Ultraviolet and visible upconversion luminescence of Tm(0.1)Yb(5):FOV oxyfluoride nanophase vitroceramics

The ultraviolet upconversion luminescence of Tm³⁺ ions sensitized by Yb³⁺ ions in oxyfluoride nanophase vitroceramics when excited by a 975 nm diode laser was studied. An ultraviolet upconversion luminescence line positioned at 363.6 nm was found. It was attributed to the fluorescence transition of ¹D₂→³H₆ of Tm³⁺ ion. Several visible upconversion luminescence lines at 450.7 nm, (477.0 nm, 462.5 nm), 648.5 nm, (680.5 nm, 699.5 nm) and (777.2 nm, 800.7 nm) were also found, which result respectively from the fluorescence transitions of ¹D₂→³F₄, ¹G₄→³H₆, ¹G₄→³F₄, ³F₃→³H₆ and ³H₄→³H₆ of Tm³⁺ ion. The careful measurement and analysis of the variation of upconversion luminescence intensity F as a function of the 975 nm pumping laser power P prove that the upconversion luminescence of ¹D₂ state is partly a five-photon upconversion luminescence, and the upconversion luminescence of ¹G₄ state and ³H₄ state are respectively the three-photon and two-photon upconversion luminescence. The theoretical analysis suggested that the upconversion mechanism of the 363.6 nm ¹D₂→³H₆ upconversion luminescence is partly the cross energy transfer of {³H₄(Tm³⁺), ³F₄(Tm³⁺), ¹G₄(Tm³⁺)→¹D₂(Tm³⁺)} and {¹G₄(Tm³⁺)→³F₄(Tm³⁺), ³H₄(Tm³⁺)→¹D₂(Tm³⁺)} between Tm³⁺ ions. In addition, the upconversion luminescence of ¹G₄ and ³H₄ state results respectively from the sequential energy transfer {²F_5/2(Yb³⁺)→²F_7/2(Yb³⁺), ³H₄(Tm³⁺)→¹G₄(Tm³⁺)} and {²F_5/2(Yb³⁺) →²F_7/2(Yb³⁺), ³F₄(Tm³⁺)→³F₂(Tm³⁺)} from Yb³⁺ ions to Tm³⁺ ions. Supported by the National Natural Science Foundation of China (Grant No. 10674019)     

多相条件下亚硫酸镁非催化氧化反应动力学及机理

副产物的氧化回收利用是影响镁法脱硫工艺发展的关键.本文通过真空旋转蒸发的方式制备了高纯度的亚硫酸镁样品,并利用鼓泡式反应装置,研究了亚硫酸镁非催化氧化的反应动力学,考察了pH、氧分压、亚硫酸镁浓度、气体流量、温度等因素对亚硫酸镁氧化反应速率的影响,得到了各反应物的分级数及表观活化能.结合三相反应过程的数学模型推断出亚硫酸镁氧化的本征反应在慢反应区进行,且氧的传质扩散是总反应的速率控制步骤.研究结果为氧化回收镁法脱硫副产物提供了理论依据.     

Recent progress on dense nuclear matter in skyrmion approaches

The Skyrme model provides a novel unified approach to nuclear physics. In this approach, single baryon, baryonic matter and medium-modified hadron properties are treated on the same footing. Intrinsic density dependence (IDD) reflecting the change of vacuum by compressed baryonic matter figures naturally in the approach. In this article, we review the recent progress on accessing dense nuclear matter by putting baryons treated as solitons, namely, skyrmions, on crystal lattice with accents on the implications in compact stars.     

An energetics analysis of fish self-propelled swimming

正Fishes can swim freely in water owing to the interaction between their deforming bodies and the surrounding fluid,as is called self-propelled swimming.Besides the experimental study,the numerical simulation can provide much more details of the flow structure,hydrodynamics and energetics of fish swimming.Since the pioneering study by Carling et al.[1],numerical simulation has become the primary method to     

Studies on the synthesis, pungency and anti-biofouling performance of capsaicin analogues

Ten capsaicin analogues were synthesized and their pungency degrees were determined through Scoville Organoleptic Test.The relationship between the structure and pungency degree of these capsaicin analogues was discussed.Then four of these capsaicin analogues with higher pungency degree were picked out and added to anti-biofouling paints as repellents to study their anti-biofouling performance by shallow sea buoyant raft hung-plate experimentation.The results showed that capsaicin and dihydrocapsaicin exhibited equally good anti-biofouling performance while nordihydrocapsaicin and N-vanillylnonanamide had poor anti-biofouling performance.Experimental results also showed that the paints with only 0.1% capsaicin or dihydrocapsaicin as repellent without any other biocides had also exhibited good anti-biofouling performance,which provided a new idea for developing novel,more environment-friendly and Cu2O-free antifouling paints.     

Guided wave propagation in multilayered piezoelectric structures

A general formulation of the method of the reverberation-ray matrix (MRRM) based on the state space formalism and plane wave expansion technique is presented for the analysis of guided waves in multilayered piezoelectric structures. Each layer of the structure is made of an arbitrarily anisotropic piezoelectric material. Since the state equation of each layer is derived from the three-dimensional theory of linear piezoelectricity, all wave modes are included in the formulation. Within the framework of the MRRM, the phase relation is properly established by excluding exponentially growing functions, while the scattering relation is also appropriately set up by avoiding matrix inversion operation. Consequently, the present MRRM is unconditionally numerically stable and free from computational limitations to the total number of layers, the thickness of individual layers, and the frequency range. Numerical examples are given to illustrate the good performance of the proposed formulation for the analysis of the dispersion characteristic of waves in layered piezoelectric structures. Supported by the National Natural Science Foundation of China (Grant Nos. 10725210 and 10832009), the Specialized Research Fund for the Doctoral Program of Higher Education (Grant No. 20060335107), the National Basic Research Program of China (Grant No. 2009CB623204), and the Scientific Research Foundation for Tsuiying Talents of Lanzhou University     

辣椒素同系物合成、辣度及海洋生物防污性能研究

合成了十种辣椒碱同系物,用感官评定的方法对其辣度进行了测定,并将它们的结构与辣度进行了对比,探讨了影响辣椒碱同系物辣度的结构因子.选取其中辣度较大的四种辣椒碱同系物作为海洋生物防污涂料的驱赶剂,考察了它们的海洋生物防污性能.结果表明,辣椒碱和二氢辣椒碱都具有良好的防污性能,二者不相上下.降二氢辣椒碱和壬酸香草胺的防污性能与辣椒碱和二氢辣椒碱有明显区别.仅以辣椒碱或二氢辣椒碱为驱赶剂,且其含量仅为0.1%的情况下,漆膜也表现出较好的防污性能,这为研发新型的、环保的、不含氧化亚铜的防污涂料提供了新思路.     

Could gingko foliage serve as a bio-monitor for organochlorine pesticides in air?

The feasibility of gingko (Gingo Biloba) foliage as a passive bio-monitor for organochlorine pesticides in air was explored. The accumulation patterns of hexachlorocyclohexanes (HCHs), dichlorodiphenyl- trichloroethanes (DDTs) and hexachlorobenzene (HCB) in gingko foliage were similar; the amounts of HCHs, DDTs and HCB increased with foliage growth in spring and decreased thereafter. This accumu-lation pattern is likely related to the growing process of the gingko foliage, which was observed for the first time in our work, giving a piece of evidence for the "bud burst effect" in plants. Compared with those in pine needles in 1980's, the residual levels of HCHs and DDTs have declined obviously in Bei-jing, indicating that the ban on the production and use of organochlorine pesticides (OCPs) in our country is effective; however, the amount of HCB has increased, indicating great progress of chemical industry in Beijing. The analysis for the source of OCPs in the gingko foliage showed that the technical HCHs and DDTs were used largely in history, but were not used in recent years. A little lidane has been used and there was a new input of o,p′-DDT in recent years; dicofol usage may be the main source of o,p′-DDT. Concentrations of HCHs, DDTs and HCB in gingko foliages were similar to those in pine nee-dles in the corresponding period and there is a strong positive correlation between the OCPs concen-tration data obtained from these two kinds of trees. It presents no difference in the accumulation style between these two kinds of trees. The level of OCPs in the gingko foliage reflects the pollution status of OCP in air. The result of this work shows that the gingko foliage can be used as a bio-monitor of OCPs in air.     

HLS bunch current measurement system

Bunch current is an important parameter for studying the injection fill-pattern in the storage ring and the instability threshold of the bunch, and the bunch current monitor also is an indispensable tool for the top-up injection. A bunch current measurement (BCM) system has been developed to meet the needs of the upgrade project of Hefei Light Source (HLS). This paper presents the layout of the BCM system. The system based on a high-speed digital oscilloscope can be used to measure the bunch current and synchronous phase shift. To obtain the absolute value of bunch-by-bunch current, the calibration coefficient is measured and analyzed. Error analysis shows that the RMS of bunch current is less than 0.01 mA when bunch current is about 5 mA, which can meet project requirement.

     

Intrinsic oxidation kinetics of sulfite catalyzed by peracetic acid under different water quality and light conditions

Oxidation of sulfite is an important process in wet flue gas desulfurization. Using highly purified water or distilled water as a reaction medium and a transparent or an opaque intermittent reaction apparatus, the intrinsic oxidation kinetics of sulfite catalyzed by peracetic acid was investigated under four different conditions. The reaction order of the reagents and the activation energy were obtained. The results indicate that water quality and light have no obvious effects on the reaction order and activation energy, but have an influence on the reaction rate constant. The mechanism of the intrinsic reaction is proposed. The results derived with this mechanism are in good agreement with the experimental results. Supported by the National Basic Research Program of China (Grant No. JK00020), the Doctor Research Fund from North China Electric Power University (Grant No. 200612008), and the National High Technology Research and Development Program of China (Grant No. 2007AA061703)