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1.
2.
Yoshiyuki Watabe Takuya Kondo Hiroe Imai Masatoshi Morita Nobuo Tanaka Jun Haginaka Ken Hosoya 《Analytical sciences》2004,20(1):133-137
A new high-performance liquid chromatography (HPLC) method has been developed to detect ultra-low concentrations of bisphenol-A (BPA) (below 1 ng/L (ppt)) using column switching electrochemical detection (ECD). The results were superior to those obtained from manual pretreatment procedure with membrane stationary phase. BPA is inherently ubiquitous in the environment, including tools and solvents used for its analysis; to obtain meaningful results, therefore, the concentration of the overall BPA contamination must be below the detection limit for BPA using the analytical system. Therefore, purified water for preparing the standard BPA solution must be filtered with a hydrophobic membrane to suppress BPA background levels of contamination. In addition, we investigated methods for effectively preserving environmental water containing BPA. The addition of a small amount of ethylenediaminetetraacetic acid (EDTA) provided good recovery even after overnight storage. By employing these precautionary measures and procedures to reduce BPA contamination from the analytical procedure, we could accurately determine l(-10) ppt of BPA in environmental water samples using a column switching HPLC system. 相似文献
3.
4.
Kazuhiro Kurata Masataka Shibata Shigeru Sakamoto 《Applied Mathematics and Optimization》2004,50(3):259-278
Let $\Omega$ be a bounded domain in ${\bf R^n}$ with Lipschitz
boundary,
$\lambda >0,$ and $1\le p \le (n+2)/(n-2)$ if $n\ge 3$ and $1\le p< +\infty$
if $n=1,2$. Let $D$ be a measurable subset of $\Omega$ which belongs
to the class
$
{\cal C}_{\beta}=\{D\subset \Omega \quad | \quad |D|=\beta\}
$
for the prescribed $\beta\in (0, |\Omega|).$
For any $D\in{\cal C}_{\beta}$, it is well known that
there exists a unique
global minimizer $u\in H^1_0(\Omega)$, which we denote by
$u_D$, of the functional
\[\quad
J_{\Omega,D}(v)=\frac12\int_{\Omega}|\nabla v|^2\,
dx+\frac{\lambda}{p+1}\int_{\Omega}|v|^{p+1}\, dx
-\int_{\Omega}\chi_Dv\,dx
\]
on $H^1_0(\Omega)$.
We consider the optimization problem
$
E_{\beta,\Omega}=\inf_{D\in {\cal C}_{\beta}} J_D(u_D)
$
and say that
a subset $D^*\in {\cal C}_{\beta}$ which attains
$E_{\beta,\Omega}$
is an optimal configuration to this problem.
In this paper we show the existence, uniqueness
and non-uniqueness, and
symmetry-preserving and symmetry-breaking phenomena of the
optimal configuration $D^*$ to this
optimization problem in various settings. 相似文献
5.
6.
T Tatee K Narita S Kurashige S Ito H Miyazaki H Yamanaka M Mizugaki T Sakamoto H Fukuda 《Chemical & pharmaceutical bulletin》1986,34(4):1643-1655
7.
Ohwada T Miura M Tanaka H Sakamoto S Yamaguchi K Ikeda H Inagaki S 《Journal of the American Chemical Society》2001,123(42):10164-10172
N-Nitrosamines can be considered as potential nitric oxide (NO)/nitrosonium ion (NO(+)) donors. However, the relation of the structures of N-nitrosamines, in particular of aliphatic N-nitrosamines, to the characteristics of release of NO or NO(+) remains unclear. Here we show that aliphatic N-nitrosoamines of 7-azabicyclo[2.2.1]heptanes can undergo heterolytic N-NO bond cleavage. On the basis of the observation of reduced rotational barriers of the N-NO bonds in solution and nitrogen-pyramidal structures of the N-nitroso group in the solid state, we postulate that N-NO bond cleavage of N-nitrosamines is enhanced by a reduction of the resonance in the N-NO group. Computational studies suggest that these structural features of the N-nitrosamines of 7-azabicyclo[2.2.1]heptane are derived from angle strain imposed on the CNC angles. 相似文献
8.
Ray K Nakahara H Sakamoto A 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(1-2):103-107
The fluorescence lifetimes decays and picosecond time-resolved fluorescence spectra were measured to investigate the dynamics of the excited state of sulforhodamine B (SRB) molecules adsorbed in the mono- and multilayered Langmuir-Blodgett (LB) films of octadecylamine. Steady-state and time-resolved fluorescence spectroscopy reveals that the fluorescence lifetimes and contents of the monomer and dimers in the molecular organizates depend upon the concentration of the dye in the solution and the adsorption process. SRB dye molecules adsorbed in LB films have been imaged with scanning near-field optical microscopy (SNOM). This information is exploited to map the distribution with molecular spatial resolution. SNOM provide the visual evidence of the monomers and dimers of SRB in cationic LB films. 相似文献
9.
10.
M Sugiyama T Sakamoto K Tabata K Endo K Ito M Kobayashi H Fukumi 《Chemical & pharmaceutical bulletin》1989,37(8):2122-2131
Thiazolo[3,2-a]thieno[3,2-d]-, [3,4-d]- and [2,3-d]pyrimidin-5-one derivatives (6, 11 and 16), and polymethylene condensed thieno[3,2-d]-, [3,4-d]- and [2,3-d]pyrimidin-5-one derivatives (19-21), in which the oxygen atom of the oxazolidine moiety in 3 was replaced by a sulfur atom or methylene groups, were synthesized and evaluated for gastric antisecretory activity in pylorus-ligated rats. The structure-activity relationships of these compounds are discussed. 相似文献