Time Evolution of Vibration-Induced Excited State Decay

A simple model consisting of two electronic levels and one vibrational mode (phonon) was theoretically studied. The electronic-vibrational interaction was linear in the vibrational displacement. The vibrational mode was taken in the harmonic approximation and was attached to the thermal bath formed by the ambient environment. The kinetic constants of the vibrational dissipation were of the second order in the vibrational-bath coupling and were taken in the Markovian limit. Although, depending on the parameters of the model, different curves of the non-radiative vibration-induced excited state decay were obtained, in general, three time intervals, corresponding to different physical behaviour, were found. In the short-time interval, small oscillations superimposed on the excited state decay were observed. They were determined by the vibrational frequency and influenced by electronic-vibrational coupling. In the middle-time interval, almost quasi-exponential decay was detected; its rate constant increased with stronger electronic-vibrational interaction and speed of vibrational relaxation. In the long-time interval, the decay was very slow and, under special conditions, even an asymptotic non-zero excited state population was observed. Its value increased with the strength of the off-diagonal electron-vibrational coupling. Links of the parameters of the model with quantum chemical terms were estimated.     

偏振分束器对光学电流传感器稳定性的影响

采用偏振光学理论,详细分析了光学电流传感器中偏振分束器消光比的变化对传感器性能的影响,得到了偏振分束器消光比与传感器输出的关系式,并用系统实验进行了验证.理论及实验结果的吻合证明了光学电流传感器稳定性直接受偏振分束器两路消光比影响的结论.     

A study of the mechanism and kinetics of interaction between nepheline powder and ammonium hydrofluoride

Behavior of a skeleton silicate, nepheline, in the reaction of fluorination with ammonium hydrofluoride was studied by means of differential-thermal, X-ray phase, and chemical analyses, IR spectroscopy, and scanning electron microscopy.     

Model of free charge generation in polymers

A time solution of the excimer-ion pair system is presented here with a special attention to the time asymptote. Presented at the Czech-Israeli-German Symposium “Dynamical Processes in Condensed Molecular Systems”, Prague, Czech Republic, 26–30 May 1997. This work was supported by the grant No. C 1050601 of the Grant Agency of the Academy of Sciences of the Czech Republic.     

Interface-induced states with an incommensurate spin-density wave in Fe/Cr-type multilayers

A model is proposed for magnetic ordering in Fe/Cr-type multilayers substantially above the Néel temperature of bulk chromium. Redistribution of the charge (and, hence, spin) density near the Fe/Cr interfaces gives rise to the formation of an essentially inhomogeneous spin-density-wave (SDW) state in the chromium spacer. The spatial structure of the antiferromagnetic order parameter in thick spacers is described. The SDW contribution to the effective exchange coupling between the moments in adjacent iron layers is calculated. The data obtained are used in the interpretation of experimental data on the tunneling spectroscopy of trilayers and neutron diffraction from Fe/Cr superlattices.     

Ph(SiMe_2)_nPh体系π→π~*UV谱的研究

本文依据Spin-Free理论,使用Gelfand基构造多电子波函数,采用四轨道模型,对Ph(SiMe_2)_nPh体系(n=1～6)的π→π*跃迁进行了EHMO-CI计算,所得第一及第二跃迁能与UV谱的实验结果基本一致。当体系硅链原子数增加时,第一吸收带红移的现象起因于LUMO中d轨道成份增加,导致电子排斥作用变化。在LUMO中,硅链上的d轨道以πd的形式与苯环π~*轨道进行πd—π~*共轭互相作用,这种作用很可能与第一吸收带的强度有内在的联系。     

钙钛矿型La_((1 x)/2)Sr_((1-x)/2)Co_(1-x)Cu_xO_3催化CO氧化活性与表征

研究了钙钛矿型LaSrCoCu_xO_3催化剂对CO氧化反应的催化活性及其表面氧的催化作用．结果表明，x＝0．4的催化剂对CO氧化具有最高催化活性，常压及本实验条件下CO完全氧化的最低温度为168℃；催化剂均为氧缺陷化合物，吸附于表面晶格氧缺陷上的吸附氧是CO氧化反应的活性氧物种；并发现催化剂中存在有非常价态的C04 ，认为CO氧化反应是通过吸附氧调变Co3 和Co4 价态而进行．     

Bifunctional monodisperse microspheres of copolymers of methyl methacrylate and N-vinylformamide

Emulsion copolymerization of methyl methacrylate and N-vinylformamide in the presence of azo initiators and dextran as a polymeric stabilizer was analyzed with the aim to prepare monodisperse polymer microspheres with a polyfunctional surface. Hydrolysis of comonomer units and cationic groups of the initiator residues in the surface layer of the particles to give amphoteric surfaces containing carboxy and amino groups was studied. The optimal conditions of formation of monodisperse microspheres with diameter varied in the 340–660 nm range and the conditions of their hydrolysis, which allow direct control of the amount and nature of functional groups on their surface, were found.