排序方式: 共有92条查询结果,搜索用时 15 毫秒
1.
Laguel Yassine Pillutla Krishna Malick Jérôme Harchaoui Zaid 《Set-Valued and Variational Analysis》2021,29(4):967-996
Set-Valued and Variational Analysis - R. Tyrell Rockafellar and his collaborators introduced, in a series of works, new regression modeling methods based on the notion of superquantile (or... 相似文献
2.
This paper deals with the solutions of linear inhomogeneous time-fractional partial differential equations in applied mathematics and fluid mechanics. The fractional derivatives are described in the Caputo sense. The fractional Green function method is used to obtain solutions for time-fractional wave equation, linearized time-fractional Burgers equation, and linear time-fractional KdV equation. The new approach introduces a promising tool for solving fractional partial differential equations. 相似文献
3.
The present work describes a novel method for the incorporation of Nile blue A into polyurethane foam matrix. This foam material was found to be very suitable for the extraction of metal ions from aqueous solutions. The characterization of Nile blue A grafted foam and the effect of halide concentration, pH, shaking time, extraction isotherm and capacity have been investigated. This foam material was found to be suitable for the separation and preconcentration of iron (III), zinc (II), cadmium (II) and mercury (II) from waste water. The extraction was accomplished in (15-20) minutes. Iron was separated from acid medium (2-4 M HCl), zinc from (3-5 M HCl), cadmium from (4-6 M HCl) as thiocyanate complexes and mercury was separated from (1-2 M HCl) as chloride. 相似文献
4.
Dr. Tarun Kumar Yan Yang Sirine Sghaier Dr. Yassir Zaid Dr. Xavier F. Le Goff Dr. Elodie Rousset Dr. Fabien Massicot Dr. Dominique Harakat Agathe Martinez Dr. Marc Taillefer Prof. Laurent Maron Prof. Jean-Bernard Behr Dr. Florian Jaroschik 《Chemistry (Weinheim an der Bergstrasse, Germany)》2021,27(12):4016-4021
The development of new fluorine-containing building blocks and their efficient synthetic access is currently a challenging research field. Herein, the highly regio- and stereoselective addition of a large range of aldehydes onto trifluoromethylated benzofulvenes was achieved using a simple La/I2/DIBAL-Cl system via a selective C−F bond activation process. This versatile methodology provided homodienyl alcohols bearing a terminal CF2-alkene with potential further applications, as shown by the dehydration to the first benzofulvenes carrying a difluorovinyl group. In addition, for certain electron-poor aldehydes, unprecedented ipso substitution of the CF3 group in a diene was observed, which, according to DFT studies, is related to the presence of the large, Lewis-acidic lanthanum metal. 相似文献
5.
Mohammad M. Khani Zaid M. Abbas Brian C. Benicewicz 《Journal of polymer science. Part A, Polymer chemistry》2017,55(9):1493-1501
The preparation of well‐defined polyisoprene‐grafted silica nanoparticles (PIP‐g‐SiO2 NPs) was investigated. Surface initiated reversible addition fragmentation chain transfer (SI‐RAFT) polymerization was used to polymerize isoprene from the surface of 15 nm silica NPs. A high temperature stable trithiocarbonate RAFT agent was anchored onto the surface of particles with controllable graft densities. The polymerization of isoprene mediated by silica anchored RAFT with different densities were investigated and compared to the polymerization mediated by free RAFT agents. The effects of different temperatures, initiators, and monomer feed ratios on the kinetics of the SI‐RAFT polymerization were also investigated. Using this technique, block copolymers of polyisoprene and polystyrene on the surface of silica particles were also prepared. The well‐defined synthesized PIP‐g‐SiO2 NPs were then mixed with a polyisoprene matrix which showed a good level of dispersion throughout the matrix. These tunable grafted particles have potential applications in the field of rubber nanocomposites. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 1493–1501 相似文献
6.
Elhossein Ali Moawed Mohamed Ahmed Zaid Mohamed Fathy El-Shahat 《International journal of environmental analytical chemistry》2013,93(12):935-946
A stable chelating resin matrix was prepared by covalently linking resorcinol with polyurethane foam matrix through a –N=N– group. Preconcentration and determination of trace Ag+ and Hg2+ ions from samples of different origin, using Res-PUF, were studied. Various conditions influencing the sorption of these metal ions onto Res-PUF were optimized. The kinetics of sorption of the Ag+ and Hg2+ by Res-PUF were found to be fast, reached equilibrium in few minutes (5–10?min) and followed a first-order rate equation with an overall rate constant k in 0.102 and 0.267/min, respectively. Study of the variation of the sorption of the tested metal ions with temperature yielded average values for ΔG, ΔH and ΔS of ?3.94, ?22.02 and ?58.37, respectively. The mean free sorption energy (E) computed from the Dubinin–Radushkevich (D–R) isotherm was found to be equal to 8.91 kJ/mol, which reflects the chelation sorption process. The capacities of the foam material were 0.15 and 0.07?mmol/g for Ag+ and Hg2+, respectively. Preconcentration factors of?>?50 were achieved (RSD?≈?5.99). The proposed preconcentration procedure was applied successfully to the determination of trace metal ions in natural and wastewater samples. 相似文献
7.
Harveen Kaur Amanda M. Heapy Renata Kowalczyk Zaid Amso Maureen Watson Jillian Cornish Margaret A. Brimble 《Tetrahedron》2014
The first synthesis and osteoblast proliferative activity of the naturally occurring cyclic peptides dianthins G and H is described. The greater potency of naturally occurring dianthin G over dianthin H at physiological concentrations mirrored the osteoblast proliferative activity observed for synthetic dianthins G and H. Six alanine-scan analogues of the more potent dianthin G were also synthesised and osteoblast assays revealed that four of the six residues can be further modified for improved activity. We also confirmed by variable temperature 1H NMR spectroscopic analysis that the sets of major and minor signals observed for dianthins G and H in DMSO-d6 are in fact due to cis–trans rotational isomers of the proline ring. 相似文献
8.
Zaid Faska Aicha Bellioua Mohamed Bouklah Lhou Majidi Rachid Fihi Abdelahamid Bouyanzer Belkheir Hammouti 《Monatshefte für Chemie / Chemical Monthly》2008,139(12):1417-1422
The inhibitive action of pulegone and pulegone oxide toward acid corrosion of steel in molar hydrochloric acid was studied
by weight loss measurements, potentiodynamic polarization, and impedance spectroscopy (EIS) methods. The pulegone is extracted
starting from oil of Pennyroyal Mint (Mentha pulegium). The natural compound was found to delay the corrosion rate. The pulegone oxide is prepared by oxidation of pulegone. The
inhibition efficiency was found to increase with the inhibitor content to attain 81 and 75% at 5 g dm−3 for pulegone and pulegone oxide. The increase in temperature leads to an increase in the inhibition efficiency of the natural
compared.
Correspondence: Belkheir Hammouti, Laboratoire de chimie Appliquée & Environnement, Faculté des Sciences, B.P. 717, 60000
Oujda, Morocco. 相似文献
9.
A novel method for nonlinear fractional partial differential equations: Combination of DTM and generalized Taylor's formula 总被引:1,自引:0,他引:1
In this article, a novel numerical method is proposed for nonlinear partial differential equations with space- and time-fractional derivatives. This method is based on the two-dimensional differential transform method (DTM) and generalized Taylor's formula. The fractional derivatives are considered in the Caputo sense. Several illustrative examples are given to demonstrate the effectiveness of the present method. Results obtained using the scheme presented here agree well with the analytical solutions and the numerical results presented elsewhere. Results also show that the numerical scheme is very effective and convenient for solving nonlinear partial differential equations of fractional order. 相似文献
10.
In this article, we implement relatively new analytical techniques, the variational iteration method and the Adomian decomposition method, for solving nonlinear partial differential equations of fractional order. The fractional derivatives are described in the Caputo sense. The two methods in applied mathematics can be used as alternative methods for obtaining analytic and approximate solutions for different types of fractional differential equations. In these schemes, the solution takes the form of a convergent series with easily computable components. Numerical results show that the two approaches are easy to implement and accurate when applied to partial differential equations of fractional order. 相似文献