多孔物质气固反应动力学研究

利用自主研制的微型流化床反应分析仪（MFBRA）在等温条件下测试了高比表面活性炭氧化反应,并根据基于固体转化的热分析动力学方法及考虑气体在微孔内扩散与反应的应用化工动力学方法求算了动力学参数．在内外扩散抑制最小化的实验条件下,粒径小于5μm的活性炭在700-1000℃的燃烧反应动力学研究表明,根据微型流化床中实验数据,采用等温热分析动力学方法求算得内扩散控制区活化能约为95kJ／mol;弓l入化工动力学方法中的随机孔模型对低温区等温燃烧数据拟合,可得孔结构参数在0．17m^-3左右,反应活化能为178kJ／mol,约为内扩散反应活化能的两倍,最为接近本征的碳燃烧反应活化能．     

Nonzero-sum games for continuous-time Markov chains with unbounded transition and average payoff rates

This paper attempts to study two-person nonzero-sum games for denumerable continuous-time Markov chains determined by transition rates,with an expected average criterion.The transition rates are allowed to be unbounded,and the payoff functions may be unbounded from above and from below.We give suitable conditions under which the existence of a Nash equilibrium is ensured.More precisely,using the socalled "vanishing discount" approach,a Nash equilibrium for the average criterion is obtained as a limit point of a sequence of equilibrium strategies for the discounted criterion as the discount factors tend to zero.Our results are illustrated with a birth-and-death game.     

Observation constraints of the hard X-ray modulation telescope HXMT

The hard X-ray modulation telescope HXMT is a low orbit X-ray space telescope whose main science goals are to accomplish a hard X-ray all sky survey and to study timing and spectral characteristics of X-ray sources. HXMT has three kinds of science instruments: the high energy X-ray detector (HE), the medium energy X-ray detector (ME) and the low energy X-ray detector (LE). The observation schedule of HXMT is a key to achieving the science goal of HXMT, and the analysis of the observation constraints is one of the first tasks in making the observation schedule. This paper analyzes how the observation constraints influence the sky visibility and the visible time distribution of X-ray sources and discusses the schedule strategy with regard to the observation constraints.     

十氢萘气相氧化裂解制低碳烯烃的研究

十氢萘气相氧化裂解（GOC）与传统的热裂解工艺相比,O2的存在降低了十氢萘GOC反应的活化能,使反应在较低温度下具有高的反应性能;O2同时起到消除积炭的作用,提高体系的抗积炭能力。十氢萘GOC反应在较低温度下即可获得较高的液体收率;高温下由于十氢萘裂解深度较高,低碳烯烃收率可高于液体收率,在所得的液体中,芳烃,尤其是BTX（苯、甲苯和二甲苯）占主要部分。十氢萘GOC反应制备低碳烯烃的适宜反应条件为,700℃~800℃,停留<0.4s,烷氧摩尔比0.3~0.5,空气可代替纯氧进料。800℃,烷氧摩尔比0.5,停留0.4s,可获得37％左右的低碳烯烃收率和50%左右的液体收率（BTX收率为29％）。