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Voranuch Somsongkul Felix Lang Ah Reum Jeong Marin Rusu Marisa Arunchaiya Thomas Dittrich 《固体物理学:研究快报》2014,8(9):763-766
Modulated charge separation across (MO)/CH3NH3PbI3 and (MO)/PbI2/CH3NH3PbI3 (MO = TiO2, MoO3) interfaces was investigated by surface photovoltage (SPV) spectroscopy. Perovskite layers were deposited by solution‐based one‐step preparation and two‐step preparation methods. An unreacted PbI2 layer remained at the interface between the metal oxide and CH3NH3PbI3 for two‐step preparation. For the two‐step preparation on TiO2, the SPV signal related to absorption in CH3NH3PbI3 increased in comparison to the one‐step preparation due to electron transfer from CH3NH3PbI3 via PbI2 into TiO2 whereas the SPV signal related to defect transitions decreased. For the one‐step preparation on MoO3, holes photogenerated in CH3NH3PbI3 recombined with electrons in MoO3. In contrast, a hole transfer from CH3NH3PbI3 towards MoO3 was blocked by the PbI2 interlayer for the two‐step preparation on MoO3. (© 2014 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
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