全文获取类型
收费全文 | 205篇 |
免费 | 0篇 |
专业分类
化学 | 173篇 |
数学 | 3篇 |
物理学 | 29篇 |
出版年
2013年 | 16篇 |
2009年 | 3篇 |
2008年 | 2篇 |
2007年 | 3篇 |
2006年 | 1篇 |
2004年 | 2篇 |
2003年 | 1篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 3篇 |
1999年 | 2篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1996年 | 5篇 |
1995年 | 2篇 |
1994年 | 4篇 |
1992年 | 3篇 |
1991年 | 4篇 |
1990年 | 9篇 |
1989年 | 8篇 |
1988年 | 11篇 |
1987年 | 8篇 |
1986年 | 6篇 |
1985年 | 9篇 |
1984年 | 6篇 |
1983年 | 4篇 |
1982年 | 10篇 |
1981年 | 5篇 |
1980年 | 8篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1977年 | 3篇 |
1976年 | 4篇 |
1975年 | 4篇 |
1974年 | 1篇 |
1973年 | 10篇 |
1972年 | 4篇 |
1971年 | 1篇 |
1970年 | 1篇 |
1969年 | 1篇 |
1968年 | 6篇 |
1967年 | 5篇 |
1966年 | 4篇 |
1965年 | 2篇 |
1964年 | 2篇 |
1963年 | 1篇 |
1962年 | 1篇 |
1961年 | 1篇 |
1959年 | 1篇 |
排序方式: 共有205条查询结果,搜索用时 15 毫秒
1.
2.
Cotton-linter pulps, wood pulps and several filter papers have been evaluated as substrates for room-temperature phosphorescence. A variety of chemical treatments of one filter paper is discussed in terms of reducing the background phosphorescence of the cellulose and in evaluating possible trace contaminants in cotton fibres. In order to account for uniformity of filter paper used in room temperature phosphorescence, a final evaluation of several different lots of one type of filter paper is presented. 相似文献
3.
Optimum conditions have been established for formation and extraction of indium-Rhodamine complexes, and limits of detection found for fluorimetric determination of gallium and indium by means of Rhodamine dyes, using the excitation with pulsed laser and xenon arc sources. 相似文献
4.
An examination was made of the effects of various cations and anions on the determinations of calcium (4227 Å) by flame emission using turbulent hydrogen/ argon/entrained-air and hydrogen/oxygen flames. The effects of height of observation and mechanisms of interference are discussed for Cs+, Rb+, F-, Br-, I-, NO3-, Cl04-, S042-, PO43-, P2O74-, acetate, oxalate, citrate, tartrate and EDTA. Ionization interferences were not detected in the hydrogen/argon/entrained-air flame, but all other types of interference were more serious with this flame than with the hydrogen/ oxygen flame. The study also suggests some methods by which the effects of the interferences may be overcome. 相似文献
5.
A pulsed tunable dye laser pumped with an excimer laser is used to excite ionic fluorescence of the rare earth elements in the inductively-coupled plasma. Because several fluorescence lines were observed after laser excitation, it was possible to draw partial energy-level diagrams for most of the rare earths. Non-resonance fluorescence lines were used for all measurements in order to minimize spectral interferences. Detection limits at given excitation wavelengths are reported for each element. Laser-excited ionic fluorescence eliminates the problem of spectral interferences which has been associated with the determination of the rare earths by atomic emission spectrometry in the inductively-coupled plasma. 相似文献
6.
The effects of anionic, non-ionic, and cationic surfactants and thallium(I) nitrate on the paper-substrate room-temperature phosphorescence (RTP) of eleven phenothiazine derivatives are described. Enhancement factors within the range 1.5–10 are observed after addition of sodium dodecylsulfate, dodecyltrimethylammonium chloride and thallium(I) nitrate. The influence of surfactant on phosphor characteristics as well as effects of moisture are discussed. Limits of detection were in the range 0.2–2 ng. Results are also reported for p-aminobenzoic acid, carbazole and o-terphenyl. 相似文献
7.
A magnetically coupled microcavity hollow cathode discharge device was evaluated for its analytical potential as a boosted atomic emission source. A magnetic field using an electromagnet was applied perpendicular to the axis of the microcavity hollow cathode. The intensity of the atomic emission of copper, aluminum and the ionic emission of magnesium increased with increasing magnetic field until it reached a maximum. A further increase in the field strength did not lead to an enhancement of these emissions. The attainment of the maxima was attributed to the increase in the electron temperature and radial diffusion of the electrons from the center of the microcavity axis. Electron temperatures in the presence of the magnetic field calculated based on the semicorona model were shown to be proportional to the square of the reduced field strength. Further, these maxima were correlated to the energies of the upper levels of the transition studied. 相似文献
8.
Determination of cadmium in river water by sequential metal vapour elution analysis (column temperature; > 1500 K) with argon and hydrogen carrier gas and with atomic absorption spectrometric detection is described. The column is made of a molybdenum capillary tube (i.d. 1.22 mm) and the temperature is 1760 K. The cadmium vapor was separated from those of calcium, iron and sodium. The calibration graph was linear up to 15 μ/ml. Relative standard deviations of 0.8–4.3% were obtained in the range 1 to 15 μ/ml. Cadmium in spiked samples (river water) was determined. The results were in good agreement with the amount spiked. 相似文献
9.
Luminescence of 1,3-dimethylxanthine in solution is impaired owing to collisional deactivation by solvent molecules and matrix interferences. Energy absorbed by 1,3-dimethylxanthine has been transferred to trivalent europium which emits narrow-band radiation in a region distant from background interferences. The enhanced luminescence of trivalent europium was utilized for the determination of 1,3-dimethylxanthine in buffered aqueous solution. An analytically useful range from 1.1 × 10?5?5.0 × 10?4 M and a detection limit of 1.1 × 10?5 M were obtained. The methodology for the analytical procedure was determined. 相似文献
10.
Surface-enhanced Raman spectra (SERS) on silver hydrosols of p-nitrobenzoic acid, p-aminobenzoic acid and aniline are reported. Several theoretical and practical aspects of the hydrosol preparation protocols and sample preparation procedures, and their effects on the sensitivity and reproducibility of the Raman signals are discussed. The effect of acidity on SERS signal intensity is shown to depend on the time of observation of the Raman spectra, illustrating the relevance of time to quantitative SERS data. the identification power of SERS at trace levels for closely related compounds (p-nitrobenzoic acid, p-aminobenzoic acid and aniline) is illustrated. 相似文献