环戊二烯基二硫代氨基甲酸钛(Ⅳ)、锆(Ⅳ)配合物的合成及结构表征

(RCp)_2MCl_2,(RCp)TiCl_3分别与N-(4-苯基-2-噻唑基)二硫代氨基甲酸钾和3-苯基-5-(2-呋哺基)-吡唑啉-1-二硫代甲酸钠进行反应,合成了三十二个未见报道的(RCp)M(S_2CNHR′)_nCl_(3-n),(RCp)_2M-(S_2CNHR′)_nCl_(2-n),[R=H,Me;M=Ti,Zr;R′=4-苯基噻唑基(PTDTC),n=1,2,3]以及(RCp)M(S_2CR~2)_nCl_(3-n),(RCp)_2M(S_2CR~2)_nCl_(2-n)[R=H,Me;M=Ti,Zr,R~2=3-苯基-15-(呋喃-2)吡唑啉基(PFPDTC),n=1,2,3]型配合物。所有配合物经元素分析、UV、IR和'H NMR谱证实,二硫代氨基甲酸是以双齿配体键合的。     

担载金属簇络合物研究进展

本文综述担载金属簇领域的发展状况和研究方法,对担载在有机高分子、无机氧化物相分子筛表面上的金属簇的合成、表征和催化作用分别进行了讨论。重点在担载金属羰基簇。     

Geometry of Quantum Coherence for Two Qubit X States

The geometry of the structure of entanglement and discord for Bell-diagonal states is depicted by Lang and Caves (Phys. Rev. Lett. 105, 150501, 2010). In this paper, we investigate the geometry with respect to several distance-based quantifiers of coherence for Bell-diagonal states. We find that as both l₁ norm and relative entropy of coherence vary continuously from zero to one, their related geometric surfaces move from the region of separable states to the region of entangled states, a fact illustrating intuitively that quantum states with nonzero coherence can be used for entanglement creation. We find the necessary and sufficient conditions that quantum discord of Bell-diagonal states equals to its relative entropy of coherence, and depict the surfaces related to the equality. We give surfaces of relative entropy of coherence for X states. We show the surfaces of dynamics of relative entropy of coherence for Bell-diagonal states under local nondissipative channels and find that all coherences under local nondissipative channels decrease.

     

电化学阶边精饰法制备钯镍合金纳米线的研究

运用连续恒电势三脉冲的电化学阶边精饰法在高定向石墨(HOPG)上制备钯镍合金纳米线阵列， 并研究了合金成分的影响因素. 结果表明，改变镀液组成可以调整钯镍合金成分，调整生长时间和生长电势来控制钯镍合金纳米线的直径. 用7 mmol•L^-1 PdCl2,3 mmo•L^-1 NiSO₄, 0.2 mol•L^-1 NH₄Cl，pH 8.5的混合溶液，控制脉冲电势-2.0 V形核0.2 s，在脉冲电势－0.4 V生长1 h，可以获得平均直径为200 nm, 长度约400 μm的钯镍合金纳米线阵列, 纳米线的合金成分中镍含量为12.4%(质量分数,w).     

One-Way Information Deficit and Geometry for a Class of Two-Qubit States

The work deficit, as introduced by Jonathan Oppenheim et al. [Phys. Rev. Lett. 89 (2002) 180402] is a good measure of the quantum correlations in a state and provides a new standpoint for understanding quantum non-locality. In this paper, we analytically evaluate the one-way information deficit (OWID) for the Bell-diagonal states and a class of two-qubit states and further give the geometry picture for OWID. The dynamic behavior of the OWID under decoherence channel is investigated and it is shown that the OWID of some classes of X states is more robust against the decoherence than the entanglement.     

Dynamics of Quantum Coherence in Bell-Diagonal States under Markovian Channels

We study the curves of coherence for the Bell-diagonal states including l_1-norm of coherence and relative entropy of coherence under the Markovian channels in the first subsystem once. For a special Bell-diagonal state under bit-phase flip channel, we find frozen coherence under l_1 norm occurs, but relative entropy of coherence decrease. It illustrates that the occurrence of frozen coherence depends on the type of the measure of coherence. Also, we study the coherence evolution of Bell-diagonal states under Markovian channels in the first subsystem n times and find that coherence under depolarizing channel decreases initially then increases for small n and tends to zero for large n. The dynamics of coherence of the Bell-diagonal state under two independent same type local Markovian channels is discussed.     

Macromolecule-to-Amphiphile Conversion Process of a Polyoxometalate–Polymer Hybrid and Assembled Hybrid Vesicles

We report our findings on the macromolecule-to-amphiphile conversion process of a polyoxometalate–polymer hybrid and the assembled hybrid vesicles formed by aggregation of the hybrid amphiphile. The polyoxometalate–polymer hybrid is composed of a polyoxometalate (POM) cluster, which is covered by five tetrabutylammonium (Bu₄N⁺) countercations, and a polystyrene (PS) chain. Through a cation-exchange process the Bu₄N⁺ countercations can be replaced by protons to form a hybrid amphiphile composed of a hydrophilic, protonated POM cluster and a hydrophobic PS chain. By implementing a directed one-dimensional diffusion and analyzing the diffusion data, we confirmed that the diffusion of solvated protons rather than macromolecules or aggregates is the key factor controlling the conversion process. Once the giant hybrid amphiphiles were formed, they immediately assembled into kinetically favored vesicular aggregates. During subsequent annealing these vesicular aggregates were transformed into thermodynamically stable vesicular aggregates with a perfect vesicle structure. The success in the preparation of the POM-containing hybrid vesicles provides us with an opportunity of preparing POM-functionalized vesicles.     

Macromolecule-to-Amphiphile Conversion Process of a Polyoxometalate-Polymer Hybrid and Assembled Hybrid Vesicles

We report our findings on the macromolecule-to-amphiphile conversion process of a polyoxometalate-polymer hybrid and the assembled hybrid vesicles formed by aggregation of the hybrid amphiphile. The polyoxometalate-polymer hybrid is composed of a polyoxometalate (POM) cluster, which is covered by five tetrabutylammonium (Bu(4) N(+) ) countercations, and a polystyrene (PS) chain. Through a cation-exchange process the Bu(4) N(+) countercations can be replaced by protons to form a hybrid amphiphile composed of a hydrophilic, protonated POM cluster and a hydrophobic PS chain. By implementing a directed one-dimensional diffusion and analyzing the diffusion data, we confirmed that the diffusion of solvated protons rather than macromolecules or aggregates is the key factor controlling the conversion process. Once the giant hybrid amphiphiles were formed, they immediately assembled into kinetically favored vesicular aggregates. During subsequent annealing these vesicular aggregates were transformed into thermodynamically stable vesicular aggregates with a perfect vesicle structure. The success in the preparation of the POM-containing hybrid vesicles provides us with an opportunity of preparing POM-functionalized vesicles.     

One-way Quantum Deficit and Decoherence for Two-qubit X States

We study one-way quantum deficit of two-qubit X states systematically from analytical derivations. An effective approach to compute one-way quantum deficit of two-qubit X states has been provided. Analytical results are presented as for detailed examples. Moreover, we demonstrate the decoherence of one-way quantum deficit under phase damping channel.     

One-Way Deficit and Quantum Phase Transitions in <Emphasis Type="Italic">XX</Emphasis> Model

Quantum correlations including entanglement and quantum discord have drawn much attention in characterizing quantum phase transitions. Quantum deficit originates in questions regarding work extraction from quantum systems coupled to a heat bath (Oppenheim et al. Phys. Rev. Lett. 89, 180402, 2002). It links quantum thermodynamics with quantum correlations and provides a new standpoint for understanding quantum non-locality. In this paper, we evaluate the one-way deficit of two adjacent spins in the bulk for the XX model. In the thermodynamic limit, the XX model undergoes a first order transition from fully polarized to a critical phase with quasi-long-range order with decrease of quantum parameter. We find that the one-way deficit becomes nonzero after the critical point. Therefore, the one-way deficit characterizes the quantum phase transition in the XX model.