GC-FPD、GC-MS法分析血液样品中的毒鼠强

采用液-液提取方法及GC—FPD定量、GC—MS定性检测手段，对血液样品中毒鼠强的提取和检测方法进行了研究。时提取毒鼠强的溶剂类型、溶剂用量及质谱分析参数等因素进行了考察，建立了一种回收率高、重现性好、灵敏度佳、干扰少的毒鼠强分析方法。毒鼠强工作曲线的线性范围为0．01-0．2μg／μL，相关系数r=0．9999，空白血液的加标平均回收率为93．6％，测定结果的相对标准偏差为5．27％。该方法满足司法鉴定中生物样品的定性、定量检验要求。     

Statistical and interferometric determination of the optical thickness of a multilayer transparent plate

Optical Review - Wavelength-tuning Fizeau interferometry has been widely used to measure and estimate the optical thickness of optical components. However, in multilayer interferometry, the...     

Influence on Transmission Properties of Solitons by Stochastic Variation of System Parameters and Interaction

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Interferometric thickness measurement of glass plate by phase-shifting analysis using wavelength scanning with elimination of bias phase error

Optical Review - Phase-shifting fringe analysis using wavelength scanning has been broadly applied to the interferometric profiling of the thickness variation of glass plates. However, the...     

Simultaneous measurement of surface shape and absolute optical thickness of a glass plate by wavelength tuning phase-shifting interferometry

The absolute optical thickness and the surface shape of a glass plate of 7-in. square and 3.1mm thick was simultaneously measured by three-surface interferometry using a wavelength tuning Fizeau interferometer. The wavelength of a tunable diode laser is scanned linearly from 632 to 642 nm, at which the initial and the final phases of the interference fringes for the surface shape and for the optical thickness were separated and measured by a tunable phase-shifting technique. The number of phase variations in the interference fringes during the scanning is counted by discrete Fourier analysis, in which systematic errors caused by a nonlinearity in the wavelength scanning is corrected by a correlation analysis between the observed and theoretical interference fringes. Experimental results demonstrate that the systematic errors in the measured value were 15 nm for the surface shape and 0.6 μm for the absolute optical thickness.     

Single-step synthesis of wrinkled MoSe2 thin films

Controlled and simple synthesis strategy of two-dimensional (2D) nanomaterials is critical for designing the related heterostructures with different geometries, which influence strain, electronic structures, light-interactions, and surface reactions. Here, we report a single-step growth method for wrinkled MoSe₂ thin films on flat SiO₂/Si substrates by using high-vacuum co-evaporation. Above the critical film thickness of 15–20?nm, the MoSe₂ films start to form wrinkled structure with lateral periodicity of 7–10?μm, which significantly reduces light reflectance in the visible range. We demonstrate formation of the wrinkled pattern on the selective area either by etching the substrate surface or by depositing gold films. In addition, we observe switching of the microscopic growth mode from a layered stacking to a vertically aligned growth, which results in 2D-3D hybrid microstructures. Our single-step synthesis approach might be generalized to obtain wrinkled 2D-3D hybrid nanomaterials and utilized for flexible electronic & optoelectronic devices, efficient solar cells, catalytic electrodes, and anti-counterfeiting applications.     

CdS nanospheres hybridized with graphitic C3N4 for effective photocatalytic hydrogen generation under visible light irradiation

Graphitic carbon nitride (g‐C₃N₄)‐based photocatalysts have received considerable attention in the field of photocatalysis, especially for photocatalytic H₂ evolution. However, the intrinsic disadvantages of g‐C₃N₄ seriously limit its practical application. Herein, CdS nanospheres with an average diameter of 135 nm prepared using a solvothermal method were used as co‐catalysts to form CdS/g‐C₃N₄ composites (CSCN) to enhance the photocatalytic activity. Various techniques were employed to characterize the structure, composition and optical properties of the as‐prepared samples. It was found that the CdS nanospheres were relatively uniformly dispersed on the surface of g‐C₃N₄. Moreover, the photocatalytic H₂ generation activity of the samples was evaluated using lactic acid as sacrificial reagent in water under visible light irradiation. When the amount of CdS nanospheres loaded in the hybridized composites was 5 wt%, the optimal H₂ evolution rate reached 924 μmol g^?1 h^?1, which was approximately 1.4 times higher than that (680 μmol g^?1 h^?1) of Pt/g‐C₃N₄ (3 wt%). Based on the results of analysis, a possible mechanism for the photocatalytic activity of CSCN is proposed tentatively.     

大功率盘形激光焊接飞溅动态识别和特征分析

提出了一种识别飞溅动态并基于飞溅特征分析焊接状态的方法.以304不锈钢板为试验对象,进行大功率盘形激光平板堆焊试验.利用高速相机捕捉紫外波段和可见光波段的飞溅图像,通过图像处理提取飞溅特征参数,包括质心位置、面积、灰度、平均灰度和半径.基于飞溅特征参数建立飞溅搜索信息库和相似度函数,用于识别飞溅、计算飞溅体积和灰度以及...     

Type-II Red Phosphorus: Wavy Packing of Twisted Pentagonal Tubes

Elemental phosphorus exhibits fascinating structural varieties and versatile properties. The unique nature of phosphorus bonds can lead to the formation of extremely complex structures, and detailed structural information on some phosphorus polymorphs is yet to be investigated. In this study, we investigated an unidentified crystalline phase of phosphorus, type-II red phosphorus (RP), by combining state-of-the-art structural characterization techniques. Electron diffraction tomography, atomic-resolution scanning transmission electron microscopy (STEM), powder X-ray diffraction, and Raman spectroscopy were concurrently used to elucidate the hidden structural motifs and their packing in type-II RP. Electron diffraction tomography, performed using individual crystalline nanowires, was used to identify a triclinic unit cell with volume of 5330 ų, which is the largest unit cell for elemental phosphorus crystals up to now and contains approximately 250 phosphorus atoms. Atomic-resolution STEM imaging, which was performed along different crystal-zone axes, confirmed that the twisted wavy tubular motif is the basic building block of type-II RP. Our study discovered and presented a new variation of building blocks in phosphorus, and it provides insights to clarify the complexities observed in phosphorus as well as other relevant systems.