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1.
2.
Unexpected benzimidazole ring formation from a quinoneimide species in the presence of ammonium acetate as supporting electrolyte used in the coupling of electrochemistry with mass spectrometry 下载免费PDF全文
3.
4.
Mohammed Ali Faya Ibrahim 《Czechoslovak Mathematical Journal》2004,54(2):303-313
It was shown in [7] that any right reversible, cancellative ordered semigroup can be embedded into an ordered group and as a consequence, it was shown that a commutative ordered semigroup can be embedded into an ordered group if and only if it is cancellative. In this paper we introduce the concept of L-maher and R-maher semigroups and use a technique similar to that used in [7] to show that any left reversible cancellative ordered L or R-maher semigroup can be embedded into an ordered group. 相似文献
5.
Let be an elliptic curve with complex multiplication, defined over . We consider linear forms on with coefficients in the CM field of . Within this framework, we present a new measure of linear independence for elliptic logarithms in (logb)(loga)n. Like recent advances in this domain (works by Ably, David, Hirata-Kohno), our result is best possible in terms of the height of the linear forms (logb) while providing a better estimate in the height of algebraic points considered (loga), removing a term in logloga. To cite this article: M. Ably, É. Gaudron, C. R. Acad. Sci. Paris, Ser. I 337 (2003). 相似文献
6.
The kinetics of oxidation of Fe2+ by [Co(C3H2O4)3]3? in acidic solutions at 605 nm showed a simple first-order dependence in each reactant concentration. The second-order rate constant dependence on [H+] is in accordance with eqn (i) k2 = k′2 + k3[H+] (i) where k′2 and k3 have values of 73.4 ± 14.0 M ?1 s?1 and 353 ± 41 M?2 s?1, respectively, at 1.0 M ionic strength (NaClO4) and 25°C. At 310 nm the formation and decomposition of an intermediate, believed to be [FeC3H2O4]+, was observed. The increase in the rate of oxidation with increasing [H+] was interpreted in terms of a “one-ended” dissociation mechanism which facilitates chelation of Fe2+ by the carbonyl oxygens of malonate in the transition state. 相似文献
7.
Shoaib Ahmad 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,18(3):309-318
The mechanisms and processes of the formation of the regenerative soot in a graphite hollow cathode discharge that produces
and emits carbon clusters are presented. Mass spectrometry with a specially designed E×B velocity filter analyzes the entire range of the charged clusters from C
1 to ∼C
4300. The state of the carbon vapour within the source is evaluated by using the characteristic line emissions from the carbonaceous
discharge whose formative mechanisms depend upon the kinetic and potential sputtering of the sooted cathode. The carbonaceous
discharge generates atomic and ionic C and its clusters C
m (m≥ 2), noble gas metastable atoms and ions, energetic electrons and photons in the cavity of the graphite hollow cathode. The
parameters of soot formation and its recycling depend critically on the discharge parameters, the geometry of the hollow cathode
and 3D profile of the cusp magnetic field contours.
Received 2nd July 2001 and Received in final form 10 September 2001 相似文献
8.
Most adhesives and binders, including bitumen for asphalt mixture production, are presently produced from petrochemicals after
the refining of crude oil. The fact that crude oil reserves are a finite resource means that in the future, it may become
necessary to produce these materials from alternative and probably renewable sources. Suitable resources of this kind may
include polysaccharides, plant oils and proteins. This paper deals with the synthesis of polymer binders from monomers that
could, in future, be derived from renewable resources. These binders consist of polyethyl acrylate (PEA) of different molecular
weight, polymethyl acrylate (PMA) and polybutyl acrylate (PBA), which were synthesised from ethyl acrylate, methyl acrylate
and butyl acrylate, respectively, by atom transfer radical polymerisation. The rheological properties of these binders were
determined by means of oscillatory testing using a dynamic shear rheometer and combinations of stress/strain, temperature
and frequency sweeps. The results indicate that PEA can be produced to have rheological properties similar to that of ‘soft’
100/150 penetration grade bitumen, PMA with similar rheological properties to that of ‘hard’ 10/20 penetration grade bitumen,
while PBA, due to its highly viscous nature and low dynamic moduli, cannot be used on its own as a binder. The synthetic polymers
were found to be thermo-rheologically simple, and the shift factors, used to produce the dynamic moduli master curves, were
found to fit an Arrhenius function. 相似文献
9.
A variety of aromatic amines are oxidized to their corresponding quinones in excellent yields by supported iodic acid under microwave irradiation and solvent free conditions. 相似文献
10.
Although pentamethylene sulfide (tetrahydrothiopyran) lacks acidic hydrogen, OsVIII has been found to catalyze its oxidation by alkaline K3Fe(CN)6 to produce 3-hydroxypentamethylene sulfide as the only product. The kinetics reveal first-order dependence on ferricyanide and OsVIII, and zero order on pentamethylene sulfide and OH–. The effects of introduced electrolytes, K4Fe(CN)6, relative permittivity and temperature have also been studied. On the basis of kinetic evidence, a mechanism that involves anation of the osmium catalyst (sulfide/water interchange) followed by intramolecular proton abstraction, followed by an electron transfer step has been proposed and discussed. 相似文献