Inventory strategies for systems with fast remanufacturing

We describe hybrid manufacturing/remanufacturing systems with a long lead time for manufacturing and a short lead time for remanufacturing. We review the classes of inventory strategies for hybrid systems in the literature. These are all based on equal lead times. For systems with slow manufacturing and fast remanufacturing, we propose a new class. An extensive numerical experiment shows that the optimal strategy in the new class almost always performs better and often much better than the optimal strategies in all other classes.     

Evolution of self-assembled silica-tetrapropylammonium nanoparticles at elevated temperatures

The time evolution of silica nanoparticles in solutions of tetrapropylammonium (TPA) has been studied using a combination of small-angle scattering, conductivity, and pH measurements to provide the first comprehensive analysis of nanoparticle structural and compositional changes at elevated temperatures. We have found that silica-TPA nanoparticles subjected to hydrothermal treatment (70-90 degrees C) grow via an Ostwald ripening mechanism with growth rates that depend on both pH and temperature. Small-angle X-ray (SAXS) and neutron (SANS) scattering confirm that the core-shell structure of the particles, initially present at room temperature, is maintained during heating, but an evolution toward sphericity is evidenced especially at high values of pH. SAXS absolute intensity calculations were utilized to calculate the changes in nanoparticle composition and concentration over time. These changes along with the conductivity and pH measurements and SANS contrast matching studies indicate that, upon heating, TPA becomes embedded in the core of nanoparticles giving rise to more zeolitic-looking nanomaterials.     

Comparison of small metal clusters: Ni, Pd, Pt, Cu, Ag, Au

Structures of small clusters of Ni, Pd, Pt, Cu, Ag, and Au with n=2–34 and n=55 atoms are calculated as functions of number of atoms and temperature by the simulated annealing Monte Carlo method using an embedded atom potential.     

Electroluminescent segmented liquid crystalline trimers

The synthesis and liquid crystal behaviour of light‐emitting trimeric liquid crystals consisting of three mesomorphic moieties connected by aliphatic spacers are reported. The combination of an aromatic light‐emitting central core and two cholestanyl (dihydrocholesteryl) groups induces a helical liquid crystalline phase with circularly polarised photoluminescence and electroluminescence. These segmented trimers are designed to possess a high glass transition temperature below which the structure of liquid crystalline phases can be fixed. The effects of odd and even spacers, spacer length and the presence of large lateral substituents on the liquid crystal behaviour and the glass transition temperature of these trimers were studied. Electroluminescence from a segmented liquid crystalline trimer is reported for the first time.     

Phosphonate‐Modified UiO‐66 Brønsted Acid Catalyst and Its Use in Dehydra‐Decyclization of 2‐Methyltetrahydrofuran to Pentadienes

Phosphorus‐modified all‐silica zeolites exhibit activity and selectivity in certain Brønsted acid catalyzed reactions for biomass conversion. In an effort to achieve similar performance with catalysts having well‐defined sites, we report the incorporation of Brønsted acidity to metal–organic frameworks with the UiO‐66 topology, achieved by attaching phosphonic acid to the 1,4‐benzenedicarboxylate ligand and using it to form UiO‐66‐PO₃H₂ by post‐synthesis modification. Characterization reveals that UiO‐66‐PO₃H₂ retains stability similar to UiO‐66, and exhibits weak Brønsted acidity, as demonstrated by titrations, alcohol dehydration, and dehydra‐decyclization of 2‐methyltetrahydrofuran (2‐MTHF). For the later reaction, the reported catalyst exhibits site‐time yields and selectivity approaching that of phosphoric acid on all‐silica zeolites. Using solid‐state NMR and deprotonation energy calculations, the chemical environments of P and the corresponding acidities are determined.     

Optical clock repetition-rate multiplier for high-speed digital optical logic circuits

Repetition-rate multiplication has been shown by use of a fiber ring oscillator with a semiconductor optical amplifier as the gain medium and by use of fast saturation and recovery of the amplifier from an external optical pulse train. Repetition-frequency multiplication up to 6 times and up to 34.68-GHz frequency have been achieved.     

Bifurcation analysis of Liesegang ring pattern formation

Bifurcation analysis is introduced to a prototype Liesegang ring (LR) model to explain pattern formation as an instability of a propagating plane reaction front. A theoretical criterion for the onset of patterning is derived and numerically tested. The uneven spacing law of LR bands is explained as a consequence of the time varying velocity of the moving reaction front. Suggestions for controlling pattern formation are provided.     

Quantum friction in a periodic potential

In this paper we study the quantum friction problem using the Hamiltonian of Caldirola-Kanai for a periodic Mathieu's type potential. In the sequel we study the lattice electron with friction we introduce a new effective Hamiltonian of the Caldirola-Kanai form for a Bloch's band. Finally we study the cases of closed solutions of Schrödinger's equation.     

Turbulent boundary layer on a mildly curved convex surface

Mean flow and turbulence measurements have been made in a boundary layer which grows first on a flat' wall and then on a convex wall of radius of curvature approximately 100 times the boundary layer thickness. The turbulence data include profiles of the four non-zero components of the Reynolds stress tensor and three triple velocity products obtained at five stream-wise positions. A number of measurements were also made for comparison in the boundary layer on a flat wall under the same conditions. The effects of convex curvature are to reduce turbulent intensities, shear stress and wall friction by approximately 10% of their plane flow values; the triple velocity products are halved in the curved layer. The measurements supplement the small quantity of previously published data available for testing mathematical models of turbulence. The results show the same general trends that have been observed in earlier investigations but there are significant differences in detail, notably in respect of levels of the normal stresses.