极小孔半导体激光器近场区光场分布研究

利用时域有限差分法(FDTD)计算和分析了极小孔半导体激光器输出光端面附近的光场分布,指出小孔激光器近场区域光场分布的特点,讨论了小孔大小和金属厚度对光场分布和光源分辨率的影响,得到设计和制备极小孔半导体激光器的优化方法.     

Quantitative assessment of rhodamine spectra

With the development of single-molecule detection and super-resolution fluorescence imaging, rhodamine dyes gain new life. Through the modification of the N-substituents and the replacement of the oxygen atom in xanthene, the wavelength and brightness can be effectively changed. However, the spectra of rhodamine, especially due to the balance between ring-closed non-fluorescent lactone and ring-opened fluorescent zwitterion/cation, are sensitive to interference from various environmental factors. In this way, the spectral data of various rhodamines reported by different research groups under different test conditions lacked comparability, sometimes even lacked accuracy. In order to meet the requirements for the accuracy and uniformity of spectral data in the research of single molecule imaging and dye structure-fluorescence relationship study, we have tested the spectra of fifteen rhodamine dyes that cover the visible and near-infrared regions under exactly the same conditions. By studying the dependence of the spectra on dye concentrations, it was confirmed that 1 μmol/L was ideal for detection less from the interference of dye molecule aggregation. We provide comprehensive and reliable spectral data of these fifteen dyes, which are expected to be used as references for future research. And the direct comparison of different rhodamine spectra would help to understand the structure-fluorescence relationship of rhodamines.     

用于光纤熔接系统的纤芯检测镜头设计

光纤已广泛应用于当今社会的信息传输领域。为了满足长距离光纤传输中高质量光纤熔接的需要,介绍了一个应用于光纤熔接系统的透射光纤纤芯检测系统。该系统中的核心器件是一组能对光纤纤芯成像的特殊镜头。借助于ZEMAX软件,设计了这组检测镜头。该镜头具有8倍放大倍率、长工作距离、短结构、高精度等特点。论述了镜头的设计方案和设计过程,并给出了满足要求的设计结果。通过在LightTools软件中对整个系统检测结果的模拟,证明了该设计的可行性。     

Durable Electrocatalytic Reduction of Nitrate to Ammonia over Defective Pseudobrookite Fe2TiO5 Nanofibers with Abundant Oxygen Vacancies

We propose the pseudobrookite Fe₂TiO₅ nanofiber with abundant oxygen vacancies as a new electrocatalyst to ambiently reduce nitrate to ammonia. Such catalyst achieves a large NH₃ yield of 0.73 mmol h⁻¹ mg⁻¹_cat. and a high Faradaic Efficiency (FE) of 87.6 % in phosphate buffer saline solution with 0.1 M NaNO₃, which is lifted to 1.36 mmol h⁻¹ mg⁻¹_cat. and 96.06 % at −0.9 V vs. RHE for nitrite conversion to ammonia in 0.1 M NaNO₂. It also shows excellent electrochemical durability and structural stability. Theoretical calculation reveals the enhanced conductivity of this catalyst and an extremely low free energy of −0.28 eV for nitrate adsorption at the presence of vacant oxygen.     

香芸火绒草精油化学成分研究

用毛细管气相色谱／质谱、毛细管气相色谱／付里叶红外联用技术对青海产香芸火绒草精油化学成分进行分离。共鉴定出１１９个化俣物，占全部峰面积的９６．８％。     

Preparation of hydrophobic coating on glass surface by dielectric barrier discharge using a 16 kHz power supply

A 16 kHz power supply was used to investigate the preparation of hydrophobic film on glass surface by means of atmospheric pressure dielectric barrier discharge (DBD). Air nonthermal plasma was induced between the two parallel electrodes with a glass plate as dielectric barrier. The process for hydrophobic film includes two parts: one is plasma pretreatment to produce active layer on glass surface, another is to form hydrophobic film on glass surface by means of the interaction between air plasma and polydimethylsiloxane oil. The surface changes were observed using contact angle measurement and atomic force microscope. The results show DBD can increase surface roughness, and effectively improve glass surface activation and form a hydrophobic coating on glass surface, and it is possibility to prepare hydrophobic glass with middle frequency power supply.     

Effect of atmospheric pressure dielectric barrier discharge air plasma on electrode surface

In order to study the influence of plasma on electrode, atmospheric pressure dielectric barrier discharge (DBD) air plasma is employed here to treat copper electrode surface. Plasma is generated between the parallel plate electrodes by means of high voltage produced by a high-frequency power supply with transformer. Electrode surface alterations induced by air plasma are investigated by using field emission scanning electron microscope (FE-SEM), X-ray energy dispersion spectroscopy (EDS) and contact angle measurement. The results show that DBD air plasma removes the organic contaminant on surface and causes electrode surface roughness, oxidization and nitridation. In addition, surface wettability is also improved, as concluded from contact angle measurements.     

一种匀光鳞甲反射罩设计

在灯具设计中,特别是开发投光灯、轨道灯等类型灯具时,经常会遇到系列化设计问题。在不修改基本外形结构的情况下,要想获得不同发光角度、照度均匀,提出了一种通过鳞甲片改变出光角度的反射罩设计方案,包括鳞片参数的计算、基面合理分隔方法、实际仿真模拟。最终给出同样基面,发散角(FWHM)为20°、40°、60°,光能利用率均达到75%,匀光效果85%左右的设计结果,证明该设计方法可行性。     

Construction of a PbII coordination polymer from a semi-rigid ditopic 2,2-biimidazole derivative: synthesis,crystal structure and characterization

<!?tlsb=-0.04pt>A new Pb^II coordination polymer, poly[0.75(aqua)[μ₃-4,4′-(1H,1′H-[2,2′-biimidazole]-1,1′-diyl)dibenzoato-κ⁵O,O′;N;O′′,O′′′]]lead(II)] 1.25-hydrate], {[Pb(C₂₀H₁₂N₄O₄)(H₂O)_0.75]·1.25H₂O}_n or {[Pb(L)(H₂O)_0.75]·1.25H₂O}_n ( 1 ) [H₂L = 4,4′-(1H,1′H-[2,2′-biimidazole]-1,1′-diyl)dibenzoic acid], was synthesized under solvothermal reaction conditions and characterized using microanalysis, IR spectroscopy and thermogravimetric analysis. Single-crystal structure analysis reveals that a two-dimensional corrugated layer structure is formed in 1 and that neighbouring layers are further extended into a three-dimensional structure by hydrogen-bonding interactions. In addition, a fluorescence sensing experiment towards Cu²⁺ based on the polymeric Pb^II complex was carried out.