全文获取类型
收费全文 | 104篇 |
免费 | 3篇 |
国内免费 | 1篇 |
专业分类
化学 | 65篇 |
力学 | 2篇 |
数学 | 19篇 |
物理学 | 22篇 |
出版年
2021年 | 2篇 |
2020年 | 1篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2015年 | 3篇 |
2014年 | 1篇 |
2013年 | 4篇 |
2012年 | 1篇 |
2011年 | 1篇 |
2010年 | 1篇 |
2009年 | 1篇 |
2008年 | 3篇 |
2007年 | 5篇 |
2006年 | 6篇 |
2005年 | 2篇 |
2004年 | 2篇 |
2003年 | 3篇 |
2002年 | 1篇 |
2001年 | 1篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1997年 | 1篇 |
1996年 | 2篇 |
1995年 | 1篇 |
1994年 | 2篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1989年 | 2篇 |
1988年 | 3篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1983年 | 6篇 |
1981年 | 3篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 2篇 |
1977年 | 1篇 |
1976年 | 5篇 |
1975年 | 2篇 |
1974年 | 3篇 |
1973年 | 2篇 |
1972年 | 2篇 |
1971年 | 2篇 |
1970年 | 2篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1965年 | 1篇 |
排序方式: 共有108条查询结果,搜索用时 15 毫秒
1.
Linda B. Whittall Robert R. Whittle Grayson W. Stowell 《Acta Crystallographica. Section C, Structural Chemistry》2002,58(8):o525-o527
Two unique conformational polymorphic forms of the compound 6‐[4‐(1‐cyclohexyl‐1H‐tetrazol‐5‐yl)butoxy]‐3,4‐dihydroquinolin‐2(1H)‐one (cilostazol), C20H27N5O2, have been discovered and characterized using single‐crystal X‐ray structural analysis. A third polymorph also exists, but acceptable crystals could not be obtained. Features of both reported polymorphic structures include a chair conformation of the cyclohexyl ring and puckering in the quinolinone ring. The major feature distinguishing the two polymorphic forms is a rotational twisting of the butoxy chain between the tetrazole and quinolinone rings. This difference in conformation influences the intermolecular forces, and hence the packing of the two molecules during crystallization. 相似文献
2.
Whittle M Murray BS Dickinson E Pinfield VJ 《Journal of colloid and interface science》2000,225(2):273-284
Preflocculated ferric hydroxide flocs were subjected to either a simple shear flow or a two-dimensional straining flow, and their motion was optically observed. Digital image analysis was applied to extract information on orientation and deformation from the digitized frames. It was found that the simple shear flow led to a rotation of the flocs whose motion can be understood from the behavior of a solid ellipsoid. In the extensional flow, no continuous rotation occurred and flocs were broken apart along the axis of straining. The rupture forces estimated from an ellipsoid model were found to be in the range of 0.1 N/m(2). Copyright 2000 Academic Press. 相似文献
3.
Feedings of [1-13C]- and [1,2-13C2]acetate Aspergillus terreus gave quadrone and terrecyclic acid which were analyzed by 13C NMR. The pattern of 13C-enrichments and couplings is consistent with the formation of 1 and 2 by cyclization of farnesyl pyrophosphate. 相似文献
4.
Whittle M Gillet VJ Willett P Alex A Loesel J 《Journal of chemical information and computer sciences》2004,44(5):1840-1848
This paper evaluates the effectiveness of various similarity coefficients for 2D similarity searching when multiple bioactive target structures are available. Similarity searches using several different activity classes within the MDL Drug Data Report and the Dictionary of Natural Products databases are performed using BCI 2D fingerprints. Using data fusion techniques to combine the resulting nearest neighbor lists we obtain group recall results which, in many cases, are a considerable improvement on standard average recall values obtained for individual structures. It is shown that the degree of improvement can be related to the structural diversity of the activity class that is searched for, the best results being found for the most diverse groups. The group recall of active compounds using subsets of the class is also investigated: for highly self-similar activity classes, the group recall improvement saturates well before the full activity class size is reached. A rough correlation is found between the relative improvement using the group recall and the square of the number of unique compounds available in all of the merged lists. The Tanimoto coefficient is found unambiguously to be the best coefficient to use for the recovery of active compounds using multiple targets. Furthermore, when using the Tanimoto coefficient, the "MAX" fusion rule is found to be more effective than the "SUM" rule for the combination of similarity searches from multiple targets. The use of group recall can lead to improved enrichment in database searches and virtual screening. 相似文献
5.
The theory of (t, m, s)-nets is useful in the study of sets of points in the unit cube with small discrepancy. It is known that the existence of a (0, 2,s)-net in baseb is equivalent to the existence ofs–2 mutually orthogonal latin squares of orderb. In this paper we generalize this equivalence by showing that fort0 the existence of a (t, t+2,s)-net in baseb is equivalent to the existence ofs mutually orthogonal hypercubes of dimensiont+2 and orderb. Using the theory of hypercubes we obtain upper bounds ons for the existence of such nets. Forb a prime power these bounds are best possible. We also state several open problems.This author would like to thank the Mathematics Department of the University of Tasmania for its hospitality during his sabbatical when this paper was written. The same author would also like to thank the NSA for partial support under grant agreement # MDA904-87-H-2023.This author's research was supported by a grant from the Commonwealth of Australia through the Australian Research Council. 相似文献
6.
Armaan GÜNSEL Aye USLUOLU Ahmet Turgut BLGL TOSUN Büra Gülnur ARABACI Meryem Nilüfer YARAIR 《Turkish Journal of Chemistry》2020,44(4):923
This work reports on dyeing of nylon/elastane fabric with water-soluble phthalocyanines ( 1-4 ) bearing quinoline 5-sulfonic acid substituents on the peripheral or nonperipheral positions and determining the antibacterial efficiency of the phthalocyanine compounds and the dyed nylon/elastane fabrics. The light, washing, water, perspiration, and rubbing fastness properties of nylon/elastane fabrics dyed with phthalocyanines were also determined. The results showed that all dyed fabrics showed very good wet fastness values. The lightfastness value of the nylon/elastane fabric dyed with phthalocyanine dye ( 1 ) showed a much better value than the others. Also, the antibacterial efficiencies of the dyed nylon fabrics and the dye compounds were investigated against a gram-negative ( Escherichia coli ) and a grampositive ( Staphylococcus aureus ) bacteria by using disc diffusion method. The results showed that the dyed nylon/elastane fabrics and the compounds exhibited antibacterial activities against both bacteria. 相似文献
7.
G. A. Stewart G. L. Whittle S. J. Campbell J. Zukrowski 《Hyperfine Interactions》1983,16(1-4):681-684
The intermetallic compound, YMn12, doped with 0.5at.%57Fe has been investigated using the57Fe Mössbauer resonance. The data show that the Fe impurities occupy preferentially the f-site at the expense of the i- and j-sites. Whereas the i- and j-sites are expected to carry identical local magnetic moments in the ordered state, low temperature hyperfine fields of 50.08(±0.05)T and 2.90(±0.03)T are measured for the i- and j-sites respectively. It is proposed that large transferred hyperfine fields are responsible for this disparity. 相似文献
8.
Matrix elements are derived for both first- and second-order Coriolis interactions between A1 and E1 vibrational modes in symmetric tops, with particular reference to sign. The results are applied to the observed microwave transitions J → J + 1 for A1 and E1 states of the C5ν molecule cyclopentadienyl thallium in various excited vibrational states. The microwave transitions in the excited A1 states v4 = 1, 2, 3, the excited E′ state v′0 = 1 and the combination state v4 = 1, v′0 = 1 have yielded constants which are anomalous in several respects (1). Coriolis interactions between the ν4 and ν10 vibrations are shown to account for the observed anomalies. 相似文献
9.
Enones can be converted in high yield to their corresponding 2-halo analogues by treatment with an excess of phenylselenium halide in methylene chloride/pyridine at 37°C. 相似文献
10.
P. Whittle 《Journal of statistical physics》1989,56(3-4):499-516
The analysis of random graphs developed by the author, principally as a model for polymerization processes, is extended to the case of directed random graphs, with models of neural nets in mind. The principal novelty of the directed case is the representation of the partition function by a complex rather than a real integral, and the replacement of simple maxima in asymptotic evaluations by an interesting form of saddle point. 相似文献