (i) accumulation and complex formation between Al(III) from the solution phase and 8HQ function on the Au electrode surface (recognition step) and (ii) monitoring the impedance of the Au–SHQ–Al(III) complex against redox reaction rate of parabenzoquinone (PBQ) (signal transduction step). The PBQ is found to be a more suitable probe for this purpose, after testing several others. Thus, the sensor was tested for quantitative determination of Al(III) from the solution phase. At the optimized conditions, a linear response, from 1.0 × 10−11 to 1.2 × 10−5 M Al(III) in semi-logarithmic scale, with a detection limit of 8.32 × 10−12 M and mean relative standard deviation of 3.2% for n = 3 at 1.0 × 10−7 M Al(III) is obtained. Possible interferences from coexisting cations and anions are also studied. The results show that many ions do not interfere significantly with the sensor response for Al(III). Validity of the method and applicability of the sensor are successfully tested by determination of Al(III) in human blood serum samples. 相似文献