The First Intramolecular Charge Transfer Transition Based on 2-Ureido-4[1H]-pyrimidinone Binding Module

The first intramolecular charge transfer transition based on 2-ureido-4[1H]-pyrimidinone binding module was reported.     

深能级杂质对光导半导体开关非线性特性的影响

建立了非线性GaAs光导开关深能级杂质瞬态模型的基本方程,获得了与实验现象定性吻合的电流输出,给出了平均载流子随时间演化的情况.分析结果表明,在考虑了深能级杂质的俘获、发射和碰撞电离后,有可能对非线性光导开关中发生的一系列现象做出解释,进一步的仔细分析将对非线性光导开关的设计和制作提供理论指导.     

Immobilization of Glucose Oxidase on Cellulose／Cellulose Acetate Membrane and its Detection by Scanning Electrochemical Microscope （SECM）

Cellulose/cellulose acetate membranes were prepared and functionalized by introducingamino group on it, and then immobilized the glucose oxidase (Gox) on the functionalizd membrane.SECM was applied for the detection of enzyme activity immobilized on the membrane.Immobilized biomolecules on such membranes was combined with analysis apparatus and can beused in bioassays.     

A Novel Proton Sensor with Luminescence and Color Signaling Based on Platinum(II) Terpyridyl Acetylide Complex

Molecular switches that are controllable, reversible and readable at molecular level are an essential compo-nent of molecular electronics1 and chemical sensors.2-6 Of particular interest are the molecules which show dramatic and reversible changes in color and/or lumi-nescence in visible spectral region upon exposure to specific substrates. A number of chromophore- spacer-receptor systems that can selectively recognize specific guest molecules at their receptor site and pro-duce measurable col…     

Synthesis and Luminescent Properties of an Acetylide-Bridged Dinuclear Platinum(II) Terpyridyl Complex

Introduction Luminescent coordinatively unsaturated platinum(II) complexes are appealing from photochemical and pho-tophysical perspective.1,2 In particular, platinum(II) ter-pyridyl complexes have attracted considerable attention due to their rich spectroscopic2a-d and biological proper-ties.2a,e-g However, the development of the photochem-istry of these complexes is limited by their short-lived MLCT excited state in solution at room temperature. The lack of emission originates from low-l…     

Simple and efficient synthesis of 3,4-dihydro-2-pyridones via novel solid-supported aza-annulation

A diverse array of 3,4-dihydro-2-pyridones 13 were produced utilizing the unique properties of solid-supported reactions to both drive the reactions to completion and isolate the desired products. The pyridones were synthesized in high purity by a simple sequence of novel steps commencing from an acetophenone-functionalized resin. The para-substituted acetophenone 9 could be anchored to the resin through either a sulfonamide or a carboxamide linkage. The sulfonamide resin 9a, which gave the best results, was treated with several aryl aldehydes and ethoxide to give a variety of chalcones 10a-k in excellent yield (82-99%) upon TFA cleavage. Addition of either methyl or allyl malonate and DBU to 10a-k afforded smoothly the Michael adducts 11a-j (70-99%) which were subsequently cyclized in one step employing acetic acid as a catalyst and several diverse amines to give pure 3,4-dihydro-2-pyridones 13a-p in moderate to excellent yields (30-98%).     

V-positivity,poverses and the economic global unicity theorems of Gale and Nikaido

Summary Strong theorems concerning globally unique solutions to nonlinear inequalities have been obtained byGale andNikaido via P-matrix characterizations of theJacobians of the mappings involved. We introduce two new concepts here: v-positivity and the poverse. These permit us to state and prove significant generalizations of the theorems just mentioned and, equally important, provide access to preliminary results concerning linear inequalities by the powerful direct techniques of linear programming theory.

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Zusammenfassung Gale undNikaido haben starke Sätze über globale, eindeutige Lösungen nichtlinearer Ungleichungen erhalten für den Fall, daß dieJacobi- Matrix der auftretenden Abbildung eineP-Matrix ist. Darauf aufbauend werden zwei neue Konzepte vorgestellt: v-positivity und die poverse. Diese erlauben es, Verallgemeinerungen der erwähnten Sätze aufzustellen und zu beweisen und, was von gleicher Bedeutung ist, die Verbindung zu früheren Ergebnissen über lineare Ungleichungen durch die wirkungsvollen direkten Verfahren der Theorie der Linearen Optimierung herzustellen.

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This Research was partly supported by Project No. NR 047-021, ONR Contracts NO 0014-67-A-0126-0008 and NO 0014-67-A-0126-0009 with the Center for Cybernetic Studies, The University of Texas.     

ON THE ASYMPTOTIC BEHAVIOR OF HOPFIELD NEURAL NETWORK WITH PERIODIC INPUTS

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Stable pricing policies in service systems

Summary Customers arriving for service at a service system are allowed to purchase their priorities. A pricing policy is said to be stable if no one customer can reduce his expected cost by deviating from it, provided that all other customers follow it. The policy considered specifies prices to be paid by arrivals based on the number in the system at the epoch of the arrival and a parameter, which is the number of customers in a group paying the same price. The necessary and sufficient conditions for this policy to be stable are derived. The optimal value of the parameter and the prices that will maximize the expected return to the service center operator while maintaining stability are discussed. The basic queueing model assumesPoisson arrivals, exponential service times and single server.

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Zusammenfassung Für die zur Abfertigung an einem Bedienungssystem eintreffenden Kunden besteht die Möglichkeit, ihre gewünschte Abfertigungspriorität gegen einen entsprechenden Preis zu kaufen. Eine vom Betreiber des Bedienungssystems verfolgte Preispolitik wird als stabil bezeichnet, falls kein Kunde seine erwarteten Kosten durch Abweichungen von dieser Preispolitik senken kann, vorausgesetzt daß alle anderen Kunden gemäß dieser Preispolitik behandelt werden. Bei der hier untersuchten Politik werden die von den eintreffenden Kunden zu zahlenden Preise nach der zum Ankunftszeitpunkt im System vorhandenen Kundenzahl festgesetzt. Außerdem wird zusätzlich als Parameter die Anzahl der Kunden in derselben Preisgruppe berücksichtigt. Es werden dann die notwendigen und hinreichenden Bedingungen für die Stabilität der Preispolitik abgeleitet. Anschließend werden diejenigen Werte für den Parameter und die Preise diskutiert, durch die der erwartete Gewinn für den Betreiber des Bedienungssystems bei stabiler Preispolitik maximiert wird. Der Untersuchung wurde ein Warteschlangenmodell mitPoisson-verteilten Ankünften, exponentialverteilten Abfertigungszeiten und einer Bedienungsstation zugrunde gelegt.